Structure and crystallization behavior of Na₂O–ZrO₂–SiO₂–P₂O₅ glass for solid-state electrolyte separation

Sakaeda, Kento; Shinozaki, Kenji; Kitta, Mitsunori; Kitagawa, Yuuki; Sukenaga, Sohei; Honma, Tsuyoshi

doi:https://doi.org/10.1016/j.jnoncrysol.2024.123070

Structure and crystallization behavior of Na₂O–ZrO₂–SiO₂–P₂O₅ glass for solid-state electrolyte separation

Sakaeda, Kento; Shinozaki, Kenji; Kitta, Mitsunori et al.

Journal of Non-Crystalline Solids, 2024, 638, 123070

アクセス数:387件（2025-07-11 18:35 集計）

固定URL: https://hdl.handle.net/11094/97656

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タイトル	Structure and crystallization behavior of Na₂O–ZrO₂–SiO₂–P₂O₅ glass for solid-state electrolyte separation
著者	著者名 Sakaeda, Kento
	NRID 1000010723489 1000010723489 ORCID 0000-0002-0967-8710 0000-0002-0967-8710 researchmap permalink kenji-shinozaki kenji-shinozaki 著者名 Shinozaki, Kenji
	NRID 1000090586546 1000090586546 著者名 Kitta, Mitsunori
	NRID 1000000964892 1000000964892 著者名 Kitagawa, Yuuki
	NRID 1000020432859 1000020432859 著者名 Sukenaga, Sohei
	NRID 1000070447647 1000070447647 著者名 Honma, Tsuyoshi
キーワード等	C. Ionic conductivity
	D. Glass
	D. Glass ceramics
	E. Battery
内容	Sakaeda K., Shinozaki K., Kitta M., et al. Structure and crystallization behavior of Na₂O–ZrO₂–SiO₂–P₂O₅ glass for solid-state electrolyte separation. Journal of Non-Crystalline Solids 638, 123070 (2024); https://doi.org/10.1016/j.jnoncrysol.2024.123070.
抄録	Glass ceramics containing Na super-ionic conductor (NASICON) crystals are promising candidates for solid-state electrolyte separators in aqueous sodium ion batteries due to their high ion conductivity, water stability, and productivity. Our objective was to fabricate a glass-ceramic separator by crystallizing a NASICON phase within the glass via heat-treatment. We conducted a detailed investigation into the structural evolution of the glass and the crystallization morphology. Upon heat-treatment, Si units polymerized to form an island-like phase, while P contributed to increasing non-bridging O to form a sea-like phase during droplet phase separation; subsequently, the Na₂Zr₂SiP₂O₁₂ crystalline phase formed. The remaining glass comprised Q⁴ units of Si in the island-like phase, and Q¹ and Q² units of P in the sea-like phase. The ionic conductivity of the sample increased by crystallization up to 5.4 × 10⁻⁵ S⋅cm ⁻¹ at 300 K. Furthermore, the water leakage tests showed that both the glass and glass-ceramics exhibited low leakages.
出版者	Elsevier B.V.
収録物名	Journal of Non-Crystalline Solids
巻(号)	638
ページ	123070
刊行年月	2024-08-15
言語	英語
ハンドルURL	https://hdl.handle.net/11094/97656
PISSN	00223093
関連情報 (isIdenticalTo)	DOI (出版社版) https://doi.org/10.1016/j.jnoncrysol.2024.123070
アクセス権	open access
権利情報	This article is licensed under a Creative Commons Attribution 4.0 International License.
出版タイプ	Version of Record
カテゴリ	学術雑誌論文 Journal Article

資源タイプ	学術雑誌論文
ローカル資源タイプ	学術雑誌論文
DCTERMS.bibliographicCitation	Journal of Non-Crystalline Solids. 2024, 638, p. 123070
DC.title	Structure and crystallization behavior of Na₂O–ZrO₂–SiO₂–P₂O₅ glass for solid-state electrolyte separation
DC.creator	Sakaeda, Kento
	Shinozaki, Kenji
	Kitta, Mitsunori
	Kitagawa, Yuuki
	Sukenaga, Sohei
	Honma, Tsuyoshi
DC.publisher	Elsevier B.V.
DC.language' scheme='DCTERMS.RFC1766	英語
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2024-08-15
DC.identifier	https://doi.org/10.1016/j.jnoncrysol.2024.123070
DC.subject	C. Ionic conductivity
	D. Glass
	D. Glass ceramics
	E. Battery
DC.description	Sakaeda K., Shinozaki K., Kitta M., et al. Structure and crystallization behavior of Na₂O–ZrO₂–SiO₂–P₂O₅ glass for solid-state electrolyte separation. Journal of Non-Crystalline Solids 638, 123070 (2024); https://doi.org/10.1016/j.jnoncrysol.2024.123070.
DCTERMS.abstract	Glass ceramics containing Na super-ionic conductor (NASICON) crystals are promising candidates for solid-state electrolyte separators in aqueous sodium ion batteries due to their high ion conductivity, water stability, and productivity. Our objective was to fabricate a glass-ceramic separator by crystallizing a NASICON phase within the glass via heat-treatment. We conducted a detailed investigation into the structural evolution of the glass and the crystallization morphology. Upon heat-treatment, Si units polymerized to form an island-like phase, while P contributed to increasing non-bridging O to form a sea-like phase during droplet phase separation; subsequently, the Na₂Zr₂SiP₂O₁₂ crystalline phase formed. The remaining glass comprised Q⁴ units of Si in the island-like phase, and Q¹ and Q² units of P in the sea-like phase. The ionic conductivity of the sample increased by crystallization up to 5.4 × 10⁻⁵ S⋅cm ⁻¹ at 300 K. Furthermore, the water leakage tests showed that both the glass and glass-ceramics exhibited low leakages.
DC.rights	This article is licensed under a Creative Commons Attribution 4.0 International License.
DC.format	97656
citation_title	Structure and crystallization behavior of Na₂O–ZrO₂–SiO₂–P₂O₅ glass for solid-state electrolyte separation
citation_author	Sakaeda, Kento
	Shinozaki, Kenji
	Kitta, Mitsunori
	Kitagawa, Yuuki
	Sukenaga, Sohei
	Honma, Tsuyoshi
citation_publisher	Elsevier B.V.
citation_language	英語
citation_date	2024-08-15
citation_journal_title	Journal of Non-Crystalline Solids
citation_volume	638
citation_firstpage	123070
citation_doi	https://doi.org/10.1016/j.jnoncrysol.2024.123070
citation_public_url	https://hdl.handle.net/11094/97656

Structure and crystallization behavior of Na₂O–ZrO₂–SiO₂–P₂O₅ glass for solid-state electrolyte separation

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