Cross-Dehydrogenative Coupling Reaction of 4-Aminophenols with 2-Naphthols Catalyzed by a Mesoporous Silica-Supported Oxovanadium Catalyst

Ito, Yutaro; Kasama, Kengo; Moon, Jihoon et al.

Asian Journal of Organic Chemistry, 2025, e00537

Number of Access:12（2025-11-28 05:29 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/102966

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Title
Cross-Dehydrogenative Coupling Reaction of 4-Aminophenols with 2-Naphthols Catalyzed by a Mesoporous Silica-Supported Oxovanadium Catalyst
Creator
CreatorName
Ito, Yutaro
NRID
1000040963236 1000040963236
CreatorName
Kasama, Kengo
CreatorName
Moon, Jihoon
CreatorName
Kanzaki, Yui
CreatorName
Nishio, Tomoya
NRID
1000040761903 1000040761903
CreatorName
Masuda, Koichiro
CreatorName
Kobayashi, Kwihwan
NRID
1000020812134 1000020812134
ORCID
0000-0002-8037-4293 0000-0002-8037-4293
researchmap permalink
akimishi akimishi
Scopus Author ID
16068836600 16068836600
CreatorName
Kimishima, Atsushi
NRID
1000060291910 1000060291910
ORCID
0000-0001-7915-8975 0000-0001-7915-8975
researchmap permalink
H_Aoyama H_Aoyama
Scopus Author ID
37042208200 37042208200
CreatorName
Aoyama, Hiroshi
NRID
1000030880447 1000030880447
ORCID
0000-0002-2251-4665 0000-0002-2251-4665
researchmap permalink
kyohei_kanomata kyohei_kanomata
Scopus Author ID
39861733600 39861733600
CreatorName
Kanomata, Kyohei
NRID
1000060192457 1000060192457
ORCID
0000-0001-9149-8745 0000-0001-9149-8745
researchmap permalink
shuji_akai shuji_akai
Scopus Author ID
7006001526 7006001526
CreatorName
Akai, Shuji
Subject
Aminophenol
C─C bond formation
C─H functionalization
Heterogeneous catalyst
Quinone monoimine
Description
Ito Y., Kasama K., Moon J., et al. Cross-Dehydrogenative Coupling Reaction of 4-Aminophenols with 2-Naphthols Catalyzed by a Mesoporous Silica-Supported Oxovanadium Catalyst. Asian Journal of Organic Chemistry, e00537 (2025); https://doi.org/10.1002/ajoc.202500537.
Abstract
Cross-dehydrogenative coupling (CDC) reactions offer an atom-economical approach for synthesizing biaryl compounds by directly forming C─C bonds from the C─H bonds of two aromatic molecules. In this study, the CDC reaction between 4-aminophenols and 2-naphthols was successfully catalyzed using a mesoporous silica-supported oxovanadium catalyst. This reaction involved the catalytic, chemo- and regio-selective oxidation of 4-aminophenols, with molecular oxygen as the terminal oxidant, eliminating the need for stoichiometric chemical oxidants, thereby making the reaction more environmentally friendly.
Publisher
John Wiley and Sons Inc
Source Title
Asian Journal of Organic Chemistry
Page
e00537
Date of Issued
2025-09-17
Language
English
Handle URL
https://hdl.handle.net/11094/102966
eISSN
21935815
Relation.isIdenticalTo
DOI (Publisher Version)
https://doi.org/10.1002/ajoc.202500537
Access Rights
open access
CopyRight
This article is licensed under a Creative Commons Attribution 4.0 International License.
oaire:version
Version of Record
Category
学術雑誌論文 Journal Article