An optically resolved crystal of thiomalate : (S)-1-phenylethanaminium (R)-thiomalate

Igawa, Kosuke; Yoshinari, Nobuto; Konno, Takumi

Acta Crystallographica Section C, 2012, 68(9), o332-o334

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Identifier to cite or link to this item: https://hdl.handle.net/11094/54382

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Title
An optically resolved crystal of thiomalate : (S)-1-phenylethanaminium (R)-thiomalate
Creator
CreatorName
Igawa, Kosuke
NRID
1000010583338 1000010583338
ORCID
0000-0003-2457-0967 0000-0003-2457-0967
researchmap permalink
read0151149 read0151149
Scopus Author ID
14009212400 14009212400
CreatorName
Yoshinari, Nobuto
NRID
1000050201497 1000050201497
CreatorName
Konno, Takumi
Abstract
The asymmetric unit of the optically resolved title salt, C_8H_<12>N+·C_4H_5O_4S^−, contains a 1-phenylethanaminium monocation and a thiomalate (3-carboxy-2-sulfanylpropanoate) monoanion. The absolute configurations of the cation and the anion are determined to be S and R, respectively. In the crystal, cation–anion N—H...O hydrogen bonds, together with anion–anion O—H...O and S—H...O hydrogen bonds, construct a two-dimensional supramolecular sheet parallel to the ab plane. The two-dimensional sheet is linked with the upper and lower sheets through C—H...π interactions to stack along the c axis.
Publisher
International Union of Crystallography
Source Title
Acta Crystallographica Section C
Volume (Issue)
68(9)
Page
o332-o334
Date of Issued
2012-09
Language
English
Handle URL
https://hdl.handle.net/11094/54382
PISSN
01082701
Relation.references
URI
http://onlinelibrary.wiley.com/doi/10.1107/S0108270112032933/abstract
Relation.isIdenticalTo
DOI (Publisher Version)
https://doi.org/10.1107/S0108270112032933
Access Rights
open access
oaire:version
Version of Record
Category
学術雑誌論文 Journal Article