Generation of Nickel Siloxycarbene Complexes from Acylsilanes for the Catalytic Synthesis of Silyl Enol Ethers

Matsuura, Akihisa; Ito, Yuri; Inagaki, Tetsuya; Kodama, Takuya; Tobisu, Mamoru

doi:https://doi.org/10.1021/acscatal.4c06272

Generation of Nickel Siloxycarbene Complexes from Acylsilanes for the Catalytic Synthesis of Silyl Enol Ethers

Matsuura, Akihisa; Ito, Yuri; Inagaki, Tetsuya et al.

ACS Catalysis, 2024, 14(23), 18216-18222

Number of Access:268（2025-06-24 14:19 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/100145

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Title	Generation of Nickel Siloxycarbene Complexes from Acylsilanes for the Catalytic Synthesis of Silyl Enol Ethers
Creator	CreatorName Matsuura, Akihisa
	CreatorName Ito, Yuri
	CreatorName Inagaki, Tetsuya
	NRID 1000080823989 1000080823989 ORCID 0000-0001-8275-2393 0000-0001-8275-2393 researchmap permalink kdm kdm Scopus Author ID 56522275700 56522275700 CreatorName Kodama, Takuya
	NRID 1000060403143 1000060403143 ORCID 0000-0002-8415-2225 0000-0002-8415-2225 researchmap permalink read0156480 read0156480 Scopus Author ID 6506514402 6506514402 CreatorName Tobisu, Mamoru
Subject	acylsilane
	DFT calculation
	Fischer carbene complexes
	nickel catalyst
	silyl enol ether
Description	Matsuura A., Ito Y., Inagaki T., et al. Generation of Nickel Siloxycarbene Complexes from Acylsilanes for the Catalytic Synthesis of Silyl Enol Ethers. ACS Catalysis 14, 18216 (2024); https://doi.org/10.1021/acscatal.4c06272.
Abstract	A catalytic protocol has been developed to access Fischer carbene nickel complexes using acylsilanes as stable and readily available precursors. The as-generated Fischer carbene complexes exhibit versatile reactivity, including cyclopropanation with alkenes, α-C-H insertion reactions, and two-component C-H addition to norbornene, which demonstrates the broad utility of the nickel(0)/acylsilane system for the catalytic applications of Fischer carbene complexes.
Publisher	American Chemical Society
Source Title	ACS Catalysis
Volume (Issue)	14(23)
Page	18216-18222
Date of Issued	2024-12-06
Language	English
Handle URL	https://hdl.handle.net/11094/100145
eISSN	21555435
Relation.isVersionOf	DOI (Publisher Version) https://doi.org/10.1021/acscatal.4c06272
Access Rights	embargoed access
CopyRight	This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acscatal.4c06272.
CopyRight	The full-text file will be made open to the public on 6 December 2025 in accordance with the publisher's policy.
oaire:version	Accepted Manuscript
Category	学術雑誌論文 Journal Article

Resource Type	journal article
Local Type	Journal Article
DCTERMS.bibliographicCitation	ACS Catalysis. 2024, 14(23), p. 18216-18222
DC.title	Generation of Nickel Siloxycarbene Complexes from Acylsilanes for the Catalytic Synthesis of Silyl Enol Ethers
DC.creator	Matsuura, Akihisa
	Ito, Yuri
	Inagaki, Tetsuya
	Kodama, Takuya
	Tobisu, Mamoru
DC.publisher	American Chemical Society
DC.language' scheme='DCTERMS.RFC1766	English
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2024-12-06
DC.identifier	https://doi.org/10.1021/acscatal.4c06272
DC.subject	acylsilane
	DFT calculation
	Fischer carbene complexes
	nickel catalyst
	silyl enol ether
DC.description	Matsuura A., Ito Y., Inagaki T., et al. Generation of Nickel Siloxycarbene Complexes from Acylsilanes for the Catalytic Synthesis of Silyl Enol Ethers. ACS Catalysis 14, 18216 (2024); https://doi.org/10.1021/acscatal.4c06272.
DCTERMS.abstract	A catalytic protocol has been developed to access Fischer carbene nickel complexes using acylsilanes as stable and readily available precursors. The as-generated Fischer carbene complexes exhibit versatile reactivity, including cyclopropanation with alkenes, α-C-H insertion reactions, and two-component C-H addition to norbornene, which demonstrates the broad utility of the nickel(0)/acylsilane system for the catalytic applications of Fischer carbene complexes.
DC.rights	This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acscatal.4c06272.
DC.rights	The full-text file will be made open to the public on 6 December 2025 in accordance with the publisher's policy.
DC.format	100145
citation_title	Generation of Nickel Siloxycarbene Complexes from Acylsilanes for the Catalytic Synthesis of Silyl Enol Ethers
citation_author	Matsuura, Akihisa
	Ito, Yuri
	Inagaki, Tetsuya
	Kodama, Takuya
	Tobisu, Mamoru
citation_publisher	American Chemical Society
citation_language	English
citation_date	2024-12-06
citation_journal_title	ACS Catalysis
citation_volume	14
citation_issue	23
citation_firstpage	18216
citation_lastpage	18222
citation_doi	https://doi.org/10.1021/acscatal.4c06272
citation_public_url	https://hdl.handle.net/11094/100145

Generation of Nickel Siloxycarbene Complexes from Acylsilanes for the Catalytic Synthesis of Silyl Enol Ethers

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