Nickel phosphide nanoalloy catalyst for the selective deoxygenation of sulfoxides to sulfides under ambient H₂ pressure

Fujita, Shu; Yamaguchi, Sho; Yamazoe, Seiji; Yamasaki, Jun; Mizugaki, Tomoo; Mitsudome, Takato

doi:https://doi.org/10.1039/d0ob01603a

Nickel phosphide nanoalloy catalyst for the selective deoxygenation of sulfoxides to sulfides under ambient H₂ pressure

Fujita, Shu; Yamaguchi, Sho; Yamazoe, Seiji et al.

Organic and Biomolecular Chemistry, 2020, 18(43), 8827-8833

アクセス数:283件（2025-04-17 05:37 集計）

固定URL: https://hdl.handle.net/11094/78257

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タイトル	Nickel phosphide nanoalloy catalyst for the selective deoxygenation of sulfoxides to sulfides under ambient H₂ pressure
著者	著者名 Fujita, Shu
	NRID 1000050700150 1000050700150 researchmap permalink 7000018077 7000018077 Scopus Author ID 56424690000 56424690000 著者名 Yamaguchi, Sho
	NRID 1000040510243 1000040510243 著者名 Yamazoe, Seiji
	NRID 1000040335071 1000040335071 researchmap permalink read0054882 read0054882 Scopus Author ID 7006278028 7006278028 著者名 Yamasaki, Jun
	NRID 1000050314406 1000050314406 ORCID 0000-0001-5701-7530 0000-0001-5701-7530 researchmap permalink read0054694 read0054694 Scopus Author ID 7003481890 7003481890 著者名 Mizugaki, Tomoo
	NRID 1000000437360 1000000437360 ORCID 0000-0003-3071-8243 0000-0003-3071-8243 researchmap permalink read0107411 read0107411 Scopus Author ID 11240122700 11240122700 著者名 Mitsudome, Takato
内容	Reproduced from Org. Biomol. Chem., 2020,18, 8827-8833 with permission from the Royal Society of Chemistry.
抄録	Exploring novel catalysis by less common, metal-non-metal nanoalloys is of great interest in organic synthesis. We herein report a titanium-dioxide-supported nickel phosphide nanoalloy (nano-Ni₂P/TiO₂) that exhibits high catalytic activity for the deoxygenation of sulfoxides. nano-Ni₂P/TiO₂ deoxygenated various sulfoxides to sulfides under 1 bar of H₂, representing the first non-noble metal catalyst for sulfoxide deoxygenation under ambient H₂ pressure. Spectroscopic analyses revealed that this high activity is due to cooperative catalysis by nano-Ni₂P and TiO₂.
出版者	Royal Society of Chemistry
収録物名	Organic and Biomolecular Chemistry
巻(号)	18(43)
ページ	8827-8833
刊行年月	2020-11-21
言語	英語
ハンドルURL	https://hdl.handle.net/11094/78257
PISSN	14770520
NCID	AA1168650X
関連情報 (isVersionOf)	DOI (出版社版) https://doi.org/10.1039/d0ob01603a
関連情報 (isIdenticalTo)	PMID 33179696
アクセス権	open access
出版タイプ	Accepted Manuscript
カテゴリ	学術雑誌論文 Journal Article

資源タイプ	学術雑誌論文
ローカル資源タイプ	学術雑誌論文
DCMI資源タイプ	text
DCTERMS.bibliographicCitation	Organic and Biomolecular Chemistry. 2020, 18(43), p. 8827-8833
DC.title	Nickel phosphide nanoalloy catalyst for the selective deoxygenation of sulfoxides to sulfides under ambient H₂ pressure
DC.creator	Fujita, Shu
	Yamaguchi, Sho
	Yamazoe, Seiji
	Yamasaki, Jun
	Mizugaki, Tomoo
	Mitsudome, Takato
DC.publisher	Royal Society of Chemistry
DC.language' scheme='DCTERMS.RFC1766	英語
DC.type' scheme='DCTERMS.DCMIType	text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2020-11-21
DC.identifier	https://doi.org/10.1039/d0ob01603a
DC.description	Reproduced from Org. Biomol. Chem., 2020,18, 8827-8833 with permission from the Royal Society of Chemistry.
DCTERMS.abstract	Exploring novel catalysis by less common, metal-non-metal nanoalloys is of great interest in organic synthesis. We herein report a titanium-dioxide-supported nickel phosphide nanoalloy (nano-Ni₂P/TiO₂) that exhibits high catalytic activity for the deoxygenation of sulfoxides. nano-Ni₂P/TiO₂ deoxygenated various sulfoxides to sulfides under 1 bar of H₂, representing the first non-noble metal catalyst for sulfoxide deoxygenation under ambient H₂ pressure. Spectroscopic analyses revealed that this high activity is due to cooperative catalysis by nano-Ni₂P and TiO₂.
DC.format	78257
citation_title	Nickel phosphide nanoalloy catalyst for the selective deoxygenation of sulfoxides to sulfides under ambient H₂ pressure
citation_author	Fujita, Shu
	Yamaguchi, Sho
	Yamazoe, Seiji
	Yamasaki, Jun
	Mizugaki, Tomoo
	Mitsudome, Takato
citation_publisher	Royal Society of Chemistry
citation_language	英語
citation_date	2020-11-21
citation_journal_title	Organic and Biomolecular Chemistry
citation_volume	18
citation_issue	43
citation_firstpage	8827
citation_lastpage	8833
citation_doi	https://doi.org/10.1039/d0ob01603a
citation_pmid	33179696
citation_public_url	https://hdl.handle.net/11094/78257

Nickel phosphide nanoalloy catalyst for the selective deoxygenation of sulfoxides to sulfides under ambient H₂ pressure

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