Decarboxylative Alkylation of Carboxylic Acids with Easily Oxidizable Functional Groups Catalyzed by an Imidazole-Coordinated Fe3 Cluster under Visible Light Irradiation

Tamaki, Sota; Kusamoto, Tetsuro; Tsurugi, Hayato

Chemistry - A European Journal, 2024, 30(69), e202402705

アクセス数:305件（2025-07-19 11:11 集計）

固定URL: https://hdl.handle.net/11094/98894

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タイトル
Decarboxylative Alkylation of Carboxylic Acids with Easily Oxidizable Functional Groups Catalyzed by an Imidazole-Coordinated Fe3 Cluster under Visible Light Irradiation
著者
著者名
Tamaki, Sota
NRID
1000090585192 1000090585192
ORCID
0000-0001-8391-4526 0000-0001-8391-4526
researchmap permalink
kusamoto_tetsuro kusamoto_tetsuro
著者名
Kusamoto, Tetsuro
NRID
1000060432514 1000060432514
ORCID
0000-0003-2942-7705 0000-0003-2942-7705
researchmap permalink
h_tsu h_tsu
Scopus Author ID
6505993971 6505993971
著者名
Tsurugi, Hayato
キーワード等
Decarboxylation
Homolysis
Iron
Photo-catalyst
内容
Tamaki S., Kusamoto T., Tsurugi H. Decarboxylative Alkylation of Carboxylic Acids with Easily Oxidizable Functional Groups Catalyzed by an Imidazole-Coordinated Fe3 Cluster under Visible Light Irradiation. Chemistry - A European Journal 30, e202402705 (2024); https://doi.org/10.1002/chem.202402705.
抄録
Decarboxylative alkylation of carboxylic acids with easily oxidizable functional groups such as phenol and indole functionalities was achieved using a catalytic amount of basic iron(III) acetate, Fe(OAc)2(OH), in the presence of benzimidazole under 427 nm LED irradiation. Kinetic analyses of this catalytic reaction revealed that the reaction rate is first-order in alkenes and is linearly correlated with the light intensity; the faster reaction rate for the benzimidazole-ligated species was consistent with the increased absorbance in the visible light region. Wide functional group tolerance for the easily oxidizable groups is ascribed to the weak oxidation ability of the in situ-generated oxo-bridged iron clusters compared with other iron(III) species.
出版者
John Wiley and Sons Inc
収録物名
Chemistry - A European Journal
巻(号)
30(69)
ページ
e202402705
刊行年月
2024-12-10
言語
英語
ハンドルURL
https://hdl.handle.net/11094/98894
PISSN
09476539
eISSN
15213765
関連情報 (isIdenticalTo)
DOI (出版社版)
https://doi.org/10.1002/chem.202402705
アクセス権
open access
権利情報
This article is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
出版タイプ
Version of Record
カテゴリ
学術雑誌論文 Journal Article