A Proton Conductive Porous Framework of an 18-Crown-6-Ether Derivative Networked by Rigid Hydrogen Bonding Modules

Chen, Xin; Huang, Rui Kang; Takahashi, Kiyonori; Noro, Shin ichiro; Nakamura, Takayoshi; Hisaki, Ichiro

doi:https://doi.org/10.1002/anie.202211686

A Proton Conductive Porous Framework of an 18-Crown-6-Ether Derivative Networked by Rigid Hydrogen Bonding Modules

Chen, Xin; Huang, Rui Kang; Takahashi, Kiyonori et al.

Angewandte Chemie - International Edition, 2022, 61(45), e202211686

アクセス数:716件（2025-09-20 03:20 集計）

固定URL: https://hdl.handle.net/11094/92731

閲覧可能ファイル

ファイル	フォーマット	利用条件	サイズ	閲覧回数	利用開始日	説明	information
AngewChemIntEd_61_45	pdf	なし	1.63 MB	156	2023.11.07

論文情報

ファイル出力 EndNote Basic出力 Mendeley出力

タイトル	A Proton Conductive Porous Framework of an 18-Crown-6-Ether Derivative Networked by Rigid Hydrogen Bonding Modules
著者	著者名 Chen, Xin
	著者名 Huang, Rui Kang
	NRID 1000090812595 1000090812595 著者名 Takahashi, Kiyonori
	NRID 1000070373347 1000070373347 著者名 Noro, Shin ichiro
	NRID 1000060270790 1000060270790 著者名 Nakamura, Takayoshi
	NRID 1000090419466 1000090419466 ORCID 0000-0002-8170-5605 0000-0002-8170-5605 researchmap permalink Ichiro_Hisaki Ichiro_Hisaki Scopus Author ID 12801798700 12801798700 著者名 Hisaki, Ichiro
キーワード等	Crown Ether
	Crystal Engineering
	Hydrogen Bond
	Porous Framework
	Proton Conduction
内容	This is the accepted version of the following article:Chen X., Huang R.K., Takahashi K., et al. A Proton Conductive Porous Framework of an 18-Crown-6-Ether Derivative Networked by Rigid Hydrogen Bonding Modules. Angewandte Chemie - International Edition 61, e202211686 (2022), which has been published in final form at https://doi.org/10.1002/anie.202211686. This article may be used for non-commercialpurposes in accordance with the Wiley Self-ArchivingPolicy [https://authorservices.wiley.com/author-resources/Journal-Authors/licensing/self-archiving.html]
抄録	A rigid hydrogen-bonded organic framework (HOF) was constructed from a C3-symmetric hexatopic carboxylic acid with a hydrophilic 18-crown-6-ether (18C6) component. Despite the flexible macrocyclic structure with many conformations, the derivative with three 4,4’-dicarboxy-o-terphenyl moieties in the periphery yielded a rigid layered porous framework through directional intermolecular hydrogen bonding. Interestingly, the HOF possesses 1D channels with bottleneck composed of 18C6 rings. The HOF shows proton conductivity (1.12×10−7 S cm−1) through Grotthuss mechanism (Ea=0.27 eV) under 98 %RH. The present unique water channel structure provides an inspiration to create molecular porous materials.
出版者	John Wiley and Sons Inc
収録物名	Angewandte Chemie - International Edition
巻(号)	61(45)
ページ	e202211686
刊行年月	2022-11-07
言語	英語
ハンドルURL	https://hdl.handle.net/11094/92731
PISSN	14337851
eISSN	15213773
関連情報 (isVersionOf)	DOI (出版社版) https://doi.org/10.1002/anie.202211686
アクセス権	open access
権利情報	© 2022 Wiley-VCH Verlag GmbH & Co. KGaA.
出版タイプ	Accepted Manuscript
カテゴリ	学術雑誌論文 Journal Article

資源タイプ	学術雑誌論文
ローカル資源タイプ	学術雑誌論文
DCMI資源タイプ	text
DCTERMS.bibliographicCitation	Angewandte Chemie - International Edition. 2022, 61(45), p. e202211686
DC.title	A Proton Conductive Porous Framework of an 18-Crown-6-Ether Derivative Networked by Rigid Hydrogen Bonding Modules
DC.creator	Chen, Xin
	Huang, Rui Kang
	Takahashi, Kiyonori
	Noro, Shin ichiro
	Nakamura, Takayoshi
	Hisaki, Ichiro
DC.publisher	John Wiley and Sons Inc
DC.language' scheme='DCTERMS.RFC1766	英語
DC.type' scheme='DCTERMS.DCMIType	text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2022-11-07
DC.identifier	https://doi.org/10.1002/anie.202211686
DC.subject	Crown Ether
	Crystal Engineering
	Hydrogen Bond
	Porous Framework
	Proton Conduction
DC.description	This is the accepted version of the following article:Chen X., Huang R.K., Takahashi K., et al. A Proton Conductive Porous Framework of an 18-Crown-6-Ether Derivative Networked by Rigid Hydrogen Bonding Modules. Angewandte Chemie - International Edition 61, e202211686 (2022), which has been published in final form at https://doi.org/10.1002/anie.202211686. This article may be used for non-commercialpurposes in accordance with the Wiley Self-ArchivingPolicy [https://authorservices.wiley.com/author-resources/Journal-Authors/licensing/self-archiving.html]
DCTERMS.abstract	A rigid hydrogen-bonded organic framework (HOF) was constructed from a C3-symmetric hexatopic carboxylic acid with a hydrophilic 18-crown-6-ether (18C6) component. Despite the flexible macrocyclic structure with many conformations, the derivative with three 4,4’-dicarboxy-o-terphenyl moieties in the periphery yielded a rigid layered porous framework through directional intermolecular hydrogen bonding. Interestingly, the HOF possesses 1D channels with bottleneck composed of 18C6 rings. The HOF shows proton conductivity (1.12×10−7 S cm−1) through Grotthuss mechanism (Ea=0.27 eV) under 98 %RH. The present unique water channel structure provides an inspiration to create molecular porous materials.
DC.rights	© 2022 Wiley-VCH Verlag GmbH & Co. KGaA.
DC.format	92731
citation_title	A Proton Conductive Porous Framework of an 18-Crown-6-Ether Derivative Networked by Rigid Hydrogen Bonding Modules
citation_author	Chen, Xin
	Huang, Rui Kang
	Takahashi, Kiyonori
	Noro, Shin ichiro
	Nakamura, Takayoshi
	Hisaki, Ichiro
citation_publisher	John Wiley and Sons Inc
citation_language	英語
citation_date	2022-11-07
citation_journal_title	Angewandte Chemie - International Edition
citation_volume	61
citation_issue	45
citation_firstpage	e202211686
citation_doi	https://doi.org/10.1002/anie.202211686
citation_public_url	https://hdl.handle.net/11094/92731

A Proton Conductive Porous Framework of an 18-Crown-6-Ether Derivative Networked by Rigid Hydrogen Bonding Modules

閲覧可能ファイル

論文情報

論文詳細を表示