Tetrapotassium [μ_2-N-carboxylato-D-penicillaminato(3-)-5:6κ^2S:S][μ_2-D-penicillaminato(1-)-2:3κ^2S:S]tetrakis[μ_2-D-penicillaminato(2-)]-1:2κ^3N,S:S;1:6κ^3N,S:S;3:4κ^3S:N,S;4:5κ^3N,S:S-2,3,5,6-tetragold(I)-1,4-dinickel(II) ethanol monosolvate decahydrate

Hashimoto, Yuji; Taguchi, Mai; Yoshinari, Nobuto et al.

Acta Crystallographica Section C, 2010, 66(6), m160-m162

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Identifier to cite or link to this item: https://hdl.handle.net/11094/54381

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Title
Tetrapotassium [μ_2-N-carboxylato-D-penicillaminato(3-)-5:6κ^2S:S][μ_2-D-penicillaminato(1-)-2:3κ^2S:S]tetrakis[μ_2-D-penicillaminato(2-)]-1:2κ^3N,S:S;1:6κ^3N,S:S;3:4κ^3S:N,S;4:5κ^3N,S:S-2,3,5,6-tetragold(I)-1,4-dinickel(II) ethanol monosolvate decahydrate
Creator
CreatorName
Hashimoto, Yuji
CreatorName
Taguchi, Mai
NRID
1000010583338 1000010583338
ORCID
0000-0003-2457-0967 0000-0003-2457-0967
researchmap permalink
read0151149 read0151149
Scopus Author ID
14009212400 14009212400
CreatorName
Yoshinari, Nobuto
NRID
1000050201497 1000050201497
CreatorName
Konno, Takumi
Abstract
In the crystal structure of the title compound, K_4[Au_4Ni_2(C_6H_8NO_4S)(C_5H_9NO_2S)_4(C_5H_<10>NO_2S)]·C_2H_6O·10H_2O, (I), two planar [Ni(C_5H_9NO_2S)_2]^<2−> units are spanned by [Au_2(C_5H_<10>NO_2S)]^+ and [Au_2(C_6H_8NO_4S)]^− linkers through S atoms, forming an S:S-bridged Au^<I>_<4>Ni^<II>_<2> hexanuclear complex anion. One of six organic ligands in the complex anion is a carbamino derivative of d-penicillamine (3-mercaptovaline) and the others are deprotonated d-penicillamines. Each complex anion binds to nine K^+ ions through six carboxylate and one carbamino groups to construct a three-dimensional structure.
Publisher
International Union of Crystallography
Source Title
Acta Crystallographica Section C
Volume (Issue)
66(6)
Page
m160-m162
Date of Issued
2010-06
Language
English
Handle URL
https://hdl.handle.net/11094/54381
PISSN
01082701
Relation.references
URI
http://onlinelibrary.wiley.com/doi/10.1107/S0108270110016550/abstract
Relation.isIdenticalTo
DOI (Publisher Version)
https://doi.org/10.1107/S0108270110016550
Access Rights
open access
oaire:version
Version of Record
Category
学術雑誌論文 Journal Article