学術雑誌論文

学術雑誌論文

text

Inorganic Chemistry. 2023, 62(24), p. 9291-9294

Silver(I) Sulfide Clusters Protected by Rhodium(III) Metalloligands with 3-Aminopropanethiolate

American Chemical Society

英語

text

2023-06-19

https://doi.org/10.1021/acs.inorgchem.3c01309

Yoshinari N., Goo Z.L., Nomura K., et al. Silver(I) Sulfide Clusters Protected by Rhodium(III) Metalloligands with 3-Aminopropanethiolate. Inorganic Chemistry 62(24), 9291-9294, 19 June 2023, © 2023 American Chemical Society. DOI: 10.1021/acs.inorgchem.3c01309.

The two homochiral AgIRhIII nanoclusters, Δ6/Λ6-[Ag11S{Rh(apt)3}6]9+ ([1]9+) and Δ6/Λ6-[Ag13S{Rh(apt)3}6]11+ ([2]11+), in which Ag11S and Ag13S cluster cores, respectively, are protected by fac-[Rh(apt)3] metalloligands, were newly synthesized from fac-[Rh(apt)3] (Hapt = 3-aminopropanethiol) and Ag+ in water in combination with sulfide sources. While [1]9+ was produced by using d-penicillamine as a sulfide source, the use of HS- as a sulfide source afforded [2]11+ without causing any precipitation of Ag2S. Cluster [1]9+ was convertible to [2]11+ via the reaction with Ag+, which led to a turn-on-type switch in photoluminescence from nonemissive [1]9+ to emissive [2]11+

This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Inorganic Chemistry, copyright © American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.3c01309.

92439

Silver(I) Sulfide Clusters Protected by Rhodium(III) Metalloligands with 3-Aminopropanethiolate

American Chemical Society

英語

2023-06-19

Inorganic Chemistry

62

24

9291

9294

https://doi.org/10.1021/acs.inorgchem.3c01309

https://hdl.handle.net/11094/92439