Paramagnetic nitroxide radical liquid crystalline compounds with methyl di(ethylene glycol) chain

Akita, Takuya; Uchida, Yoshiaki; Kiyohara, Daichi et al.

Ferroelectrics, 2016, 495(1), 97-104

Number of Access:620（2025-08-28 23:54 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/91450

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Title
Paramagnetic nitroxide radical liquid crystalline compounds with methyl di(ethylene glycol) chain
Creator
CreatorName
Akita, Takuya
NRID
1000060559558 1000060559558
ORCID
0000-0001-5043-9239 0000-0001-5043-9239
researchmap permalink
Yoshiaki_Uchida Yoshiaki_Uchida
Scopus Author ID
8348749200 8348749200
CreatorName
Uchida, Yoshiaki
CreatorName
Kiyohara, Daichi
CreatorName
Nakagami, Sho
NRID
1000010283730 1000010283730
researchmap permalink
read0046501 read0046501
Scopus Author ID
7201750198 7201750198
CreatorName
Nishiyama, Norikazu
Subject
chiral nematic phase
di (ethylene glycol) chain
enantiomeric resolution
molecular design
nematic phase
nitroxide radicals
Paramagnetic chiral liquid crystals
Description
This is an Accepted Manuscript of an article published by Taylor & Francis in Ferroelectrics on 2 May 2016, available at https://doi.org/10.1080/00150193.2016.1136767.
Abstract
We have synthesized a racemic and enantiomerically enriched all-organic paramagnetic nitroxide radical (NR) liquid crystalline (LC) compound, which contains a chiral NR unit in the mesogen core and a methyl di(ethylene glycol) chain as one of their terminal units. These new compounds showed remarkable substituent effects of the methyl di(ethylene glycol) chain on the phase transition behaviors and hydrophilic properties in contrast to structural analogs of the previous reported NR-LC compounds containing alkoxy chains.
Publisher
Taylor and Francis Inc.325 Chestnut St, Suite 800PhiladelphiaPA 19106
Source Title
Ferroelectrics
Volume (Issue)
495(1)
Page
97-104
Date of Issued
2016-05-02
Language
English
Handle URL
https://hdl.handle.net/11094/91450
PISSN
00150193
eISSN
15635112
Relation.isVersionOf
DOI (Publisher Version)
https://doi.org/10.1080/00150193.2016.1136767
Access Rights
open access
oaire:version
Accepted Manuscript
Category
会議発表論文 Conference Paper