Cp*M-Catalyzed Direct Annulation with Terminal Alkynes and Their Surrogates for the Construction of Multi-Ring Systems

Nishii, Yuji; Miura, Masahiro

doi:https://doi.org/10.1021/acscatal.0c02972

Cp*M-Catalyzed Direct Annulation with Terminal Alkynes and Their Surrogates for the Construction of Multi-Ring Systems

Nishii, Yuji; Miura, Masahiro

ACS Catalysis, 2020, 10(17), 9747-9757

アクセス数:387件（2025-10-24 13:15 集計）

固定URL: https://hdl.handle.net/11094/92813

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タイトル	Cp*M-Catalyzed Direct Annulation with Terminal Alkynes and Their Surrogates for the Construction of Multi-Ring Systems
著者	NRID 1000070773787 1000070773787 ORCID 0000-0002-6824-0639 0000-0002-6824-0639 researchmap permalink y_nishii y_nishii Scopus Author ID 55233363700 55233363700 著者名 Nishii, Yuji
著者	NRID 1000020183626 1000020183626 ORCID 0000-0001-8288-6439 0000-0001-8288-6439 researchmap permalink read0013936 read0013936 Scopus Author ID 7402799909 7402799909 著者名 Miura, Masahiro
キーワード等	alkynes
	C-H functionalization
	cobalt
	cyclization
	iridium
	rhodium
内容	Nishii Y., Miura M.. Cp*M-Catalyzed Direct Annulation with Terminal Alkynes and Their Surrogates for the Construction of Multi-Ring Systems. ACS Catalysis. 10(17), 9747-9757, (2020), 4 September 2020; ©2020 American Chemical Society. https://doi.org/10.1021/acscatal.0c02972.
抄録	Transition-metal-catalyzed C–H activation followed by oxidative cyclization with unsaturated coupling partners has been a valuable synthetic tool for the multi-ring molecular scaffolds. This Perspective introduces the recent progress on the Cp*M-catalyzed (M = Co, Rh, and Ir) oxidative direct annulation of functionalized arenes with terminal alkynes and their equivalents through C–H bond cleavage. The highlighted examples are categorized according to the ten different types of reagents used in the transfor-mations. The representative conditions, selected examples of the reaction scope, and key mechanistic aspects are briefly summarized.
出版者	American Chemical Society
収録物名	ACS Catalysis
巻(号)	10(17)
ページ	9747-9757
刊行年月	2020-09-04
言語	英語
ハンドルURL	https://hdl.handle.net/11094/92813
eISSN	21555435
NCID	AA12599706
関連情報 (isVersionOf)	DOI (出版社版) https://doi.org/10.1021/acscatal.0c02972
アクセス権	open access
権利情報	This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acscatal.0c02972.
出版タイプ	Accepted Manuscript
カテゴリ	学術雑誌論文 Journal Article

資源タイプ	学術雑誌論文
ローカル資源タイプ	学術雑誌論文
DCMI資源タイプ	text
DCTERMS.bibliographicCitation	ACS Catalysis. 2020, 10(17), p. 9747-9757
DC.title	Cp*M-Catalyzed Direct Annulation with Terminal Alkynes and Their Surrogates for the Construction of Multi-Ring Systems
DC.creator	Nishii, Yuji
DC.creator	Miura, Masahiro
DC.publisher	American Chemical Society
DC.language' scheme='DCTERMS.RFC1766	英語
DC.type' scheme='DCTERMS.DCMIType	text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2020-09-04
DC.identifier	https://doi.org/10.1021/acscatal.0c02972
DC.subject	alkynes
	C-H functionalization
	cobalt
	cyclization
	iridium
	rhodium
DC.description	Nishii Y., Miura M.. Cp*M-Catalyzed Direct Annulation with Terminal Alkynes and Their Surrogates for the Construction of Multi-Ring Systems. ACS Catalysis. 10(17), 9747-9757, (2020), 4 September 2020; ©2020 American Chemical Society. https://doi.org/10.1021/acscatal.0c02972.
DCTERMS.abstract	Transition-metal-catalyzed C–H activation followed by oxidative cyclization with unsaturated coupling partners has been a valuable synthetic tool for the multi-ring molecular scaffolds. This Perspective introduces the recent progress on the Cp*M-catalyzed (M = Co, Rh, and Ir) oxidative direct annulation of functionalized arenes with terminal alkynes and their equivalents through C–H bond cleavage. The highlighted examples are categorized according to the ten different types of reagents used in the transfor-mations. The representative conditions, selected examples of the reaction scope, and key mechanistic aspects are briefly summarized.
DC.rights	This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acscatal.0c02972.
DC.format	92813
citation_title	Cp*M-Catalyzed Direct Annulation with Terminal Alkynes and Their Surrogates for the Construction of Multi-Ring Systems
citation_author	Nishii, Yuji
citation_author	Miura, Masahiro
citation_publisher	American Chemical Society
citation_language	英語
citation_date	2020-09-04
citation_journal_title	ACS Catalysis
citation_volume	10
citation_issue	17
citation_firstpage	9747
citation_lastpage	9757
citation_doi	https://doi.org/10.1021/acscatal.0c02972
citation_public_url	https://hdl.handle.net/11094/92813

Cp*M-Catalyzed Direct Annulation with Terminal Alkynes and Their Surrogates for the Construction of Multi-Ring Systems

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