Chemical Strategies for the Cleavage of the C(sp3)−F Bonds in Perfluoroalkyl Groups

Doi, Ryohei; Ogoshi, Sensuke

European Journal of Organic Chemistry, 2024, 27(11), e202301229

アクセス数:537件（2026-04-04 22:19 集計）

固定URL: https://hdl.handle.net/11094/95268

閲覧可能ファイル 

ファイル フォーマット 利用条件 サイズ 閲覧回数 利用開始日 説明 information
EurJOrgChem_27_11_e202301229 pdf なし 1.91 MB 333 2024.04.18  
Creative Commons : 表示

論文情報

ファイル出力 EndNote Basic出力 Mendeley出力

タイトル
Chemical Strategies for the Cleavage of the C(sp3)−F Bonds in Perfluoroalkyl Groups
著者
NRID
1000040780052 1000040780052
ORCID
0000-0001-8285-0209 0000-0001-8285-0209
researchmap permalink
ryoheidoi ryoheidoi
Scopus Author ID
37067246400 37067246400
著者名
Doi, Ryohei
NRID
1000030252589 1000030252589
researchmap permalink
read0042792 read0042792
Scopus Author ID
7005303403 7005303403
著者名
Ogoshi, Sensuke
キーワード等
C−F bond activation
Homogeneous catalysis
Hydrodefluorination
Lewis acids
Perfluoroalkyl substance
内容
Doi R., Ogoshi S.. Chemical Strategies for the Cleavage of the C(sp3)−F Bonds in Perfluoroalkyl Groups. European Journal of Organic Chemistry 27, e202301229 (2024); https://doi.org/10.1002/ejoc.202301229.
抄録
Perfluoroalkyl substances (PFAS) have been recognized as environmental pollutants. Hence, their efficient and mild destruction is a significant research interest. While many research articles and review papers have reported the cleavage of the C(sp2)−F bonds, single C(sp3)−F bond, and CF3 groups in PFAS, in this study, limited and emerging examples of a longer perfluoroalkyl group containing at least one repeating unit of 1,1,2,2-tetrafluoroethylene was focused. In this Concept, we summarized recent progress on the chemical defluorination of PFAS via the cleavage of unactivated C(sp3)−F bonds in longer perfluoroalkyl groups under mild conditions (~150 °C). In addition to classical reductive defluorination, strategies featuring Lewis acid activation and the transient generation of an unsaturated bond were described.
出版者
John Wiley and Sons Inc
収録物名
European Journal of Organic Chemistry
巻(号)
27(11)
ページ
e202301229
刊行年月
2024-03-18
言語
英語
ハンドルURL
https://hdl.handle.net/11094/95268
PISSN
1434193X
eISSN
10990690
関連情報 (isIdenticalTo)
DOI (出版社版)
https://doi.org/10.1002/ejoc.202301229
アクセス権
open access
権利情報
This article is licensed under a Creative Commons Attribution 4.0 International License.
出版タイプ
Version of Record
カテゴリ
学術雑誌論文 Journal Article