Direct Synthesis of Dibenzophospholes from Biaryls by Double C-P Bond Formation via Phosphenium Dication Equivalents

Nishimura, Kazutoshi; Hirano, Koji; Miura, Masahiro

doi:https://doi.org/10.1021/acs.orglett.0c00944

Direct Synthesis of Dibenzophospholes from Biaryls by Double C-P Bond Formation via Phosphenium Dication Equivalents

Nishimura, Kazutoshi; Hirano, Koji; Miura, Masahiro

Organic Letters, 2020, 22(8), 3185-3189

アクセス数:343件（2025-08-28 17:22 集計）

固定URL: https://hdl.handle.net/11094/92703

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タイトル	Direct Synthesis of Dibenzophospholes from Biaryls by Double C-P Bond Formation via Phosphenium Dication Equivalents
著者	著者名 Nishimura, Kazutoshi
	NRID 1000070532696 1000070532696 ORCID 0000-0001-9752-1985 0000-0001-9752-1985 researchmap permalink koj koj Scopus Author ID 7402407063 7402407063 著者名 Hirano, Koji
	NRID 1000020183626 1000020183626 ORCID 0000-0001-8288-6439 0000-0001-8288-6439 researchmap permalink read0013936 read0013936 Scopus Author ID 7402799909 7402799909 著者名 Miura, Masahiro
内容	Nishimura K., Hirano K., Miura M.. Direct Synthesis of Dibenzophospholes from Biaryls by Double C-P Bond Formation via Phosphenium Dication Equivalents. Organic Letters. 22(8), 3185-3189, (2020), 17 April 2020; © 2020 American Chemical Society. https://doi.org/10.1021/acs.orglett.0c00944.
抄録	We have developed a new strategy for the generation of phosphenium dication equivalents from readily available phosphinic acids and Tf2O. The in situ-generated dication equivalents can be readily coupled with simple (hetero)biaryls to form the corresponding dibenzophospholes directly. This protocol can also be applied to the concise synthesis of six- A nd seven-membered phosphacycles as well as the largely Ï-extended heteroacene derivatives, which are of great interest in the field of organic functional materials.
出版者	American Chemical Societyservice@acs.org
収録物名	Organic Letters
巻(号)	22(8)
ページ	3185-3189
刊行年月	2020-04-17
言語	英語
ハンドルURL	https://hdl.handle.net/11094/92703
PISSN	15237060
eISSN	15237052
関連情報 (isVersionOf)	DOI (出版社版) https://doi.org/10.1021/acs.orglett.0c00944
アクセス権	open access
権利情報	© 2020 American Chemical Society.
権利情報	This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in, Organic Letters, copyright © American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.0c00944.
出版タイプ	Accepted Manuscript
カテゴリ	学術雑誌論文 Journal Article

資源タイプ	学術雑誌論文
ローカル資源タイプ	学術雑誌論文
DCMI資源タイプ	text
DCTERMS.bibliographicCitation	Organic Letters. 2020, 22(8), p. 3185-3189
DC.title	Direct Synthesis of Dibenzophospholes from Biaryls by Double C-P Bond Formation via Phosphenium Dication Equivalents
DC.creator	Nishimura, Kazutoshi
	Hirano, Koji
	Miura, Masahiro
DC.publisher	American Chemical Societyservice@acs.org
DC.language' scheme='DCTERMS.RFC1766	英語
DC.type' scheme='DCTERMS.DCMIType	text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2020-04-17
DC.identifier	https://doi.org/10.1021/acs.orglett.0c00944
DC.description	Nishimura K., Hirano K., Miura M.. Direct Synthesis of Dibenzophospholes from Biaryls by Double C-P Bond Formation via Phosphenium Dication Equivalents. Organic Letters. 22(8), 3185-3189, (2020), 17 April 2020; © 2020 American Chemical Society. https://doi.org/10.1021/acs.orglett.0c00944.
DCTERMS.abstract	We have developed a new strategy for the generation of phosphenium dication equivalents from readily available phosphinic acids and Tf2O. The in situ-generated dication equivalents can be readily coupled with simple (hetero)biaryls to form the corresponding dibenzophospholes directly. This protocol can also be applied to the concise synthesis of six- A nd seven-membered phosphacycles as well as the largely Ï-extended heteroacene derivatives, which are of great interest in the field of organic functional materials.
DC.rights	© 2020 American Chemical Society.
DC.rights	This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in, Organic Letters, copyright © American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.0c00944.
DC.format	92703
citation_title	Direct Synthesis of Dibenzophospholes from Biaryls by Double C-P Bond Formation via Phosphenium Dication Equivalents
citation_author	Nishimura, Kazutoshi
	Hirano, Koji
	Miura, Masahiro
citation_publisher	American Chemical Societyservice@acs.org
citation_language	英語
citation_date	2020-04-17
citation_journal_title	Organic Letters
citation_volume	22
citation_issue	8
citation_firstpage	3185
citation_lastpage	3189
citation_doi	https://doi.org/10.1021/acs.orglett.0c00944
citation_public_url	https://hdl.handle.net/11094/92703

Direct Synthesis of Dibenzophospholes from Biaryls by Double C-P Bond Formation via Phosphenium Dication Equivalents

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