Hydrogen-induced pore formation in Ni–P-plated Al–Zn–Mg alloys revealed by synchrotron X-ray computed tomography and hydrogen detection

Horikawa, Keitaro; Hino, Makoto; Shimizu, Kazuyuki; Toda, Hiroyuki; Hoshino, Masato; Uesugi, Kentaro

doi:https://doi.org/10.1016/j.ijhydene.2024.07.380

Hydrogen-induced pore formation in Ni–P-plated Al–Zn–Mg alloys revealed by synchrotron X-ray computed tomography and hydrogen detection

Horikawa, Keitaro; Hino, Makoto; Shimizu, Kazuyuki et al.

International Journal of Hydrogen Energy, 2024, 82, 801-809

アクセス数:599件（2025-10-31 19:10 集計）

固定URL: https://hdl.handle.net/11094/97798

閲覧可能ファイル

ファイル	フォーマット	利用条件	サイズ	閲覧回数	利用開始日	説明	information
IntJHydrogenEnergy_82_801	pdf	なし	10.8 MB	70	2024.08.30

Creative Commons : 表示

論文情報

ファイル出力 EndNote Basic出力 Mendeley出力

タイトル	Hydrogen-induced pore formation in Ni–P-plated Al–Zn–Mg alloys revealed by synchrotron X-ray computed tomography and hydrogen detection
著者	NRID 1000050314836 1000050314836 ORCID 0000-0003-4573-9952 0000-0003-4573-9952 researchmap permalink read0118558 read0118558 Scopus Author ID 7102628912 7102628912 著者名 Horikawa, Keitaro
	NRID 1000070510486 1000070510486 著者名 Hino, Makoto
	NRID 1000030748760 1000030748760 著者名 Shimizu, Kazuyuki
	NRID 1000070293751 1000070293751 著者名 Toda, Hiroyuki
	NRID 1000030508461 1000030508461 著者名 Hoshino, Masato
	NRID 1000080344399 1000080344399 著者名 Uesugi, Kentaro
キーワード等	Al–Zn–Mg alloy
	Hydrogen analysis
	Hydrogen-associated defect
	Ni–P plating
	X-ray computed tomography
内容	Horikawa K., Hino M., Shimizu K., et al. Hydrogen-induced pore formation in Ni–P-plated Al–Zn–Mg alloys revealed by synchrotron X-ray computed tomography and hydrogen detection. International Journal of Hydrogen Energy 82, 801 (2024); https://doi.org/10.1016/j.ijhydene.2024.07.380.
抄録	The internal microstructures of Ni–P-plated Al–Zn–Mg-based alloys were investigated using synchrotron X-ray computed tomography, together with various analytical methods for hydrogen detection. We clarified that hydrogen-induced pores were generated and segregated near the top and bottom surfaces of a rolled sheet of a commercial-purity Al–Zn–Mg-based alloy with Ni–P plating. In contrast, such segregation of hydrogen micropores was not observed in the high-purity-grade Al–Zn–Mg alloys with Ni–P plating. This result suggests that hydrogen enters the Ni–P plating layer during the plating operation and generates pores in the surface region owing to surface inclusions. Additionally, the hydrogen-induced defects deteriorated the tensile properties such as tensile strength and elongation of the commercial-purity Al–Zn–Mg-based alloys containing higher levels of impurities such as Fe and Si with Ni–P plating.
出版者	Elsevier Ltd
収録物名	International Journal of Hydrogen Energy
巻(号)	82
ページ	801-809
刊行年月	2024-09-11
言語	英語
ハンドルURL	https://hdl.handle.net/11094/97798
PISSN	03603199
関連情報 (isIdenticalTo)	DOI (出版社版) https://doi.org/10.1016/j.ijhydene.2024.07.380
アクセス権	open access
権利情報	This article is licensed under a Creative Commons Attribution 4.0 International License.
出版タイプ	Version of Record
カテゴリ	学術雑誌論文 Journal Article

資源タイプ	学術雑誌論文
ローカル資源タイプ	学術雑誌論文
DCTERMS.bibliographicCitation	International Journal of Hydrogen Energy. 2024, 82, p. 801-809
DC.title	Hydrogen-induced pore formation in Ni–P-plated Al–Zn–Mg alloys revealed by synchrotron X-ray computed tomography and hydrogen detection
DC.creator	Horikawa, Keitaro
	Hino, Makoto
	Shimizu, Kazuyuki
	Toda, Hiroyuki
	Hoshino, Masato
	Uesugi, Kentaro
DC.publisher	Elsevier Ltd
DC.language' scheme='DCTERMS.RFC1766	英語
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2024-09-11
DC.identifier	https://doi.org/10.1016/j.ijhydene.2024.07.380
DC.subject	Al–Zn–Mg alloy
	Hydrogen analysis
	Hydrogen-associated defect
	Ni–P plating
	X-ray computed tomography
DC.description	Horikawa K., Hino M., Shimizu K., et al. Hydrogen-induced pore formation in Ni–P-plated Al–Zn–Mg alloys revealed by synchrotron X-ray computed tomography and hydrogen detection. International Journal of Hydrogen Energy 82, 801 (2024); https://doi.org/10.1016/j.ijhydene.2024.07.380.
DCTERMS.abstract	The internal microstructures of Ni–P-plated Al–Zn–Mg-based alloys were investigated using synchrotron X-ray computed tomography, together with various analytical methods for hydrogen detection. We clarified that hydrogen-induced pores were generated and segregated near the top and bottom surfaces of a rolled sheet of a commercial-purity Al–Zn–Mg-based alloy with Ni–P plating. In contrast, such segregation of hydrogen micropores was not observed in the high-purity-grade Al–Zn–Mg alloys with Ni–P plating. This result suggests that hydrogen enters the Ni–P plating layer during the plating operation and generates pores in the surface region owing to surface inclusions. Additionally, the hydrogen-induced defects deteriorated the tensile properties such as tensile strength and elongation of the commercial-purity Al–Zn–Mg-based alloys containing higher levels of impurities such as Fe and Si with Ni–P plating.
DC.rights	This article is licensed under a Creative Commons Attribution 4.0 International License.
DC.format	97798
citation_title	Hydrogen-induced pore formation in Ni–P-plated Al–Zn–Mg alloys revealed by synchrotron X-ray computed tomography and hydrogen detection
citation_author	Horikawa, Keitaro
	Hino, Makoto
	Shimizu, Kazuyuki
	Toda, Hiroyuki
	Hoshino, Masato
	Uesugi, Kentaro
citation_publisher	Elsevier Ltd
citation_language	英語
citation_date	2024-09-11
citation_journal_title	International Journal of Hydrogen Energy
citation_volume	82
citation_firstpage	801
citation_lastpage	809
citation_doi	https://doi.org/10.1016/j.ijhydene.2024.07.380
citation_public_url	https://hdl.handle.net/11094/97798

Hydrogen-induced pore formation in Ni–P-plated Al–Zn–Mg alloys revealed by synchrotron X-ray computed tomography and hydrogen detection

閲覧可能ファイル

論文情報

論文詳細を表示