Rhodium-catalyzed Decarbonylation of Acylsilanes

Yoshida, Tomoki; Kodama, Takuya; Tobisu, Mamoru

Asian Journal of Organic Chemistry, 2022, 11(12), e202200610

Number of Access:675（2025-08-01 03:04 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/89944

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Title
Rhodium-catalyzed Decarbonylation of Acylsilanes
Creator
CreatorName
Yoshida, Tomoki
NRID
1000080823989 1000080823989
ORCID
0000-0001-8275-2393 0000-0001-8275-2393
researchmap permalink
kdm kdm
Scopus Author ID
56522275700 56522275700
CreatorName
Kodama, Takuya
NRID
1000060403143 1000060403143
researchmap permalink
read0156480 read0156480
Scopus Author ID
6506514402 6506514402
ORCID
0000-0002-8415-2225 0000-0002-8415-2225
CreatorName
Tobisu, Mamoru
Description
This is the peer reviewed version of the following article: Yoshida, T., Kodama, T., Tobisu, M., Asian J. Org. Chem. 2022, 11, e202200610 which has been published in final form at https://doi.org/10.1002/ajoc.202200610. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.
Abstract
The rhodium-catalyzed decarbonylation of acylsilanes is reported. This reaction proceeds through the cleavage of a carbon–silicon bond in acylsilanes. When two different acylsilanes are reacted in one batch, crossover products are formed. These results indicate that two mechanisms are operating in this catalytic reaction.
Publisher
John Wiley and Sons Inc
Source Title
Asian Journal of Organic Chemistry
Volume (Issue)
11(12)
Page
e202200610
Date of Issued
2022-12-16
Language
English
Handle URL
https://hdl.handle.net/11094/89944
PISSN
21935807
NCID
AA12586329
Relation.isVersionOf
DOI (Publisher Version)
https://doi.org/10.1002/ajoc.202200610
Access Rights
open access
CopyRight
© 2022 Wiley-VCH GmbH
oaire:version
Accepted Manuscript
Category
学術雑誌論文 Journal Article