Air-Stable and Reusable Cobalt Phosphide Nanoalloy Catalyst for Selective Hydrogenation of Furfural Derivatives

Ishikawa, Hiroya; Sheng, Min; Nakata, Ayako; Nakajima, Kiyotaka; Yamazoe, Seiji; Yamasaki, Jun; Yamaguchi, Sho; Mizugaki, Tomoo; Mitsudome, Takato

doi:https://doi.org/10.1021/acscatal.0c03300

Air-Stable and Reusable Cobalt Phosphide Nanoalloy Catalyst for Selective Hydrogenation of Furfural Derivatives

Ishikawa, Hiroya; Sheng, Min; Nakata, Ayako et al.

ACS Catalysis, 2021, 11(2), 750-757

Number of Access:1,348（2025-08-14 15:06 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/78258

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Title	Air-Stable and Reusable Cobalt Phosphide Nanoalloy Catalyst for Selective Hydrogenation of Furfural Derivatives
Creator	CreatorName Ishikawa, Hiroya
	CreatorName Sheng, Min
	NRID 1000020595152 1000020595152 CreatorName Nakata, Ayako
	NRID 1000090451997 1000090451997 CreatorName Nakajima, Kiyotaka
	NRID 1000040510243 1000040510243 CreatorName Yamazoe, Seiji
	NRID 1000040335071 1000040335071 researchmap permalink read0054882 read0054882 Scopus Author ID 7006278028 7006278028 CreatorName Yamasaki, Jun
	NRID 1000050700150 1000050700150 researchmap permalink 7000018077 7000018077 Scopus Author ID 56424690000 56424690000 CreatorName Yamaguchi, Sho
	NRID 1000050314406 1000050314406 ORCID 0000-0001-5701-7530 0000-0001-5701-7530 researchmap permalink read0054694 read0054694 Scopus Author ID 7003481890 7003481890 CreatorName Mizugaki, Tomoo
	NRID 1000000437360 1000000437360 ORCID 0000-0003-3071-8243 0000-0003-3071-8243 researchmap permalink read0107411 read0107411 Scopus Author ID 11240122700 11240122700 CreatorName Mitsudome, Takato
Description	Hiroya Ishikawa, Min Sheng, Ayako Nakata, Kiyotaka Nakajima, Seiji Yamazoe, Jun Yamasaki, Sho Yamaguchi, Tomoo Mizugaki, and Takato Mitsudome. Air-Stable and Reusable Cobalt Phosphide Nanoalloy Catalyst for Selective Hydrogenation of Furfural Derivatives. ACS Catalysis 2021, 11, 750-757, DOI: 10.1021/acscatal.0c03300.
Description	This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in ACS Catalysis, copyright © American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/acscatal.0c03300.
Abstract	While metal phosphides have begun to attract attention as electrocatalysts, they remain underutilized in the field of liquid-phase molecular transformations. Herein, we describe a supported cobalt phosphide nanoalloy (nano-Co₂P) that functions as a highly efficient, reusable heterogeneous catalyst for the selective hydrogenation of furfural derivatives. The carbonyl moieties of several furfural derivatives were selectively hydrogenated to produce the desired products in high yields. In contrast to conventional nonprecious metal catalysts, nano-Co₂P uniquely exhibited air stability, which enabled easy and safe handling and precluded the need for H₂ pretreatment. Infrared and density functional theory studies revealed that the highly efficient hydrogenation is due to the favorable activation of the carbonyl moiety of furfural derivatives through the backdonation to its π* orbital from the Co d-electrons.
Publisher	American Chemical Society (ACS)
Source Title	ACS Catalysis
Volume (Issue)	11(2)
Page	750-757
Date of Issued	2021-01-15
Language	English
Handle URL	https://hdl.handle.net/11094/78258
eISSN	21555435
NCID	AA12599706
Relation.isVersionOf	DOI (Publisher Version) https://doi.org/10.1021/acscatal.0c03300
Access Rights	open access
CopyRight	© American Chemical Society
oaire:version	Accepted Manuscript
Category	学術雑誌論文 Journal Article

Resource Type	journal article
Local Type	Journal Article
DCMI Type	Text
DCTERMS.bibliographicCitation	ACS Catalysis. 2021, 11(2), p. 750-757
DC.title	Air-Stable and Reusable Cobalt Phosphide Nanoalloy Catalyst for Selective Hydrogenation of Furfural Derivatives
DC.creator	Ishikawa, Hiroya
	Sheng, Min
	Nakata, Ayako
	Nakajima, Kiyotaka
	Yamazoe, Seiji
	Yamasaki, Jun
	Yamaguchi, Sho
	Mizugaki, Tomoo
	Mitsudome, Takato
DC.publisher	American Chemical Society (ACS)
DC.language' scheme='DCTERMS.RFC1766	English
DC.type' scheme='DCTERMS.DCMIType	Text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2021-01-15
DC.identifier	https://doi.org/10.1021/acscatal.0c03300
DC.description	Hiroya Ishikawa, Min Sheng, Ayako Nakata, Kiyotaka Nakajima, Seiji Yamazoe, Jun Yamasaki, Sho Yamaguchi, Tomoo Mizugaki, and Takato Mitsudome. Air-Stable and Reusable Cobalt Phosphide Nanoalloy Catalyst for Selective Hydrogenation of Furfural Derivatives. ACS Catalysis 2021, 11, 750-757, DOI: 10.1021/acscatal.0c03300.
DC.description	This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in ACS Catalysis, copyright © American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/acscatal.0c03300.
DCTERMS.abstract	While metal phosphides have begun to attract attention as electrocatalysts, they remain underutilized in the field of liquid-phase molecular transformations. Herein, we describe a supported cobalt phosphide nanoalloy (nano-Co₂P) that functions as a highly efficient, reusable heterogeneous catalyst for the selective hydrogenation of furfural derivatives. The carbonyl moieties of several furfural derivatives were selectively hydrogenated to produce the desired products in high yields. In contrast to conventional nonprecious metal catalysts, nano-Co₂P uniquely exhibited air stability, which enabled easy and safe handling and precluded the need for H₂ pretreatment. Infrared and density functional theory studies revealed that the highly efficient hydrogenation is due to the favorable activation of the carbonyl moiety of furfural derivatives through the backdonation to its π* orbital from the Co d-electrons.
DC.rights	© American Chemical Society
DC.format	78258
citation_title	Air-Stable and Reusable Cobalt Phosphide Nanoalloy Catalyst for Selective Hydrogenation of Furfural Derivatives
citation_author	Ishikawa, Hiroya
	Sheng, Min
	Nakata, Ayako
	Nakajima, Kiyotaka
	Yamazoe, Seiji
	Yamasaki, Jun
	Yamaguchi, Sho
	Mizugaki, Tomoo
	Mitsudome, Takato
citation_publisher	American Chemical Society (ACS)
citation_language	English
citation_date	2021-01-15
citation_journal_title	ACS Catalysis
citation_volume	11
citation_issue	2
citation_firstpage	750
citation_lastpage	757
citation_doi	https://doi.org/10.1021/acscatal.0c03300
citation_public_url	https://hdl.handle.net/11094/78258

Air-Stable and Reusable Cobalt Phosphide Nanoalloy Catalyst for Selective Hydrogenation of Furfural Derivatives

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