Synthesis of Dibenzoxasilepine Using Ring Expansion Reaction of a Pentacoordinate Silicon Intermediate

Watanabe, Keigo; Sato, Mutsuki; Takehara, Tsunayoshi; Asano, Kaori; Matsuzaki, Tsuyoshi; Suzuki, Takeyuki; Sako, Makoto; Arisawa, Mitsuhiro

doi:https://doi.org/10.1002/adsc.202401125

Synthesis of Dibenzoxasilepine Using Ring Expansion Reaction of a Pentacoordinate Silicon Intermediate

Watanabe, Keigo; Sato, Mutsuki; Takehara, Tsunayoshi et al.

Advanced Synthesis and Catalysis, 2024

アクセス数:1,016件（2025-09-29 21:33 集計）

固定URL: https://hdl.handle.net/11094/100190

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タイトル	Synthesis of Dibenzoxasilepine Using Ring Expansion Reaction of a Pentacoordinate Silicon Intermediate
著者	著者名 Watanabe, Keigo
	著者名 Sato, Mutsuki
	著者名 Takehara, Tsunayoshi
	NRID 1000000311762 1000000311762 researchmap permalink read0054814 read0054814 Scopus Author ID 7402920138 7402920138 著者名 Asano, Kaori
	著者名 Matsuzaki, Tsuyoshi
	NRID 1000010262924 1000010262924 ORCID 0000-0002-2137-0276 0000-0002-2137-0276 researchmap permalink read0183932 read0183932 Scopus Author ID 55731626500 55731626500 著者名 Suzuki, Takeyuki
	NRID 1000020804090 1000020804090 ORCID 0000-0002-4268-7002 0000-0002-4268-7002 researchmap permalink ms39 ms39 Scopus Author ID 56014375200 56014375200 著者名 Sako, Makoto
	NRID 1000040312962 1000040312962 ORCID 0000-0002-7937-670X 0000-0002-7937-670X researchmap permalink read0054866 read0054866 Scopus Author ID 7102922041 7102922041 著者名 Arisawa, Mitsuhiro
キーワード等	Heterocycles
	Medium-ring compounds
	Ring expansion
	Silicon
内容	Watanabe K., Sato M., Takehara T., et al. Synthesis of Dibenzoxasilepine Using Ring Expansion Reaction of a Pentacoordinate Silicon Intermediate. Advanced Synthesis and Catalysis , (2024); https://doi.org/10.1002/adsc.202401125.
抄録	Dibenzoxasilepine is an important skeleton in both synthetic organic and medicinal chemistry. Here, we have succeeded in obtaining it in higher yield than the conventional method, elucidating for the first time the rearrangement tendency of the two aromatic rings during the ring expansion reaction on the cyclic pentacoordinate silicon intermediate.
出版者	John Wiley and Sons Inc
収録物名	Advanced Synthesis and Catalysis
刊行年月	2024-12-16
言語	英語
ハンドルURL	https://hdl.handle.net/11094/100190
PISSN	16154150
eISSN	16154169
関連情報 (isIdenticalTo)	DOI (出版社版) https://doi.org/10.1002/adsc.202401125
アクセス権	open access
権利情報	This article is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
出版タイプ	Version of Record
カテゴリ	学術雑誌論文 Journal Article

資源タイプ	学術雑誌論文
ローカル資源タイプ	学術雑誌論文
DCTERMS.bibliographicCitation	Advanced Synthesis and Catalysis. 2024
DC.title	Synthesis of Dibenzoxasilepine Using Ring Expansion Reaction of a Pentacoordinate Silicon Intermediate
DC.creator	Watanabe, Keigo
	Sato, Mutsuki
	Takehara, Tsunayoshi
	Asano, Kaori
	Matsuzaki, Tsuyoshi
	Suzuki, Takeyuki
	Sako, Makoto
	Arisawa, Mitsuhiro
DC.publisher	John Wiley and Sons Inc
DC.language' scheme='DCTERMS.RFC1766	英語
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2024-12-16
DC.identifier	https://doi.org/10.1002/adsc.202401125
DC.subject	Heterocycles
	Medium-ring compounds
	Ring expansion
	Silicon
DC.description	Watanabe K., Sato M., Takehara T., et al. Synthesis of Dibenzoxasilepine Using Ring Expansion Reaction of a Pentacoordinate Silicon Intermediate. Advanced Synthesis and Catalysis , (2024); https://doi.org/10.1002/adsc.202401125.
DCTERMS.abstract	Dibenzoxasilepine is an important skeleton in both synthetic organic and medicinal chemistry. Here, we have succeeded in obtaining it in higher yield than the conventional method, elucidating for the first time the rearrangement tendency of the two aromatic rings during the ring expansion reaction on the cyclic pentacoordinate silicon intermediate.
DC.rights	This article is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
DC.format	100190
citation_title	Synthesis of Dibenzoxasilepine Using Ring Expansion Reaction of a Pentacoordinate Silicon Intermediate
citation_author	Watanabe, Keigo
	Sato, Mutsuki
	Takehara, Tsunayoshi
	Asano, Kaori
	Matsuzaki, Tsuyoshi
	Suzuki, Takeyuki
	Sako, Makoto
	Arisawa, Mitsuhiro
citation_publisher	John Wiley and Sons Inc
citation_language	英語
citation_date	2024-12-16
citation_journal_title	Advanced Synthesis and Catalysis
citation_doi	https://doi.org/10.1002/adsc.202401125
citation_public_url	https://hdl.handle.net/11094/100190

Synthesis of Dibenzoxasilepine Using Ring Expansion Reaction of a Pentacoordinate Silicon Intermediate

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