journal article

Journal Article

Text

The Journal of Chemical Physics. 2018, 148(13), p. 134707

Molecular dynamics analysis of the influence of Coulomb and van der Waals interactions on the work of adhesion at the solid-liquid interface

American Institute of Physics

English

Text

2018-04-07

https://doi.org/10.1063/1.5019185

Donatas Surblys, Frédéric Leroy, Yasutaka Yamaguchi, and Florian Müller-Plathe, "Molecular dynamics analysis of the influence of Coulomb and van der Waals interactions on the work of adhesion at the solid-liquid interface", The Journal of Chemical Physics 148, 134707 (2018) https://doi.org/10.1063/1.5019185.

We investigated the solid-liquid work of adhesion of water on a model silica surface by molecular dynamics simulations, where a methodology previously developed to determine the work of adhesion through thermodynamic integration was extended to a system with long-range electrostatic interactions between solid and liquid. In agreement with previous studies, the work of adhesion increased when the magnitude of the surface polarity was increased. On the other hand, we found that when comparing two systems with and without solid-liquid electrostatic interactions, which were set to have approximately the same total solid-liquid interfacial energy, former had a significantly smaller work of adhesion and a broader distribution in the interfacial energies, which has not been previously reported in detail. This was explained by the entropy contribution to the adhesion free energy; i.e., the former with a broader energy distribution had a larger interfacial entropy than the latter. While the entropy contribution to the work of adhesion has already been known, as a work of adhesion itself is free energy, these results indicate that, contrary to common belief, wetting behavior such as the contact angle is not only governed by the interfacial energy but also significantly affected by the interfacial entropy. Finally, a new interpretation of interfacial entropy in the context of solid-liquid energy variance was offered, from which a fast way to qualitatively estimate the work of adhesion was also presented.

This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. This article appeared in The Journal of Chemical Physics 148, 134707 (2018) and may be found at https://doi.org/10.1063/1.5019185.

82376

Molecular dynamics analysis of the influence of Coulomb and van der Waals interactions on the work of adhesion at the solid-liquid interface

American Institute of Physics

English

2018-04-07

The Journal of Chemical Physics

148

13

134707

https://doi.org/10.1063/1.5019185

29626889

https://hdl.handle.net/11094/82376