学術雑誌論文

学術雑誌論文

text

Acta Crystallographica Section C. 2010, 66(6), p. m160-m162

Tetrapotassium [μ_2-N-carboxylato-D-penicillaminato(3-)-5:6κ^2S:S][μ_2-D-penicillaminato(1-)-2:3κ^2S:S]tetrakis[μ_2-D-penicillaminato(2-)]-1:2κ^3N,S:S;1:6κ^3N,S:S;3:4κ^3S:N,S;4:5κ^3N,S:S-2,3,5,6-tetragold(I)-1,4-dinickel(II) ethanol monosolvate decahydrate

International Union of Crystallography

英語

text

2010-06

https://doi.org/10.1107/S0108270110016550

http://onlinelibrary.wiley.com/doi/10.1107/S0108270110016550/abstract

In the crystal structure of the title compound, K_4[Au_4Ni_2(C_6H_8NO_4S)(C_5H_9NO_2S)_4(C_5H_<10>NO_2S)]·C_2H_6O·10H_2O, (I), two planar [Ni(C_5H_9NO_2S)_2]^<2−> units are spanned by [Au_2(C_5H_<10>NO_2S)]^+ and [Au_2(C_6H_8NO_4S)]^− linkers through S atoms, forming an S:S-bridged Au^<I>_<4>Ni^<II>_<2> hexanuclear complex anion. One of six organic ligands in the complex anion is a carbamino derivative of d-penicillamine (3-mercaptovaline) and the others are deprotonated d-penicillamines. Each complex anion binds to nine K^+ ions through six carboxylate and one carbamino groups to construct a three-dimensional structure.

54381

Tetrapotassium [μ_2-N-carboxylato-D-penicillaminato(3-)-5:6κ^2S:S][μ_2-D-penicillaminato(1-)-2:3κ^2S:S]tetrakis[μ_2-D-penicillaminato(2-)]-1:2κ^3N,S:S;1:6κ^3N,S:S;3:4κ^3S:N,S;4:5κ^3N,S:S-2,3,5,6-tetragold(I)-1,4-dinickel(II) ethanol monosolvate decahydrate

International Union of Crystallography

英語

2010-06

Acta Crystallographica Section C

66

6

m160

m162

https://doi.org/10.1107/S0108270110016550

https://hdl.handle.net/11094/54381

http://onlinelibrary.wiley.com/doi/10.1107/S0108270110016550/abstract