Copper-Mediated Decarboxylative C–H Arylation of Phenol Derivatives with ortho-Nitrobenzoic Acids Using Phenanthroline-Based Bidentate Auxiliary

Takamatsu, Kazutaka; Hayashi, Yoshihiro; Kawauchi, Susumu; Hirano, Koji; Miura, Masahiro

doi:https://doi.org/10.1002/slct.201902860

Copper-Mediated Decarboxylative C–H Arylation of Phenol Derivatives with ortho-Nitrobenzoic Acids Using Phenanthroline-Based Bidentate Auxiliary

Takamatsu, Kazutaka; Hayashi, Yoshihiro; Kawauchi, Susumu et al.

ChemistrySelect, 2019, 4(40), 11833-11838

アクセス数:190件（2025-08-28 19:40 集計）

固定URL: https://hdl.handle.net/11094/92736

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タイトル	Copper-Mediated Decarboxylative C–H Arylation of Phenol Derivatives with ortho-Nitrobenzoic Acids Using Phenanthroline-Based Bidentate Auxiliary
著者	著者名 Takamatsu, Kazutaka
	NRID 1000080739029 1000080739029 著者名 Hayashi, Yoshihiro
	NRID 1000080204676 1000080204676 著者名 Kawauchi, Susumu
	NRID 1000070532696 1000070532696 ORCID 0000-0001-9752-1985 0000-0001-9752-1985 researchmap permalink koj koj Scopus Author ID 7402407063 7402407063 著者名 Hirano, Koji
	NRID 1000020183626 1000020183626 ORCID 0000-0001-8288-6439 0000-0001-8288-6439 researchmap permalink read0013936 read0013936 Scopus Author ID 7402799909 7402799909 著者名 Miura, Masahiro
キーワード等	bidentate auxiliary
	copper
	C−H arylation
	decarboxylation
	phenols
内容	Takamatsu K., Hayashi Y., Kawauchi S., et al. Copper-Mediated Decarboxylative C–H Arylation of Phenol Derivatives with ortho-Nitrobenzoic Acids Using Phenanthroline-Based Bidentate Auxiliary. ChemistrySelect 4, 11833 (2019); https://doi.org/10.1002/slct.201902860.
抄録	A copper-mediated decarboxylative C–H arylation of phenol derivatives with ortho-nitrobenzoic acid salts via phenanthroline-directed C–H cleavage has been developed. The N,N-bidentate phenanthroline auxiliary uniquely promotes the reaction only in the presence of a copper salt to produce the corresponding biaryls in acceptable yields. Moreover, the directing group can be easily introduced and removed. Additionally, preliminary computational mechanistic studies with DFT have also been performed.
出版者	Wiley
収録物名	ChemistrySelect
巻(号)	4(40)
ページ	11833-11838
刊行年月	2019-10-25
言語	英語
ハンドルURL	https://hdl.handle.net/11094/92736
eISSN	23656549
関連情報 (isVersionOf)	DOI (出版社版) https://doi.org/10.1002/slct.201902860
アクセス権	open access
権利情報	© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
出版タイプ	Accepted Manuscript
カテゴリ	学術雑誌論文 Journal Article

資源タイプ	学術雑誌論文
ローカル資源タイプ	学術雑誌論文
DCMI資源タイプ	text
DCTERMS.bibliographicCitation	ChemistrySelect. 2019, 4(40), p. 11833-11838
DC.title	Copper-Mediated Decarboxylative C–H Arylation of Phenol Derivatives with ortho-Nitrobenzoic Acids Using Phenanthroline-Based Bidentate Auxiliary
DC.creator	Takamatsu, Kazutaka
	Hayashi, Yoshihiro
	Kawauchi, Susumu
	Hirano, Koji
	Miura, Masahiro
DC.publisher	Wiley
DC.language' scheme='DCTERMS.RFC1766	英語
DC.type' scheme='DCTERMS.DCMIType	text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2019-10-25
DC.identifier	https://doi.org/10.1002/slct.201902860
DC.subject	bidentate auxiliary
	copper
	C−H arylation
	decarboxylation
	phenols
DC.description	Takamatsu K., Hayashi Y., Kawauchi S., et al. Copper-Mediated Decarboxylative C–H Arylation of Phenol Derivatives with ortho-Nitrobenzoic Acids Using Phenanthroline-Based Bidentate Auxiliary. ChemistrySelect 4, 11833 (2019); https://doi.org/10.1002/slct.201902860.
DCTERMS.abstract	A copper-mediated decarboxylative C–H arylation of phenol derivatives with ortho-nitrobenzoic acid salts via phenanthroline-directed C–H cleavage has been developed. The N,N-bidentate phenanthroline auxiliary uniquely promotes the reaction only in the presence of a copper salt to produce the corresponding biaryls in acceptable yields. Moreover, the directing group can be easily introduced and removed. Additionally, preliminary computational mechanistic studies with DFT have also been performed.
DC.rights	© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
DC.format	92736
citation_title	Copper-Mediated Decarboxylative C–H Arylation of Phenol Derivatives with ortho-Nitrobenzoic Acids Using Phenanthroline-Based Bidentate Auxiliary
citation_author	Takamatsu, Kazutaka
	Hayashi, Yoshihiro
	Kawauchi, Susumu
	Hirano, Koji
	Miura, Masahiro
citation_publisher	Wiley
citation_language	英語
citation_date	2019-10-25
citation_journal_title	ChemistrySelect
citation_volume	4
citation_issue	40
citation_firstpage	11833
citation_lastpage	11838
citation_doi	https://doi.org/10.1002/slct.201902860
citation_public_url	https://hdl.handle.net/11094/92736

Copper-Mediated Decarboxylative C–H Arylation of Phenol Derivatives with ortho-Nitrobenzoic Acids Using Phenanthroline-Based Bidentate Auxiliary

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