学術雑誌論文

学術雑誌論文

Journal of Physical Chemistry B. 2014, 118(47), p. 13404-13408

Nucleophilic reactions of bromocyclopentane in the structure-h methane + bromocyclopentane mixed hydrate system at high pressures

American Chemical Society

英語

2014-07-11

https://doi.org/10.1021/jp505313v

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Physical Chemistry B, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/jp505313v.

Thermodynamic stability boundary in the structure-H methane + bromocyclopentane mixed hydrate system was measured at pressures from 20 to 100 MPa. The thermodynamic stability boundary of the methane + bromocyclopentane mixed hydrate exhibits anomalous behavior under conditions at high pressures and high temperatures. This phenomenon is due to the elimination and substitution reactions of bromocyclopentane to cyclopentene and cyclopentanol, respectively. The nucleophilic reactions of bromocyclopentane are mainly advanced in the liquid bromocyclopentane-rich phases, while it is restrained when bromocyclopentane is enclathrated in hydrate cage.

© 2014 American Chemical Society.

100987

Nucleophilic reactions of bromocyclopentane in the structure-h methane + bromocyclopentane mixed hydrate system at high pressures

American Chemical Society

英語

2014-07-11

Journal of Physical Chemistry B

118

47

13404

13408

https://doi.org/10.1021/jp505313v

https://hdl.handle.net/11094/100987