An optically resolved crystal of thiomalate : (S)-1-phenylethanaminium (R)-thiomalate

Igawa, Kosuke; Yoshinari, Nobuto; Konno, Takumi

doi:info:doi/10.1107/S0108270112032933

このアイテムのアクセス数:27件（2018-05-21 12:07 集計）

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タイトル	An optically resolved crystal of thiomalate : (S)-1-phenylethanaminium (R)-thiomalate
著者	Igawa, Kosuke Igawa, Kosuke
	Yoshinari, Nobuto Yoshinari, Nobuto
	Konno, Takumi Konno, Takumi
抄録	The asymmetric unit of the optically resolved title salt, C_8H_<12>N+·C_4H_5O_4S^−, contains a 1-phenylethanaminium monocation and a thiomalate (3-carboxy-2-sulfanylpropanoate) monoanion. The absolute configurations of the cation and the anion are determined to be S and R, respectively. In the crystal, cation–anion N—H...O hydrogen bonds, together with anion–anion O—H...O and S—H...O hydrogen bonds, construct a two-dimensional supramolecular sheet parallel to the ab plane. The two-dimensional sheet is linked with the upper and lower sheets through C—H...π interactions to stack along the c axis.
公開者	International Union of Crystallography
掲載誌名	Acta Crystallographica Section C
巻	68
号	9
開始ページ	o332
終了ページ	o334
刊行年月	2012-09
ISSN	01082701
DOI	info:doi/10.1107/S0108270112032933
URL	http://hdl.handle.net/11094/54382
関連情報 (references)	http://onlinelibrary.wiley.com/doi/10.1107/S0108270112032933/abstract
言語	英語

著者版フラグ	publisher
NII資源タイプ	学術雑誌論文
ローカル資源タイプ	学術雑誌論文
dcmi資源タイプ	text
DCTERMS.bibliographicCitation	Acta Crystallographica Section C.68(9) P.o332-P.o334
DC.title	An optically resolved crystal of thiomalate : (S)-1-phenylethanaminium (R)-thiomalate
DC.creator	Igawa, Kosuke
	Yoshinari, Nobuto
	Konno, Takumi
DC.publisher	International Union of Crystallography
DC.language" scheme="DCTERMS.RFC1766	英語
DCTERMS.issued" scheme="DCTERMS.W3CDTF	2012-09
DC.identifier	info:doi/10.1107/S0108270112032933
DC.identifier" scheme="DCTERMS.URI	http://hdl.handle.net/11094/54382
DCTERMS.abstract	The asymmetric unit of the optically resolved title salt, C_8H_<12>N+·C_4H_5O_4S^−, contains a 1-phenylethanaminium monocation and a thiomalate (3-carboxy-2-sulfanylpropanoate) monoanion. The absolute configurations of the cation and the anion are determined to be S and R, respectively. In the crystal, cation–anion N—H...O hydrogen bonds, together with anion–anion O—H...O and S—H...O hydrogen bonds, construct a two-dimensional supramolecular sheet parallel to the ab plane. The two-dimensional sheet is linked with the upper and lower sheets through C—H...π interactions to stack along the c axis.
citation_title	An optically resolved crystal of thiomalate : (S)-1-phenylethanaminium (R)-thiomalate
citation_author	Igawa, Kosuke
	Yoshinari, Nobuto
	Konno, Takumi
citation_publisher	International Union of Crystallography
citation_language	英語
citation_date	2012-09
citation_journal_title	Acta Crystallographica Section C
citation_volume	68
citation_issue	9
citation_firstpage	o332
citation_lastpage	o334
citation_issn	01082701
citation_doi	info:doi/10.1107/S0108270112032933
citation_public_url	http://hdl.handle.net/11094/54382

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