Air-stable and reusable nickel phosphide nanoparticle catalyst for the highly selective hydrogenation of d-glucose to d-sorbitol

Yamaguchi, Sho; Fujita, Shu; Nakajima, Kiyotaka; Yamazoe, Seiji; Yamasaki, Jun; Mizugaki, Tomoo; Mitsudome, Takato

doi:https://doi.org/10.1039/D0GC03301D

Air-stable and reusable nickel phosphide nanoparticle catalyst for the highly selective hydrogenation of d-glucose to d-sorbitol

Yamaguchi, Sho; Fujita, Shu; Nakajima, Kiyotaka et al.

Green Chemistry, 2021, 23(5), 2010-2016

Number of Access:1,493（2025-08-15 22:51 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/79298

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Title	Air-stable and reusable nickel phosphide nanoparticle catalyst for the highly selective hydrogenation of d-glucose to d-sorbitol
Creator	NRID 1000050700150 1000050700150 researchmap permalink 7000018077 7000018077 Scopus Author ID 56424690000 56424690000 CreatorName Yamaguchi, Sho
	CreatorName Fujita, Shu
	NRID 1000090451997 1000090451997 CreatorName Nakajima, Kiyotaka
	NRID 1000040510243 1000040510243 CreatorName Yamazoe, Seiji
	NRID 1000040335071 1000040335071 researchmap permalink read0054882 read0054882 Scopus Author ID 7006278028 7006278028 CreatorName Yamasaki, Jun
	NRID 1000050314406 1000050314406 ORCID 0000-0001-5701-7530 0000-0001-5701-7530 researchmap permalink read0054694 read0054694 Scopus Author ID 7003481890 7003481890 CreatorName Mizugaki, Tomoo
	NRID 1000000437360 1000000437360 ORCID 0000-0003-3071-8243 0000-0003-3071-8243 researchmap permalink read0107411 read0107411 Scopus Author ID 11240122700 11240122700 CreatorName Mitsudome, Takato
Description	Reproduced from Ref. Green Chem., 2021, 23, pp. 2010-2016. with permission from the Royal Society of Chemistry.
Abstract	The hydrogenation of carbohydrates to polyols is an industrially important process, but it requires air-unstable, non-noble metal catalysts with low activity and harsh reaction conditions. Herein, we report a hydrotalcite (HT)-supported nickel phosphide nanoparticle (nano-Ni₂P/HT) that exhibits both air stability and high activity for the selective hydrogenation of d-glucose to d-sorbitol in water. The nano-Ni₂P/HT catalyst provides d-sorbitol in excellent yield with >99% selectivity under mild reaction conditions, and is the first non-noble metal catalyst that can operate under just 1 bar of H₂ or at ambient temperature. This high-performance nano-Ni₂P/HT catalyst is significantly different from conventional Ni(0) and NiO nanoparticles and Raney catalysts, which result in almost no production of d-sorbitol, demonstrating the unique catalysis of nano-Ni₂P/HT. Furthermore, nano-Ni₂P/HT shows the highest activity among those reported for non-noble metal catalysts. The nano-Ni₂P/HT catalyst can also be reused without sacrificing its high activity and selectivity. Additionally, the successful transformation of a concentrated d-glucose solution (50 wt%) to d-sorbitol has been achieved. This is the first example of an air-stable, highly active, and reusable non-noble metal catalyst that can replace conventional catalysts used for d-sorbitol production, thus providing a cheap, green, and sustainable route for this process.
Publisher	Royal Society of Chemistry
Source Title	Green Chemistry
Volume (Issue)	23(5)
Page	2010-2016
Date of Issued	2021-03-07
Language	English
Handle URL	https://hdl.handle.net/11094/79298
PISSN	14639262
eISSN	14639270
Relation.isVersionOf	DOI (Publisher Version) https://doi.org/10.1039/D0GC03301D
Access Rights	open access
oaire:version	Accepted Manuscript
Category	学術雑誌論文 Journal Article

Resource Type	journal article
Local Type	Journal Article
DCMI Type	Text
DCTERMS.bibliographicCitation	Green Chemistry. 2021, 23(5), p. 2010-2016
DC.title	Air-stable and reusable nickel phosphide nanoparticle catalyst for the highly selective hydrogenation of d-glucose to d-sorbitol
DC.creator	Yamaguchi, Sho
	Fujita, Shu
	Nakajima, Kiyotaka
	Yamazoe, Seiji
	Yamasaki, Jun
	Mizugaki, Tomoo
	Mitsudome, Takato
DC.publisher	Royal Society of Chemistry
DC.language' scheme='DCTERMS.RFC1766	English
DC.type' scheme='DCTERMS.DCMIType	Text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2021-03-07
DC.identifier	https://doi.org/10.1039/D0GC03301D
DC.description	Reproduced from Ref. Green Chem., 2021, 23, pp. 2010-2016. with permission from the Royal Society of Chemistry.
DCTERMS.abstract	The hydrogenation of carbohydrates to polyols is an industrially important process, but it requires air-unstable, non-noble metal catalysts with low activity and harsh reaction conditions. Herein, we report a hydrotalcite (HT)-supported nickel phosphide nanoparticle (nano-Ni₂P/HT) that exhibits both air stability and high activity for the selective hydrogenation of d-glucose to d-sorbitol in water. The nano-Ni₂P/HT catalyst provides d-sorbitol in excellent yield with >99% selectivity under mild reaction conditions, and is the first non-noble metal catalyst that can operate under just 1 bar of H₂ or at ambient temperature. This high-performance nano-Ni₂P/HT catalyst is significantly different from conventional Ni(0) and NiO nanoparticles and Raney catalysts, which result in almost no production of d-sorbitol, demonstrating the unique catalysis of nano-Ni₂P/HT. Furthermore, nano-Ni₂P/HT shows the highest activity among those reported for non-noble metal catalysts. The nano-Ni₂P/HT catalyst can also be reused without sacrificing its high activity and selectivity. Additionally, the successful transformation of a concentrated d-glucose solution (50 wt%) to d-sorbitol has been achieved. This is the first example of an air-stable, highly active, and reusable non-noble metal catalyst that can replace conventional catalysts used for d-sorbitol production, thus providing a cheap, green, and sustainable route for this process.
DC.format	79298
citation_title	Air-stable and reusable nickel phosphide nanoparticle catalyst for the highly selective hydrogenation of d-glucose to d-sorbitol
citation_author	Yamaguchi, Sho
	Fujita, Shu
	Nakajima, Kiyotaka
	Yamazoe, Seiji
	Yamasaki, Jun
	Mizugaki, Tomoo
	Mitsudome, Takato
citation_publisher	Royal Society of Chemistry
citation_language	English
citation_date	2021-03-07
citation_journal_title	Green Chemistry
citation_volume	23
citation_issue	5
citation_firstpage	2010
citation_lastpage	2016
citation_doi	https://doi.org/10.1039/D0GC03301D
citation_public_url	https://hdl.handle.net/11094/79298

Air-stable and reusable nickel phosphide nanoparticle catalyst for the highly selective hydrogenation of d-glucose to d-sorbitol

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