Dimensions and viscosity behavior of polyelectrolyte brushes in aqueous sodium chloride. A polymacromonomer consisting of sodium poly(styrene sulfonate)

Kanemaru, Eiji; Nakamura, Yo; Terao, Ken; Norisuye, Takashi

doi:https://doi.org/10.1016/j.polymer.2008.07.047

Dimensions and viscosity behavior of polyelectrolyte brushes in aqueous sodium chloride. A polymacromonomer consisting of sodium poly(styrene sulfonate)

Kanemaru, Eiji; Nakamura, Yo; Terao, Ken et al.

Polymer, 2008, 49(19), 4174-4179

アクセス数:498件（2025-07-11 12:11 集計）

固定URL: https://hdl.handle.net/11094/25936

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タイトル	Dimensions and viscosity behavior of polyelectrolyte brushes in aqueous sodium chloride. A polymacromonomer consisting of sodium poly(styrene sulfonate)
著者	著者名 Kanemaru, Eiji
	NRID 1000090243162 1000090243162 著者名 Nakamura, Yo
	NRID 1000060334132 1000060334132 ORCID 0000-0001-7363-4491 0000-0001-7363-4491 researchmap permalink kenterao kenterao Scopus Author ID 7101653015 7101653015 著者名 Terao, Ken
	NRID 1000010028227 1000010028227 著者名 Norisuye, Takashi
キーワード等	Polyelectrolyte brush
	Light scattering
	Chain stiffness
抄録	Nine samples of a polymacromonomer consisting of sodium poly(styrene sulfonate) and having a side-chain polymerization degree of 15 are investigated by light scattering, small-angle X-ray scattering, and viscometry with 0.05 M aqueous NaCl at 25 °C as the solvent. The (total) weight-average molecular weight M_w ranges from 2.2 × 10^4 to 7.1 × 10^6. The radii of gyration, scattering functions, and intrinsic viscosities determined as functions of Mw are analyzed in terms of the cylindrical wormlike chain model. The estimated Kuhn segment length of about 120 nm is much larger than that (16 nm) for the polystyrene polymacromonomer with the equivalent side-chain length in toluene, a good solvent, while the chain thickness (5.5 nm) is comparable to or only slightly larger than that (5 nm) of the nonionic polymer. It is thus concluded that the electrostatic repulsion between side chains significantly stiffens the main chain of the polyelectrolyte brush.
出版者	Elsevier BV
収録物名	Polymer
巻(号)	49(19)
ページ	4174-4179
刊行年月	2008-09-09
言語	英語
ハンドルURL	https://hdl.handle.net/11094/25936
PISSN	00323861
NCID	AA11537383
関連情報 (isVersionOf)	DOI (出版社版) https://doi.org/10.1016/j.polymer.2008.07.047
アクセス権	open access
出版タイプ	Accepted Manuscript
カテゴリ	学術雑誌論文 Journal Article

資源タイプ	学術雑誌論文
ローカル資源タイプ	学術雑誌論文
DCMI資源タイプ	text
DCTERMS.bibliographicCitation	Polymer. 2008, 49(19), p. 4174-4179
DC.title	Dimensions and viscosity behavior of polyelectrolyte brushes in aqueous sodium chloride. A polymacromonomer consisting of sodium poly(styrene sulfonate)
DC.creator	Kanemaru, Eiji
	Nakamura, Yo
	Terao, Ken
	Norisuye, Takashi
DC.publisher	Elsevier BV
DC.language' scheme='DCTERMS.RFC1766	英語
DC.type' scheme='DCTERMS.DCMIType	text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2008-09-09
DC.identifier	https://doi.org/10.1016/j.polymer.2008.07.047
DC.subject	Polyelectrolyte brush
	Light scattering
	Chain stiffness
DCTERMS.abstract	Nine samples of a polymacromonomer consisting of sodium poly(styrene sulfonate) and having a side-chain polymerization degree of 15 are investigated by light scattering, small-angle X-ray scattering, and viscometry with 0.05 M aqueous NaCl at 25 °C as the solvent. The (total) weight-average molecular weight M_w ranges from 2.2 × 10^4 to 7.1 × 10^6. The radii of gyration, scattering functions, and intrinsic viscosities determined as functions of Mw are analyzed in terms of the cylindrical wormlike chain model. The estimated Kuhn segment length of about 120 nm is much larger than that (16 nm) for the polystyrene polymacromonomer with the equivalent side-chain length in toluene, a good solvent, while the chain thickness (5.5 nm) is comparable to or only slightly larger than that (5 nm) of the nonionic polymer. It is thus concluded that the electrostatic repulsion between side chains significantly stiffens the main chain of the polyelectrolyte brush.
DC.format	25936
citation_title	Dimensions and viscosity behavior of polyelectrolyte brushes in aqueous sodium chloride. A polymacromonomer consisting of sodium poly(styrene sulfonate)
citation_author	Kanemaru, Eiji
	Nakamura, Yo
	Terao, Ken
	Norisuye, Takashi
citation_publisher	Elsevier BV
citation_language	英語
citation_date	2008-09-09
citation_journal_title	Polymer
citation_volume	49
citation_issue	19
citation_firstpage	4174
citation_lastpage	4179
citation_doi	https://doi.org/10.1016/j.polymer.2008.07.047
citation_public_url	https://hdl.handle.net/11094/25936

Dimensions and viscosity behavior of polyelectrolyte brushes in aqueous sodium chloride. A polymacromonomer consisting of sodium poly(styrene sulfonate)

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