Nucleophilic reactions of bromocyclopentane in the structure-h methane + bromocyclopentane mixed hydrate system at high pressures

Matsumoto, Yuuki; Katsuta, Yoshito; Kamo, Fumitaka; Bando, Tatsuya; Makino, Takashi; Sugahara, Takeshi; Ohgaki, Kazunari

doi:https://doi.org/10.1021/jp505313v

Nucleophilic reactions of bromocyclopentane in the structure-h methane + bromocyclopentane mixed hydrate system at high pressures

Matsumoto, Yuuki; Katsuta, Yoshito; Kamo, Fumitaka et al.

Journal of Physical Chemistry B, 2014, 118(47), 13404-13408

Number of Access:512（2025-07-27 08:52 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/100987

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Title	Nucleophilic reactions of bromocyclopentane in the structure-h methane + bromocyclopentane mixed hydrate system at high pressures
Creator	CreatorName Matsumoto, Yuuki
	CreatorName Katsuta, Yoshito
	CreatorName Kamo, Fumitaka
	CreatorName Bando, Tatsuya
	NRID 1000070455153 1000070455153 CreatorName Makino, Takashi
	NRID 1000020335384 1000020335384 ORCID 0000-0002-5236-5605 0000-0002-5236-5605 researchmap permalink read0191169 read0191169 Scopus Author ID 56212469300 56212469300 CreatorName Sugahara, Takeshi
	NRID 1000080107078 1000080107078 CreatorName Ohgaki, Kazunari
Description	This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Physical Chemistry B, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/jp505313v.
Abstract	Thermodynamic stability boundary in the structure-H methane + bromocyclopentane mixed hydrate system was measured at pressures from 20 to 100 MPa. The thermodynamic stability boundary of the methane + bromocyclopentane mixed hydrate exhibits anomalous behavior under conditions at high pressures and high temperatures. This phenomenon is due to the elimination and substitution reactions of bromocyclopentane to cyclopentene and cyclopentanol, respectively. The nucleophilic reactions of bromocyclopentane are mainly advanced in the liquid bromocyclopentane-rich phases, while it is restrained when bromocyclopentane is enclathrated in hydrate cage.
Publisher	American Chemical Society
Source Title	Journal of Physical Chemistry B
Volume (Issue)	118(47)
Page	13404-13408
Date of Issued	2014-07-11
Language	English
Handle URL	https://hdl.handle.net/11094/100987
PISSN	15206106
eISSN	15205207
Relation.isVersionOf	DOI (Publisher Version) https://doi.org/10.1021/jp505313v
Access Rights	open access
CopyRight	© 2014 American Chemical Society.
oaire:version	Accepted Manuscript
Category	学術雑誌論文 Journal Article

Resource Type	journal article
Local Type	Journal Article
DCTERMS.bibliographicCitation	Journal of Physical Chemistry B. 2014, 118(47), p. 13404-13408
DC.title	Nucleophilic reactions of bromocyclopentane in the structure-h methane + bromocyclopentane mixed hydrate system at high pressures
DC.creator	Matsumoto, Yuuki
	Katsuta, Yoshito
	Kamo, Fumitaka
	Bando, Tatsuya
	Makino, Takashi
	Sugahara, Takeshi
	Ohgaki, Kazunari
DC.publisher	American Chemical Society
DC.language' scheme='DCTERMS.RFC1766	English
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2014-07-11
DC.identifier	https://doi.org/10.1021/jp505313v
DC.description	This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Physical Chemistry B, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/jp505313v.
DCTERMS.abstract	Thermodynamic stability boundary in the structure-H methane + bromocyclopentane mixed hydrate system was measured at pressures from 20 to 100 MPa. The thermodynamic stability boundary of the methane + bromocyclopentane mixed hydrate exhibits anomalous behavior under conditions at high pressures and high temperatures. This phenomenon is due to the elimination and substitution reactions of bromocyclopentane to cyclopentene and cyclopentanol, respectively. The nucleophilic reactions of bromocyclopentane are mainly advanced in the liquid bromocyclopentane-rich phases, while it is restrained when bromocyclopentane is enclathrated in hydrate cage.
DC.rights	© 2014 American Chemical Society.
DC.format	100987
citation_title	Nucleophilic reactions of bromocyclopentane in the structure-h methane + bromocyclopentane mixed hydrate system at high pressures
citation_author	Matsumoto, Yuuki
	Katsuta, Yoshito
	Kamo, Fumitaka
	Bando, Tatsuya
	Makino, Takashi
	Sugahara, Takeshi
	Ohgaki, Kazunari
citation_publisher	American Chemical Society
citation_language	English
citation_date	2014-07-11
citation_journal_title	Journal of Physical Chemistry B
citation_volume	118
citation_issue	47
citation_firstpage	13404
citation_lastpage	13408
citation_doi	https://doi.org/10.1021/jp505313v
citation_public_url	https://hdl.handle.net/11094/100987

Nucleophilic reactions of bromocyclopentane in the structure-h methane + bromocyclopentane mixed hydrate system at high pressures

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