学術雑誌論文

学術雑誌論文

text

Physical Review Materials. 2019, 3(4)

Diffusionless isothermal omega transformation in titanium alloys driven by quenched-in compositional fluctuations

American Physical Society

英語

text

2019-04-16

https://doi.org/10.1103/PhysRevMaterials.3.043604

Tane M., Nishiyama H., Umeda A., et al. Diffusionless isothermal omega transformation in titanium alloys driven by quenched-in compositional fluctuations. Physical Review Materials 3, 043604 (2019); https://doi.org/10.1103/PhysRevMaterials.3.043604.

In titanium alloys, the ω(hexagonal)-phase transformation has been categorized as either a diffusion-mediated isothermal transformation or an athermal transformation that occurs spontaneously via a diffusionless mechanism. Here we report a diffusionless isothermal ω transformation that can occur even above the ω transformation temperature. In body-centered cubic β-titanium alloyed with β-stabilizing elements, there are locally unstable regions having fewer β-stabilizing elements owing to quenched-in compositional fluctuations that are inevitably present in thermal equilibrium. In these locally unstable regions, diffusionless isothermal ω transformation occurs even when the entire β region is stable on average so that athermal ω transformation cannot occur. This anomalous, localized transformation originates from the fluctuation-driven localized softening of 2/3[111]β longitudinal phonon, which cannot be suppressed by the stabilization of β phase on average. In the diffusionless isothermal and athermal ω transformations, the transformation rate is dominated by two activation processes: a dynamical collapse of {111}β pairs, caused by the phonon softening, and a nucleation process. In the diffusionless isothermal transformation, the ω-phase nucleation, resulting from the localized phonon softening, requires relatively high activation energy owing to the coherent β/ω interface. Thus, the transformation occurs at slower rates than the athermal transformation, which occurs by the widely spread phonon softening. Consequently, the nucleation probability reflecting the β/ω interface energy is the rate-determining process in the diffusionless ω transformations.

Copyright (2019) by the American Physical Society

89929

Diffusionless isothermal omega transformation in titanium alloys driven by quenched-in compositional fluctuations

American Physical Society

英語

2019-04-16

Physical Review Materials

3

4

https://doi.org/10.1103/PhysRevMaterials.3.043604

https://hdl.handle.net/11094/89929