学術雑誌論文

学術雑誌論文

text

European Polymer Journaｌ. 2004, 40(8), p. 1623-1627

On-Line measurement of molecular weight and radius of gyration of polystyrene in a good solvent and in a theta solvent measured with a two-angle light scattering detector

Elsevier Limited

英語

text

2004-08

https://doi.org/10.1016/j.eurpolymj.2004.03.010

On-line two-angle (15° and 90°) light scattering measurements with a gel permeation chromatography for linear and branched polystyrene in tetrahydrofuran (a good solvent) and in trans-decalin (a theta solvent) were made and compared with data from a multi-angle light scattering detector and literature values. Theoretically, weight-average molecular weight and the radius of gyration R_g can be determined accurately in the range where R_g^2k^2 is less than 1.2 (rod)~1.7 (random coil); here, k is the absolute value of the scattering vector for a right angle detector with the Berry square root method. Molecular weight dependence of the radius of gyration obtained from the two-angle light scattering detector for linear and branched polystyrenes under different thermodynamic conditions were measured and found to be almost the same as values measured with a multi-angle light scattering detector and literature values in the appropriate range of molecular weight.

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On-Line measurement of molecular weight and radius of gyration of polystyrene in a good solvent and in a theta solvent measured with a two-angle light scattering detector

Elsevier Limited

英語

2004-08

European Polymer Journaｌ

40

8

1623

1627

https://doi.org/10.1016/j.eurpolymj.2004.03.010

https://hdl.handle.net/11094/25928