Air-Stable and Reusable Cobalt Phosphide Nanoalloy Catalyst for Selective Hydrogenation of Furfural Derivatives

Ishikawa, Hiroya; Sheng, Min; Nakata, Ayako; Nakajima, Kiyotaka; Yamazoe, Seiji; Yamasaki, Jun; Yamaguchi, Sho; Mizugaki, Tomoo; Mitsudome, Takato

doi:https://doi.org/10.1021/acscatal.0c03300

Air-Stable and Reusable Cobalt Phosphide Nanoalloy Catalyst for Selective Hydrogenation of Furfural Derivatives

Ishikawa, Hiroya; Sheng, Min; Nakata, Ayako et al.

ACS Catalysis, 2021, 11(2), 750-757

アクセス数:339件（2025-04-17 05:38 集計）

固定URL: https://hdl.handle.net/11094/78258

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タイトル	Air-Stable and Reusable Cobalt Phosphide Nanoalloy Catalyst for Selective Hydrogenation of Furfural Derivatives
著者	著者名 Ishikawa, Hiroya
	著者名 Sheng, Min
	NRID 1000020595152 1000020595152 著者名 Nakata, Ayako
	NRID 1000090451997 1000090451997 著者名 Nakajima, Kiyotaka
	NRID 1000040510243 1000040510243 著者名 Yamazoe, Seiji
	NRID 1000040335071 1000040335071 researchmap permalink read0054882 read0054882 Scopus Author ID 7006278028 7006278028 著者名 Yamasaki, Jun
	NRID 1000050700150 1000050700150 researchmap permalink 7000018077 7000018077 Scopus Author ID 56424690000 56424690000 著者名 Yamaguchi, Sho
	NRID 1000050314406 1000050314406 ORCID 0000-0001-5701-7530 0000-0001-5701-7530 researchmap permalink read0054694 read0054694 Scopus Author ID 7003481890 7003481890 著者名 Mizugaki, Tomoo
	NRID 1000000437360 1000000437360 ORCID 0000-0003-3071-8243 0000-0003-3071-8243 researchmap permalink read0107411 read0107411 Scopus Author ID 11240122700 11240122700 著者名 Mitsudome, Takato
内容	Hiroya Ishikawa, Min Sheng, Ayako Nakata, Kiyotaka Nakajima, Seiji Yamazoe, Jun Yamasaki, Sho Yamaguchi, Tomoo Mizugaki, and Takato Mitsudome. Air-Stable and Reusable Cobalt Phosphide Nanoalloy Catalyst for Selective Hydrogenation of Furfural Derivatives. ACS Catalysis 2021, 11, 750-757, DOI: 10.1021/acscatal.0c03300.
内容	This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in ACS Catalysis, copyright © American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/acscatal.0c03300.
抄録	While metal phosphides have begun to attract attention as electrocatalysts, they remain underutilized in the field of liquid-phase molecular transformations. Herein, we describe a supported cobalt phosphide nanoalloy (nano-Co₂P) that functions as a highly efficient, reusable heterogeneous catalyst for the selective hydrogenation of furfural derivatives. The carbonyl moieties of several furfural derivatives were selectively hydrogenated to produce the desired products in high yields. In contrast to conventional nonprecious metal catalysts, nano-Co₂P uniquely exhibited air stability, which enabled easy and safe handling and precluded the need for H₂ pretreatment. Infrared and density functional theory studies revealed that the highly efficient hydrogenation is due to the favorable activation of the carbonyl moiety of furfural derivatives through the backdonation to its π* orbital from the Co d-electrons.
出版者	American Chemical Society (ACS)
収録物名	ACS Catalysis
巻(号)	11(2)
ページ	750-757
刊行年月	2021-01-15
言語	英語
ハンドルURL	https://hdl.handle.net/11094/78258
eISSN	21555435
NCID	AA12599706
関連情報 (isVersionOf)	DOI (出版社版) https://doi.org/10.1021/acscatal.0c03300
アクセス権	open access
権利情報	© American Chemical Society
出版タイプ	Accepted Manuscript
カテゴリ	学術雑誌論文 Journal Article

資源タイプ	学術雑誌論文
ローカル資源タイプ	学術雑誌論文
DCMI資源タイプ	text
DCTERMS.bibliographicCitation	ACS Catalysis. 2021, 11(2), p. 750-757
DC.title	Air-Stable and Reusable Cobalt Phosphide Nanoalloy Catalyst for Selective Hydrogenation of Furfural Derivatives
DC.creator	Ishikawa, Hiroya
	Sheng, Min
	Nakata, Ayako
	Nakajima, Kiyotaka
	Yamazoe, Seiji
	Yamasaki, Jun
	Yamaguchi, Sho
	Mizugaki, Tomoo
	Mitsudome, Takato
DC.publisher	American Chemical Society (ACS)
DC.language' scheme='DCTERMS.RFC1766	英語
DC.type' scheme='DCTERMS.DCMIType	text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2021-01-15
DC.identifier	https://doi.org/10.1021/acscatal.0c03300
DC.description	Hiroya Ishikawa, Min Sheng, Ayako Nakata, Kiyotaka Nakajima, Seiji Yamazoe, Jun Yamasaki, Sho Yamaguchi, Tomoo Mizugaki, and Takato Mitsudome. Air-Stable and Reusable Cobalt Phosphide Nanoalloy Catalyst for Selective Hydrogenation of Furfural Derivatives. ACS Catalysis 2021, 11, 750-757, DOI: 10.1021/acscatal.0c03300.
DC.description	This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in ACS Catalysis, copyright © American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/acscatal.0c03300.
DCTERMS.abstract	While metal phosphides have begun to attract attention as electrocatalysts, they remain underutilized in the field of liquid-phase molecular transformations. Herein, we describe a supported cobalt phosphide nanoalloy (nano-Co₂P) that functions as a highly efficient, reusable heterogeneous catalyst for the selective hydrogenation of furfural derivatives. The carbonyl moieties of several furfural derivatives were selectively hydrogenated to produce the desired products in high yields. In contrast to conventional nonprecious metal catalysts, nano-Co₂P uniquely exhibited air stability, which enabled easy and safe handling and precluded the need for H₂ pretreatment. Infrared and density functional theory studies revealed that the highly efficient hydrogenation is due to the favorable activation of the carbonyl moiety of furfural derivatives through the backdonation to its π* orbital from the Co d-electrons.
DC.rights	© American Chemical Society
DC.format	78258
citation_title	Air-Stable and Reusable Cobalt Phosphide Nanoalloy Catalyst for Selective Hydrogenation of Furfural Derivatives
citation_author	Ishikawa, Hiroya
	Sheng, Min
	Nakata, Ayako
	Nakajima, Kiyotaka
	Yamazoe, Seiji
	Yamasaki, Jun
	Yamaguchi, Sho
	Mizugaki, Tomoo
	Mitsudome, Takato
citation_publisher	American Chemical Society (ACS)
citation_language	英語
citation_date	2021-01-15
citation_journal_title	ACS Catalysis
citation_volume	11
citation_issue	2
citation_firstpage	750
citation_lastpage	757
citation_doi	https://doi.org/10.1021/acscatal.0c03300
citation_public_url	https://hdl.handle.net/11094/78258

Air-Stable and Reusable Cobalt Phosphide Nanoalloy Catalyst for Selective Hydrogenation of Furfural Derivatives

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