Sulfide-Induced Dimerization Versus Demetallation of Tricopper(I) Clusters Protected by Tris-Thiolato Metalloligands

Goo, Zi Lang; Yoshinari, Nobuto; Yasukawa, Yuhei; Minami, Katsue; Konno, Takumi

doi:https://doi.org/10.1002/asia.202400266

Sulfide-Induced Dimerization Versus Demetallation of Tricopper(I) Clusters Protected by Tris-Thiolato Metalloligands

Goo, Zi Lang; Yoshinari, Nobuto; Yasukawa, Yuhei et al.

Chemistry - An Asian Journal, 2024, 19(13), e202400266

アクセス数:144件（2025-06-19 03:05 集計）

固定URL: https://hdl.handle.net/11094/97146

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タイトル	Sulfide-Induced Dimerization Versus Demetallation of Tricopper(I) Clusters Protected by Tris-Thiolato Metalloligands
著者	著者名 Goo, Zi Lang
	NRID 1000010583338 1000010583338 ORCID 0000-0003-2457-0967 0000-0003-2457-0967 researchmap permalink read0151149 read0151149 Scopus Author ID 14009212400 14009212400 著者名 Yoshinari, Nobuto
	著者名 Yasukawa, Yuhei
	著者名 Minami, Katsue
	NRID 1000050201497 1000050201497 researchmap permalink takumikonno takumikonno Scopus Author ID 7202325347 7202325347 著者名 Konno, Takumi
キーワード等	copper cluster
	metalloligand
	S ligand
	structural conversion
	sulfide ion
内容	Goo Z.L., Yoshinari N., Yasukawa Y., et al. Sulfide-Induced Dimerization Versus Demetallation of Tricopper(I) Clusters Protected by Tris-Thiolato Metalloligands. Chemistry - An Asian Journal 19, e202400266 (2024); https://doi.org/10.1002/asia.202400266.
抄録	Here, we report the reactivity of copper(I) clusters toward sulfide ions; these sulfide copper(I) clusters have attracted much attention due to their relevance to biologically active centers and their fascinating structural and photophysical properties. Treatment of the CuI3RhIII2 pentanuclear complex, [Cu3{Rh(aet)3}2]3+ (aet=2-aminoethanethiolate), in which a {CuI3}3+ cluster moiety is bound by two fac-[Rh(aet)3] metalloligands, with NaSH in water produced the CuI6RhIII4 decanuclear complex, [Cu6S{Rh(aet)3}4]4+, accompanied by the dimerization of [Cu3{Rh(aet)3}2]3+ and the incorporation of a sulfide ion at the center. While similar treatment using the analogous CuI3IrIII2 complex with fac-[Ir(aet)3] metalloligands, [Cu3{Ir(aet)3}2]3+, produced the isostructural CuI6IrIII4 decanuclear complex, [Cu6S{Ir(aet)3}4]4+, the use of the CuI3RhIII2 complex with fac-[Rh(apt)3] metalloligands, [Cu3{Rh(apt)3}2]3+ (apt=3-aminopropanethiolate), resulted in the removal of one of the three CuI atoms from {CuI3}3+ to afford the CuI2RhIII2 tetranuclear complex, [Cu2{Rh(apt)3}2]2+.
出版者	John Wiley and Sons Ltd
収録物名	Chemistry - An Asian Journal
巻(号)	19(13)
ページ	e202400266
刊行年月	2024-07-02
言語	英語
ハンドルURL	https://hdl.handle.net/11094/97146
PISSN	18614728
eISSN	1861471X
関連情報 (isIdenticalTo)	DOI (出版社版) https://doi.org/10.1002/asia.202400266
アクセス権	open access
権利情報	This article is licensed under a Creative Commons Attribution 4.0 International License.
出版タイプ	Version of Record
カテゴリ	学術雑誌論文 Journal Article

資源タイプ	学術雑誌論文
ローカル資源タイプ	学術雑誌論文
DCTERMS.bibliographicCitation	Chemistry - An Asian Journal. 2024, 19(13), p. e202400266
DC.title	Sulfide-Induced Dimerization Versus Demetallation of Tricopper(I) Clusters Protected by Tris-Thiolato Metalloligands
DC.creator	Goo, Zi Lang
	Yoshinari, Nobuto
	Yasukawa, Yuhei
	Minami, Katsue
	Konno, Takumi
DC.publisher	John Wiley and Sons Ltd
DC.language' scheme='DCTERMS.RFC1766	英語
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2024-07-02
DC.identifier	https://doi.org/10.1002/asia.202400266
DC.subject	copper cluster
	metalloligand
	S ligand
	structural conversion
	sulfide ion
DC.description	Goo Z.L., Yoshinari N., Yasukawa Y., et al. Sulfide-Induced Dimerization Versus Demetallation of Tricopper(I) Clusters Protected by Tris-Thiolato Metalloligands. Chemistry - An Asian Journal 19, e202400266 (2024); https://doi.org/10.1002/asia.202400266.
DCTERMS.abstract	Here, we report the reactivity of copper(I) clusters toward sulfide ions; these sulfide copper(I) clusters have attracted much attention due to their relevance to biologically active centers and their fascinating structural and photophysical properties. Treatment of the CuI3RhIII2 pentanuclear complex, [Cu3{Rh(aet)3}2]3+ (aet=2-aminoethanethiolate), in which a {CuI3}3+ cluster moiety is bound by two fac-[Rh(aet)3] metalloligands, with NaSH in water produced the CuI6RhIII4 decanuclear complex, [Cu6S{Rh(aet)3}4]4+, accompanied by the dimerization of [Cu3{Rh(aet)3}2]3+ and the incorporation of a sulfide ion at the center. While similar treatment using the analogous CuI3IrIII2 complex with fac-[Ir(aet)3] metalloligands, [Cu3{Ir(aet)3}2]3+, produced the isostructural CuI6IrIII4 decanuclear complex, [Cu6S{Ir(aet)3}4]4+, the use of the CuI3RhIII2 complex with fac-[Rh(apt)3] metalloligands, [Cu3{Rh(apt)3}2]3+ (apt=3-aminopropanethiolate), resulted in the removal of one of the three CuI atoms from {CuI3}3+ to afford the CuI2RhIII2 tetranuclear complex, [Cu2{Rh(apt)3}2]2+.
DC.rights	This article is licensed under a Creative Commons Attribution 4.0 International License.
DC.format	97146
citation_title	Sulfide-Induced Dimerization Versus Demetallation of Tricopper(I) Clusters Protected by Tris-Thiolato Metalloligands
citation_author	Goo, Zi Lang
	Yoshinari, Nobuto
	Yasukawa, Yuhei
	Minami, Katsue
	Konno, Takumi
citation_publisher	John Wiley and Sons Ltd
citation_language	英語
citation_date	2024-07-02
citation_journal_title	Chemistry - An Asian Journal
citation_volume	19
citation_issue	13
citation_firstpage	e202400266
citation_doi	https://doi.org/10.1002/asia.202400266
citation_public_url	https://hdl.handle.net/11094/97146

Sulfide-Induced Dimerization Versus Demetallation of Tricopper(I) Clusters Protected by Tris-Thiolato Metalloligands

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