学術雑誌論文

学術雑誌論文

text

Journal of Organic Chemistry. 2022, 87(24), p. 16887-16894

Synthesis of Diarylselenides through Rh-Catalyzed Direct Diarylation of Elemental Selenium with Benzamides

American Chemical Society

英語

text

2022-12-16

https://doi.org/10.1021/acs.joc.2c02131

Xu-Xu Q.F., Nishii Y., Miura M.. Synthesis of Diarylselenides through Rh-Catalyzed Direct Diarylation of Elemental Selenium with Benzamides. Journal of Organic Chemistry. 87(24), 16887-16894, (2022), 16 December 2022; ©2022 American Chemical Society. https://doi.org/10.1021/acs.joc.2c02131.

Diarylselenides are a representative class of molecules in organoselenium compounds. We herein report a Rh-cata-lyzed direct diarylation of selenium with benzamide derivatives. The use of elemental selenium as the Se source is intriguing in the view of atom economy, cost, stability, and handling. A series of diarylselenides with amide moieties were readily accessible through the directed C–H activation. The intermediacy of electrophilic Se(IV) species was indicated by the control experiments.

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Organic Chemistry, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.joc.2c02131.

92806

Synthesis of Diarylselenides through Rh-Catalyzed Direct Diarylation of Elemental Selenium with Benzamides

American Chemical Society

英語

2022-12-16

Journal of Organic Chemistry

87

24

16887

16894

https://doi.org/10.1021/acs.joc.2c02131

https://hdl.handle.net/11094/92806