Synthesis of DPPP- And DPPPEN-Type Bidentate Ligands by Ring-Opening Diphosphination of Methylene- And Vinylcyclopropanes under Visible-Light-Promoted Photoredox Catalysis

Kato, Yugo; Otomura, Nobutaka; Hirano, Koji et al.

Journal of Organic Chemistry, 2020, 85(9), 5981-5994

アクセス数:368件（2025-08-28 19:40 集計）

固定URL: https://hdl.handle.net/11094/92702

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タイトル
Synthesis of DPPP- And DPPPEN-Type Bidentate Ligands by Ring-Opening Diphosphination of Methylene- And Vinylcyclopropanes under Visible-Light-Promoted Photoredox Catalysis
著者
著者名
Kato, Yugo
著者名
Otomura, Nobutaka
NRID
1000070532696 1000070532696
ORCID
0000-0001-9752-1985 0000-0001-9752-1985
researchmap permalink
koj koj
Scopus Author ID
7402407063 7402407063
著者名
Hirano, Koji
NRID
1000020183626 1000020183626
ORCID
0000-0001-8288-6439 0000-0001-8288-6439
researchmap permalink
read0013936 read0013936
Scopus Author ID
7402799909 7402799909
著者名
Miura, Masahiro
内容
Kato Y., Otomura N., Hirano K., et al. Synthesis of DPPP- And DPPPEN-Type Bidentate Ligands by Ring-Opening Diphosphination of Methylene- And Vinylcyclopropanes under Visible-Light-Promoted Photoredox Catalysis. Journal of Organic Chemistry. 85(9), 5981-5994, (2020), 1 May 2020; © 2020 American Chemical Society. https://doi.org/10.1021/acs.joc.0c00417.
抄録
A ring-opening diphosphination of methylene- and vinylcyclopropanes with tetraaryldiphosphines (Ar2P-PAr2) has been developed to afford the corresponding 1,3-diphenylphosphinopropane- and 1,3-diphenylphosphinopentane-type bidentate ligands, respectively. The reaction proceeds under bromine cation-initiated, visible-light-promoted photoredox catalysis at ambient temperature. Owing to the ready availability of functionalized diphosphines, the electronically diverse MeO- and CF3-substituted bidentate ligands are also easily prepared.
出版者
American Chemical Societyservice@acs.org
収録物名
Journal of Organic Chemistry
巻(号)
85(9)
ページ
5981-5994
刊行年月
2020-05-01
言語
英語
ハンドルURL
https://hdl.handle.net/11094/92702
PISSN
00223263
eISSN
15206904
関連情報 (isVersionOf)
DOI (出版社版)
https://doi.org/10.1021/acs.joc.0c00417
アクセス権
open access
権利情報
© 2020 American Chemical Society.
This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in, Journal of Organic Chemistry, copyright © American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/acs.joc.0c00417.
出版タイプ
Accepted Manuscript
カテゴリ
学術雑誌論文 Journal Article