3,11-Diaminodibenzo[a,j]phenazine: Synthesis, Properties, and Applications to Tröger's Base-Forming Ladder Polymerization

Izumi, Saika; Inoue, Keiki; Nitta, Yuya; Enjou, Tomoya; Ami, Takahiro; Oka, Kouki; Tohnai, Norimitsu; Minakata, Satoshi; Fukushima, Takanori; Ishiwari, Fumitaka; Takeda, Youhei

doi:https://doi.org/10.1002/chem.202202702

3,11-Diaminodibenzo[a,j]phenazine: Synthesis, Properties, and Applications to Tröger's Base-Forming Ladder Polymerization

Izumi, Saika; Inoue, Keiki; Nitta, Yuya et al.

Chemistry - A European Journal, 2023, 29(14), e202202702

アクセス数:1,155件（2025-07-06 07:27 集計）

固定URL: https://hdl.handle.net/11094/98090

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タイトル	3,11-Diaminodibenzo[a,j]phenazine: Synthesis, Properties, and Applications to Tröger's Base-Forming Ladder Polymerization
著者	著者名 Izumi, Saika
	著者名 Inoue, Keiki
	著者名 Nitta, Yuya
	著者名 Enjou, Tomoya
	著者名 Ami, Takahiro
	NRID 1000050907376 1000050907376 researchmap permalink k.oka k.oka Scopus Author ID 57197754064 57197754064 著者名 Oka, Kouki
	NRID 1000030346184 1000030346184 researchmap permalink read0089607 read0089607 Scopus Author ID 6701482198 6701482198 ORCID 0000-0001-7051-7599 0000-0001-7051-7599 著者名 Tohnai, Norimitsu
	NRID 1000090273599 1000090273599 researchmap permalink read0185263 read0185263 Scopus Author ID 7003640913 7003640913 ORCID 0000-0001-9619-445X 0000-0001-9619-445X 著者名 Minakata, Satoshi
	NRID 1000070281970 1000070281970 著者名 Fukushima, Takanori
	NRID 1000000635807 1000000635807 ORCID 0000-0002-0200-4510 0000-0002-0200-4510 researchmap permalink fishiwari fishiwari Scopus Author ID 24767538500 24767538500 著者名 Ishiwari, Fumitaka
	NRID 1000060608785 1000060608785 ORCID 0000-0001-9103-4238 0000-0001-9103-4238 researchmap permalink read0156438 read0156438 Scopus Author ID 12753487600 12753487600 著者名 Takeda, Youhei
キーワード等	charge-transfer
	gas absorption
	ladder polymers
	luminescence
	phenazine
内容	This is the accepted version of the following article: Izumi S., Inoue K., Nitta Y., et al. 3,11-Diaminodibenzo[a,j]phenazine: Synthesis, Properties, and Applications to Tröger's Base-Forming Ladder Polymerization. Chemistry - A European Journal 29, e202202702 (2023), which has been published in final form at https://doi.org/10.1002/chem.202202702. This article may be used for non-commercialpurposes in accordance with the Wiley Self-ArchivingPolicy. [https://authorservices.wiley.com/author-resources/Journal-Authors/licensing/self-archiving.html]
抄録	A new class of diamino-substituted π-extended phenazine compound was synthesized, and its photophysical properties were investigated. The U-shaped diaminophenazine displayed photoluminescence in solution with moderate quantum yield. The diamino aromatic compound was found applicable to the poly-condensation with formaldehyde to form Tröger's base ladder polymer. The obtained microporous ladder polymer features high CO2 adsorption selectivity against N2, most likely due to the presence of basic nitrogen atoms in the phenazine rings.
出版者	John Wiley and Sons Inc
収録物名	Chemistry - A European Journal
巻(号)	29(14)
ページ	e202202702
刊行年月	2023-03-07
言語	英語
ハンドルURL	https://hdl.handle.net/11094/98090
PISSN	09476539
eISSN	15213765
関連情報 (isVersionOf)	DOI (出版社版) https://doi.org/10.1002/chem.202202702
アクセス権	open access
権利情報	© 2022 Wiley-VCH GmbH.
出版タイプ	Accepted Manuscript
カテゴリ	学術雑誌論文 Journal Article

資源タイプ	学術雑誌論文
ローカル資源タイプ	学術雑誌論文
DCTERMS.bibliographicCitation	Chemistry - A European Journal. 2023, 29(14), p. e202202702
DC.title	3,11-Diaminodibenzo[a,j]phenazine: Synthesis, Properties, and Applications to Tröger's Base-Forming Ladder Polymerization
DC.creator	Izumi, Saika
	Inoue, Keiki
	Nitta, Yuya
	Enjou, Tomoya
	Ami, Takahiro
	Oka, Kouki
	Tohnai, Norimitsu
	Minakata, Satoshi
	Fukushima, Takanori
	Ishiwari, Fumitaka
	Takeda, Youhei
DC.publisher	John Wiley and Sons Inc
DC.language' scheme='DCTERMS.RFC1766	英語
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2023-03-07
DC.identifier	https://doi.org/10.1002/chem.202202702
DC.subject	charge-transfer
	gas absorption
	ladder polymers
	luminescence
	phenazine
DC.description	This is the accepted version of the following article: Izumi S., Inoue K., Nitta Y., et al. 3,11-Diaminodibenzo[a,j]phenazine: Synthesis, Properties, and Applications to Tröger's Base-Forming Ladder Polymerization. Chemistry - A European Journal 29, e202202702 (2023), which has been published in final form at https://doi.org/10.1002/chem.202202702. This article may be used for non-commercialpurposes in accordance with the Wiley Self-ArchivingPolicy. [https://authorservices.wiley.com/author-resources/Journal-Authors/licensing/self-archiving.html]
DCTERMS.abstract	A new class of diamino-substituted π-extended phenazine compound was synthesized, and its photophysical properties were investigated. The U-shaped diaminophenazine displayed photoluminescence in solution with moderate quantum yield. The diamino aromatic compound was found applicable to the poly-condensation with formaldehyde to form Tröger's base ladder polymer. The obtained microporous ladder polymer features high CO2 adsorption selectivity against N2, most likely due to the presence of basic nitrogen atoms in the phenazine rings.
DC.rights	© 2022 Wiley-VCH GmbH.
DC.format	98090
citation_title	3,11-Diaminodibenzo[a,j]phenazine: Synthesis, Properties, and Applications to Tröger's Base-Forming Ladder Polymerization
citation_author	Izumi, Saika
	Inoue, Keiki
	Nitta, Yuya
	Enjou, Tomoya
	Ami, Takahiro
	Oka, Kouki
	Tohnai, Norimitsu
	Minakata, Satoshi
	Fukushima, Takanori
	Ishiwari, Fumitaka
	Takeda, Youhei
citation_publisher	John Wiley and Sons Inc
citation_language	英語
citation_date	2023-03-07
citation_journal_title	Chemistry - A European Journal
citation_volume	29
citation_issue	14
citation_firstpage	e202202702
citation_doi	https://doi.org/10.1002/chem.202202702
citation_public_url	https://hdl.handle.net/11094/98090

3,11-Diaminodibenzo[a,j]phenazine: Synthesis, Properties, and Applications to Tröger's Base-Forming Ladder Polymerization

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