Utilization of sulfur function in directed catalytic C-H transformation: site-selective substitution on indole and naphthalene skeletons

Nishii, Yuji; Miura, Masahiro

doi:https://doi.org/10.1080/10426507.2022.2152815

Utilization of sulfur function in directed catalytic C-H transformation: site-selective substitution on indole and naphthalene skeletons

Nishii, Yuji; Miura, Masahiro

Phosphorus, Sulfur, and Silicon and the Related Elements, 2022, 198(6), 486-492

Number of Access:172（2025-06-05 02:17 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/89666

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Title	Utilization of sulfur function in directed catalytic C-H transformation: site-selective substitution on indole and naphthalene skeletons
Creator	NRID 1000070773787 1000070773787 ORCID 0000-0002-6824-0639 0000-0002-6824-0639 researchmap permalink y_nishii y_nishii Scopus Author ID 55233363700 55233363700 CreatorName Nishii, Yuji
Creator	NRID 1000020183626 1000020183626 ORCID 0000-0001-8288-6439 0000-0001-8288-6439 researchmap permalink read0013936 read0013936 Scopus Author ID 7402799909 7402799909 CreatorName Miura, Masahiro
Subject	C-H transformation
	Thioether
	Indole
	Rhodium
	Iridium
Description	This is an Accepted Manuscript of an article published by Taylor & Francis in Phosphorus, Sulfur, and Silicon and the Related Elements on 6 Dec 2022, available at https://doi.org/10.1080/10426507.2022.2152815.
Abstract	Sulfur-containing functional groups, among various coordinating functions, have recently attracted attention as useful directing groups for the direct catalytic C-H transformation of aromatic and heteroaromatic compounds. Herein we briefly summarize our recent work on the site-selective substitution on indole and naphthalene skeletons using thioether directing groups under either CpRh(III) or CpIr(III) catalysis. The thioether groups can readily be removed and transformed to other functional groups. The reactions developed appear to be of importance in pharmaceutical and materials chemistry.
Publisher	Taylor & Francis
Source Title	Phosphorus, Sulfur, and Silicon and the Related Elements
Volume (Issue)	198(6)
Page	486-492
Date of Issued	2022-12-06
Language	English
Handle URL	https://hdl.handle.net/11094/89666
PISSN	10426507
eISSN	15635325
Relation.isVersionOf	DOI (Publisher Version) https://doi.org/10.1080/10426507.2022.2152815
Access Rights	open access
oaire:version	Accepted Manuscript
Category	学術雑誌論文 Journal Article

Resource Type	journal article
Local Type	Journal Article
DCMI Type	Text
DCTERMS.bibliographicCitation	Phosphorus, Sulfur, and Silicon and the Related Elements. 2022, 198(6), p. 486-492
DC.title	Utilization of sulfur function in directed catalytic C-H transformation: site-selective substitution on indole and naphthalene skeletons
DC.creator	Nishii, Yuji
DC.creator	Miura, Masahiro
DC.publisher	Taylor & Francis
DC.language' scheme='DCTERMS.RFC1766	English
DC.type' scheme='DCTERMS.DCMIType	Text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2022-12-06
DC.identifier	https://doi.org/10.1080/10426507.2022.2152815
DC.subject	C-H transformation
	Thioether
	Indole
	Rhodium
	Iridium
DC.description	This is an Accepted Manuscript of an article published by Taylor & Francis in Phosphorus, Sulfur, and Silicon and the Related Elements on 6 Dec 2022, available at https://doi.org/10.1080/10426507.2022.2152815.
DCTERMS.abstract	Sulfur-containing functional groups, among various coordinating functions, have recently attracted attention as useful directing groups for the direct catalytic C-H transformation of aromatic and heteroaromatic compounds. Herein we briefly summarize our recent work on the site-selective substitution on indole and naphthalene skeletons using thioether directing groups under either CpRh(III) or CpIr(III) catalysis. The thioether groups can readily be removed and transformed to other functional groups. The reactions developed appear to be of importance in pharmaceutical and materials chemistry.
DC.format	89666
citation_title	Utilization of sulfur function in directed catalytic C-H transformation: site-selective substitution on indole and naphthalene skeletons
citation_author	Nishii, Yuji
citation_author	Miura, Masahiro
citation_publisher	Taylor & Francis
citation_language	English
citation_date	2022-12-06
citation_journal_title	Phosphorus, Sulfur, and Silicon and the Related Elements
citation_volume	198
citation_issue	6
citation_firstpage	486
citation_lastpage	492
citation_doi	https://doi.org/10.1080/10426507.2022.2152815
citation_public_url	https://hdl.handle.net/11094/89666

Utilization of sulfur function in directed catalytic C-H transformation: site-selective substitution on indole and naphthalene skeletons

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