Ni₂P Nanoalloy as an Air-Stable and Versatile Hydrogenation Catalyst in Water : P-Alloying Strategy for Designing Smart Catalysts

Fujita, Shu; Yamaguchi, Sho; Yamasaki, Jun; Nakajima, Kiyotaka; Yamazoe, Seiji; Mizugaki, Tomoo; Mitsudome, Takato

doi:https://doi.org/10.1002/chem.202005037

Ni₂P Nanoalloy as an Air-Stable and Versatile Hydrogenation Catalyst in Water : P-Alloying Strategy for Designing Smart Catalysts

Fujita, Shu; Yamaguchi, Sho; Yamasaki, Jun et al.

Chemistry : A European Journal, 2021, 27(13), 4439-4446

Number of Access:1,658（2025-09-30 11:15 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/79299

Link to primary information

File	Format	Terms of use	Size	Views	Date.Available	Description	information
ChemEurJ_27_13_4439	pdf	None	947 KB	246	2022.03.02

Item Information

Output File Export EndNote Basic Export Mendeley

Title	Ni₂P Nanoalloy as an Air-Stable and Versatile Hydrogenation Catalyst in Water : P-Alloying Strategy for Designing Smart Catalysts
Creator	CreatorName Fujita, Shu
	NRID 1000050700150 1000050700150 researchmap permalink 7000018077 7000018077 Scopus Author ID 56424690000 56424690000 CreatorName Yamaguchi, Sho
	NRID 1000040335071 1000040335071 researchmap permalink read0054882 read0054882 Scopus Author ID 7006278028 7006278028 CreatorName Yamasaki, Jun
	NRID 1000090451997 1000090451997 CreatorName Nakajima, Kiyotaka
	NRID 1000040510243 1000040510243 CreatorName Yamazoe, Seiji
	NRID 1000050314406 1000050314406 ORCID 0000-0001-5701-7530 0000-0001-5701-7530 researchmap permalink read0054694 read0054694 Scopus Author ID 7003481890 7003481890 CreatorName Mizugaki, Tomoo
	NRID 1000000437360 1000000437360 ORCID 0000-0003-3071-8243 0000-0003-3071-8243 researchmap permalink read0107411 read0107411 Scopus Author ID 11240122700 11240122700 CreatorName Mitsudome, Takato
Subject	carbonyl
	heterogeneous catalysis
	hydrogenation
	nickel phosphide
	nitrile
Description	This is the peer reviewed version of the following article: S. Fujita, S. Yamaguchi, J. Yamasaki, K. Nakajima, S. Yamazoe, T. Mizugaki, T. Mitsudome, Chem. Eur. J. 2021, 27, 4439., which has been published in final form at https://doi.org/10.1002/chem.202005037. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
Abstract	Non-noble metal-based hydrogenation catalysts have limited practical applications because they exhibit low activity, require harsh reaction conditions, and are unstable in air. To overcome these limitations, herein we propose the alloying of non-noble metal nanoparticles with phosphorus as a promising strategy for developing smart catalysts that exhibit both excellent activity and air stability. We synthesized a novel nickel phosphide nanoalloy (nano-Ni₂P) with coordinatively unsaturated Ni active sites. Unlike conventional air-unstable non-noble metal catalysts, nano-Ni₂P retained its metallic nature in air, and exhibited a high activity for the hydrogenation of various substrates with polar functional groups, such as aldehydes, ketones, nitriles, and nitroarenes to the desired products in excellent yields in water. Furthermore, the used nano-Ni₂P catalyst was easy to handle in air and could be reused without pretreatment, providing a simple and clean catalyst system for general hydrogenation reactions.
Publisher	Wiley-VCH Verlag
Source Title	Chemistry : A European Journal
Volume (Issue)	27(13)
Page	4439-4446
Date of Issued	2021-03-01
Language	English
Handle URL	https://hdl.handle.net/11094/79299
PISSN	09476539
eISSN	15213765
Relation.isVersionOf	DOI (Publisher Version) https://doi.org/10.1002/chem.202005037
Relation.isIdenticalTo	PMID 33283374
Access Rights	open access
oaire:version	Accepted Manuscript
Category	学術雑誌論文 Journal Article

Resource Type	journal article
Local Type	Journal Article
DCMI Type	Text
DCTERMS.bibliographicCitation	Chemistry : A European Journal. 2021, 27(13), p. 4439-4446
DC.title	Ni₂P Nanoalloy as an Air-Stable and Versatile Hydrogenation Catalyst in Water : P-Alloying Strategy for Designing Smart Catalysts
DC.creator	Fujita, Shu
	Yamaguchi, Sho
	Yamasaki, Jun
	Nakajima, Kiyotaka
	Yamazoe, Seiji
	Mizugaki, Tomoo
	Mitsudome, Takato
DC.publisher	Wiley-VCH Verlag
DC.language' scheme='DCTERMS.RFC1766	English
DC.type' scheme='DCTERMS.DCMIType	Text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2021-03-01
DC.identifier	https://doi.org/10.1002/chem.202005037
DC.subject	carbonyl
	heterogeneous catalysis
	hydrogenation
	nickel phosphide
	nitrile
DC.description	This is the peer reviewed version of the following article: S. Fujita, S. Yamaguchi, J. Yamasaki, K. Nakajima, S. Yamazoe, T. Mizugaki, T. Mitsudome, Chem. Eur. J. 2021, 27, 4439., which has been published in final form at https://doi.org/10.1002/chem.202005037. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
DCTERMS.abstract	Non-noble metal-based hydrogenation catalysts have limited practical applications because they exhibit low activity, require harsh reaction conditions, and are unstable in air. To overcome these limitations, herein we propose the alloying of non-noble metal nanoparticles with phosphorus as a promising strategy for developing smart catalysts that exhibit both excellent activity and air stability. We synthesized a novel nickel phosphide nanoalloy (nano-Ni₂P) with coordinatively unsaturated Ni active sites. Unlike conventional air-unstable non-noble metal catalysts, nano-Ni₂P retained its metallic nature in air, and exhibited a high activity for the hydrogenation of various substrates with polar functional groups, such as aldehydes, ketones, nitriles, and nitroarenes to the desired products in excellent yields in water. Furthermore, the used nano-Ni₂P catalyst was easy to handle in air and could be reused without pretreatment, providing a simple and clean catalyst system for general hydrogenation reactions.
DC.format	79299
citation_title	Ni₂P Nanoalloy as an Air-Stable and Versatile Hydrogenation Catalyst in Water : P-Alloying Strategy for Designing Smart Catalysts
citation_author	Fujita, Shu
	Yamaguchi, Sho
	Yamasaki, Jun
	Nakajima, Kiyotaka
	Yamazoe, Seiji
	Mizugaki, Tomoo
	Mitsudome, Takato
citation_publisher	Wiley-VCH Verlag
citation_language	English
citation_date	2021-03-01
citation_journal_title	Chemistry : A European Journal
citation_volume	27
citation_issue	13
citation_firstpage	4439
citation_lastpage	4446
citation_doi	https://doi.org/10.1002/chem.202005037
citation_pmid	33283374
citation_public_url	https://hdl.handle.net/11094/79299

Ni₂P Nanoalloy as an Air-Stable and Versatile Hydrogenation Catalyst in Water : P-Alloying Strategy for Designing Smart Catalysts

Link to primary information

Item Information

Show details