Copper-Catalyzed Electrophilic Amination: An Umpolung Strategy for New CN Bond Formations

Hirano, Koji

Bulletin of the Chemical Society of Japan, 2023, 96(3), 198-207

アクセス数:276件（2025-08-28 17:22 集計）

固定URL: https://hdl.handle.net/11094/92800

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タイトル
Copper-Catalyzed Electrophilic Amination: An Umpolung Strategy for New CN Bond Formations
著者
NRID
1000070532696 1000070532696
ORCID
0000-0001-9752-1985 0000-0001-9752-1985
researchmap permalink
koj koj
Scopus Author ID
7402407063 7402407063
著者名
Hirano, Koji
キーワード等
Amination
Copper
Umpolung
抄録
The nitrogen atom is ubiquitous in bioactive molecules and functional materials, and the development of new CN bond forming strategies is thus one of the long-standing research subjects in the synthetic community. This account describes the nitrogen-umpolung-enabled copper-catalyzed highly chemo- and stereoselective amination protocols developed by the author’s research group. Starting from the CH amination, electrophilic amination of stable organoboron and organosilicon compounds, aminoboration/hydroamination of alkenes, and their applications to the synthesis of functionality-rich alkylamines are shown. The reaction design, concept, and substrate scope are briefly summarized.
出版者
Chemical Society of Japan
収録物名
Bulletin of the Chemical Society of Japan
巻(号)
96(3)
ページ
198-207
刊行年月
2023-03-01
言語
英語
ハンドルURL
https://hdl.handle.net/11094/92800
PISSN
00092673
eISSN
13480634
NCID
AA00580132
関連情報 (isVersionOf)
DOI (出版社版)
https://doi.org/10.1246/bcsj.20230003
アクセス権
open access
権利情報
© 2023 The Chemical Society of Japan.
出版タイプ
Accepted Manuscript
カテゴリ
学術雑誌論文 Journal Article