Strain-induced carbon-carbon bond cleavage of bowl-shaped sumanenone

Nishimoto, Mikey; Uetake, Yuta; Yakiyama, Yumi; Sakurai, Hidehiro

doi:https://doi.org/10.1039/d4cc00008k

Strain-induced carbon-carbon bond cleavage of bowl-shaped sumanenone

Nishimoto, Mikey; Uetake, Yuta; Yakiyama, Yumi et al.

Chemical Communications, 2024, 60(29), 3982-3985

アクセス数:709件（2025-07-19 11:16 集計）

固定URL: https://hdl.handle.net/11094/98571

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タイトル	Strain-induced carbon-carbon bond cleavage of bowl-shaped sumanenone
著者	著者名 Nishimoto, Mikey
	NRID 1000010755440 1000010755440 ORCID 0000-0002-4742-8085 0000-0002-4742-8085 researchmap permalink yutauetake yutauetake Scopus Author ID 56417952700 56417952700 著者名 Uetake, Yuta
	NRID 1000060636819 1000060636819 ORCID 0000-0003-4278-2015 0000-0003-4278-2015 researchmap permalink yumiyakiyama yumiyakiyama Scopus Author ID 57195377416 57195377416 著者名 Yakiyama, Yumi
	NRID 1000000262147 1000000262147 ORCID 0000-0001-5783-4151 0000-0001-5783-4151 researchmap permalink read0184917 read0184917 Scopus Author ID 7402869823 7402869823 著者名 Sakurai, Hidehiro
内容	Nishimoto M., Uetake Y., Yakiyama Y., et al. Strain-induced carbon-carbon bond cleavage of bowl-shaped sumanenone. Chemical Communications 60, 3982 (2024); https://doi.org/10.1039/d4cc00008k.
抄録	This study details a highly effective ring-opening reaction that involves acid-mediated carbon-carbon bond cleavage of the buckybowl, sumanenone. The reaction of the bowl-shaped sumanenone with AcOH and TfOH results in the formation of a planar carboxylic acid. The examination of reactivity in comparison to planar analogues, along with theoretical calculations, suggests that the release of curved strain is a crucial factor for the success of this reaction.
出版者	Royal Society of Chemistry
収録物名	Chemical Communications
巻(号)	60(29)
ページ	3982-3985
刊行年月	2024-03-13
言語	英語
ハンドルURL	https://hdl.handle.net/11094/98571
PISSN	13597345
eISSN	1364548X
関連情報 (isIdenticalTo)	DOI (出版社版) https://doi.org/10.1039/d4cc00008k
アクセス権	open access
権利情報	This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 International License.
出版タイプ	Version of Record
カテゴリ	学術雑誌論文 Journal Article

資源タイプ	学術雑誌論文
ローカル資源タイプ	学術雑誌論文
DCTERMS.bibliographicCitation	Chemical Communications. 2024, 60(29), p. 3982-3985
DC.title	Strain-induced carbon-carbon bond cleavage of bowl-shaped sumanenone
DC.creator	Nishimoto, Mikey
	Uetake, Yuta
	Yakiyama, Yumi
	Sakurai, Hidehiro
DC.publisher	Royal Society of Chemistry
DC.language' scheme='DCTERMS.RFC1766	英語
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2024-03-13
DC.identifier	https://doi.org/10.1039/d4cc00008k
DC.description	Nishimoto M., Uetake Y., Yakiyama Y., et al. Strain-induced carbon-carbon bond cleavage of bowl-shaped sumanenone. Chemical Communications 60, 3982 (2024); https://doi.org/10.1039/d4cc00008k.
DCTERMS.abstract	This study details a highly effective ring-opening reaction that involves acid-mediated carbon-carbon bond cleavage of the buckybowl, sumanenone. The reaction of the bowl-shaped sumanenone with AcOH and TfOH results in the formation of a planar carboxylic acid. The examination of reactivity in comparison to planar analogues, along with theoretical calculations, suggests that the release of curved strain is a crucial factor for the success of this reaction.
DC.rights	This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 International License.
DC.format	98571
citation_title	Strain-induced carbon-carbon bond cleavage of bowl-shaped sumanenone
citation_author	Nishimoto, Mikey
	Uetake, Yuta
	Yakiyama, Yumi
	Sakurai, Hidehiro
citation_publisher	Royal Society of Chemistry
citation_language	英語
citation_date	2024-03-13
citation_journal_title	Chemical Communications
citation_volume	60
citation_issue	29
citation_firstpage	3982
citation_lastpage	3985
citation_doi	https://doi.org/10.1039/d4cc00008k
citation_public_url	https://hdl.handle.net/11094/98571

Strain-induced carbon-carbon bond cleavage of bowl-shaped sumanenone

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