Room-Temperature Reversible Chemisorption of Carbon Monoxide on Nickel(0) Complexes

Yamauchi, Yasuhiro; Hoshimoto, Yoichi; Kawakita, Takahiro; Kinoshita, Takuya; Uetake, Yuta; Sakurai, Hidehiro; Ogoshi, Sensuke

doi:https://doi.org/10.1021/jacs.2c02870

Room-Temperature Reversible Chemisorption of Carbon Monoxide on Nickel(0) Complexes

Yamauchi, Yasuhiro; Hoshimoto, Yoichi; Kawakita, Takahiro et al.

Journal of the American Chemical Society, 2022, 144(19), 8818-8826

アクセス数:1,069件（2025-07-26 22:21 集計）

固定URL: https://hdl.handle.net/11094/92548

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タイトル	Room-Temperature Reversible Chemisorption of Carbon Monoxide on Nickel(0) Complexes
著者	著者名 Yamauchi, Yasuhiro
	NRID 1000030710074 1000030710074 ORCID 0000-0003-0882-6109 0000-0003-0882-6109 researchmap permalink YHoshimoto YHoshimoto Scopus Author ID 36463455400 36463455400 著者名 Hoshimoto, Yoichi
	著者名 Kawakita, Takahiro
	著者名 Kinoshita, Takuya
	NRID 1000010755440 1000010755440 ORCID 0000-0002-4742-8085 0000-0002-4742-8085 researchmap permalink yutauetake yutauetake Scopus Author ID 56417952700 56417952700 著者名 Uetake, Yuta
	NRID 1000000262147 1000000262147 ORCID 0000-0001-5783-4151 0000-0001-5783-4151 researchmap permalink read0184917 read0184917 Scopus Author ID 7402869823 7402869823 著者名 Sakurai, Hidehiro
	NRID 1000030252589 1000030252589 researchmap permalink read0042792 read0042792 Scopus Author ID 7005303403 7005303403 著者名 Ogoshi, Sensuke
キーワード等	Adsorption
	Desorption
	Inorganic carbon compounds
	Ligands
	Oxides
内容	Yamauchi Y., Hoshimoto Y., Kawakita T., et al. Room-Temperature Reversible Chemisorption of Carbon Monoxide on Nickel(0) Complexes. Journal of the American Chemical Society , (2022); https://doi.org/10.1021/jacs.2c02870.
抄録	Chemisorption on organometallic-based adsorbents is crucial for the controlled separation and long-term storage of gaseous molecules. The formation of covalent bonds between the metal centers in the adsorbents and the targeted gases affects the desorption efficiency, especially when the oxidation state of the metal is low. Herein, we report a pressure-responsive nickel(0)-based system that is able to reversibly chemisorb carbon monoxide (CO) at room temperature. The use of N-heterocyclic carbene ligands with hemi-labile N-phosphine oxide substituents facilitates both the adsorption and desorption of CO on nickel(0) via ligand substitution. Ionic liquids were used as the reaction medium to enhance the desorption rate and establish a reusable system. These results showcase a way for the sustainable chemisorption of CO using a zero-valent transition-metal complex.
出版者	American Chemical Society
収録物名	Journal of the American Chemical Society
巻(号)	144(19)
ページ	8818-8826
刊行年月	2022-05-03
言語	英語
ハンドルURL	https://hdl.handle.net/11094/92548
PISSN	00027863
eISSN	15205126
NCID	AA12097173
関連情報 (isIdenticalTo)	DOI (出版社版) https://doi.org/10.1021/jacs.2c02870
アクセス権	open access
権利情報	© 2022 The Authors. Published by American Chemical Society.
権利情報	This article is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
出版タイプ	Version of Record
カテゴリ	学術雑誌論文 Journal Article

資源タイプ	学術雑誌論文
ローカル資源タイプ	学術雑誌論文
DCMI資源タイプ	text
DCTERMS.bibliographicCitation	Journal of the American Chemical Society. 2022, 144(19), p. 8818-8826
DC.title	Room-Temperature Reversible Chemisorption of Carbon Monoxide on Nickel(0) Complexes
DC.creator	Yamauchi, Yasuhiro
	Hoshimoto, Yoichi
	Kawakita, Takahiro
	Kinoshita, Takuya
	Uetake, Yuta
	Sakurai, Hidehiro
	Ogoshi, Sensuke
DC.publisher	American Chemical Society
DC.language' scheme='DCTERMS.RFC1766	英語
DC.type' scheme='DCTERMS.DCMIType	text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2022-05-03
DC.identifier	https://doi.org/10.1021/jacs.2c02870
DC.subject	Adsorption
	Desorption
	Inorganic carbon compounds
	Ligands
	Oxides
DC.description	Yamauchi Y., Hoshimoto Y., Kawakita T., et al. Room-Temperature Reversible Chemisorption of Carbon Monoxide on Nickel(0) Complexes. Journal of the American Chemical Society , (2022); https://doi.org/10.1021/jacs.2c02870.
DCTERMS.abstract	Chemisorption on organometallic-based adsorbents is crucial for the controlled separation and long-term storage of gaseous molecules. The formation of covalent bonds between the metal centers in the adsorbents and the targeted gases affects the desorption efficiency, especially when the oxidation state of the metal is low. Herein, we report a pressure-responsive nickel(0)-based system that is able to reversibly chemisorb carbon monoxide (CO) at room temperature. The use of N-heterocyclic carbene ligands with hemi-labile N-phosphine oxide substituents facilitates both the adsorption and desorption of CO on nickel(0) via ligand substitution. Ionic liquids were used as the reaction medium to enhance the desorption rate and establish a reusable system. These results showcase a way for the sustainable chemisorption of CO using a zero-valent transition-metal complex.
DC.rights	© 2022 The Authors. Published by American Chemical Society.
DC.rights	This article is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
DC.format	92548
citation_title	Room-Temperature Reversible Chemisorption of Carbon Monoxide on Nickel(0) Complexes
citation_author	Yamauchi, Yasuhiro
	Hoshimoto, Yoichi
	Kawakita, Takahiro
	Kinoshita, Takuya
	Uetake, Yuta
	Sakurai, Hidehiro
	Ogoshi, Sensuke
citation_publisher	American Chemical Society
citation_language	英語
citation_date	2022-05-03
citation_journal_title	Journal of the American Chemical Society
citation_volume	144
citation_issue	19
citation_firstpage	8818
citation_lastpage	8826
citation_doi	https://doi.org/10.1021/jacs.2c02870
citation_public_url	https://hdl.handle.net/11094/92548

Room-Temperature Reversible Chemisorption of Carbon Monoxide on Nickel(0) Complexes

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