A nanosheet molding method to estimate the size of bilayers suspended in liquids

Sasaki, Koki; Hernandez Gaitan, Jose A.; Tokuda, Yuki; Miyake, Koji; Uchida, Yoshiaki; Nishiyama, Norikazu

doi:https://doi.org/10.1039/D2TC03765C

A nanosheet molding method to estimate the size of bilayers suspended in liquids

Sasaki, Koki; Hernandez Gaitan, Jose A.; Tokuda, Yuki et al.

Journal of Materials Chemistry C, 2022, 10(42), 15816-15821

Number of Access:670（2025-08-14 07:35 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/91521

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Title	A nanosheet molding method to estimate the size of bilayers suspended in liquids
Creator	CreatorName Sasaki, Koki
	CreatorName Hernandez Gaitan, Jose A.
	CreatorName Tokuda, Yuki
	ORCID 0000-0001-9868-5391 0000-0001-9868-5391 researchmap permalink 7000028816 7000028816 Scopus Author ID 56594314800 56594314800 NRID 1000040844717 1000040844717 CreatorName Miyake, Koji
	NRID 1000060559558 1000060559558 ORCID 0000-0001-5043-9239 0000-0001-5043-9239 researchmap permalink Yoshiaki_Uchida Yoshiaki_Uchida Scopus Author ID 8348749200 8348749200 CreatorName Uchida, Yoshiaki
	NRID 1000010283730 1000010283730 researchmap permalink read0046501 read0046501 Scopus Author ID 7201750198 7201750198 CreatorName Nishiyama, Norikazu
Description	Sasaki K., Hernandez Gaitan J.A., Tokuda Y., et al. A nanosheet molding method to estimate the size of bilayers suspended in liquids. Journal of Materials Chemistry C 10, 15816 (2022); https://doi.org/10.1039/D2TC03765C.
Abstract	Various methods have been developed to determine the size of molecular bilayer structures dispersed in liquids. We focused on the nanosheet (NS) growth inside the bilayers in hyperswollen lamellar (HL) phases. Here, we propose the method to evaluate the size of bilayers in liquid by observing palladium NSs (PdNSs) growing rapidly in the bilayers of the HL phase. It uncovered that the width of PdNSs depends on methanol concentration, on which the stability of the HL phase also depends. Considering that the stability of the HL phase is positively correlated with the width of bilayers, we concluded that the observation of PdNSs probably corresponds to the indirect measurement of the width of bilayers. This method will also be applied to various other bilayers. Moreover, the PdNSs of a few nanometers in thickness and several hundred nanometers in width show higher catalytic activity for the reduction reaction of 4-nitrophenol to 4-aminophenol than the previously reported Pd catalysts without any supports.
Publisher	Royal Society of Chemistry
Source Title	Journal of Materials Chemistry C
Volume (Issue)	10(42)
Page	15816-15821
Date of Issued	2022-10-19
Language	English
Handle URL	https://hdl.handle.net/11094/91521
eISSN	20507526
NCID	AA12605026
Relation.isVersionOf	DOI (Publisher Version) https://doi.org/10.1039/D2TC03765C
Access Rights	open access
CopyRight	Reproduced from J. Mater. Chem. C, 2022, 10, 15816-15821 with permission from the Royal Society of Chemistry.
oaire:version	Accepted Manuscript
Category	学術雑誌論文 Journal Article

Resource Type	journal article
Local Type	Journal Article
DCMI Type	Text
DCTERMS.bibliographicCitation	Journal of Materials Chemistry C. 2022, 10(42), p. 15816-15821
DC.title	A nanosheet molding method to estimate the size of bilayers suspended in liquids
DC.creator	Sasaki, Koki
	Hernandez Gaitan, Jose A.
	Tokuda, Yuki
	Miyake, Koji
	Uchida, Yoshiaki
	Nishiyama, Norikazu
DC.publisher	Royal Society of Chemistry
DC.language' scheme='DCTERMS.RFC1766	English
DC.type' scheme='DCTERMS.DCMIType	Text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2022-10-19
DC.identifier	https://doi.org/10.1039/D2TC03765C
DC.description	Sasaki K., Hernandez Gaitan J.A., Tokuda Y., et al. A nanosheet molding method to estimate the size of bilayers suspended in liquids. Journal of Materials Chemistry C 10, 15816 (2022); https://doi.org/10.1039/D2TC03765C.
DCTERMS.abstract	Various methods have been developed to determine the size of molecular bilayer structures dispersed in liquids. We focused on the nanosheet (NS) growth inside the bilayers in hyperswollen lamellar (HL) phases. Here, we propose the method to evaluate the size of bilayers in liquid by observing palladium NSs (PdNSs) growing rapidly in the bilayers of the HL phase. It uncovered that the width of PdNSs depends on methanol concentration, on which the stability of the HL phase also depends. Considering that the stability of the HL phase is positively correlated with the width of bilayers, we concluded that the observation of PdNSs probably corresponds to the indirect measurement of the width of bilayers. This method will also be applied to various other bilayers. Moreover, the PdNSs of a few nanometers in thickness and several hundred nanometers in width show higher catalytic activity for the reduction reaction of 4-nitrophenol to 4-aminophenol than the previously reported Pd catalysts without any supports.
DC.rights	Reproduced from J. Mater. Chem. C, 2022, 10, 15816-15821 with permission from the Royal Society of Chemistry.
DC.format	91521
citation_title	A nanosheet molding method to estimate the size of bilayers suspended in liquids
citation_author	Sasaki, Koki
	Hernandez Gaitan, Jose A.
	Tokuda, Yuki
	Miyake, Koji
	Uchida, Yoshiaki
	Nishiyama, Norikazu
citation_publisher	Royal Society of Chemistry
citation_language	English
citation_date	2022-10-19
citation_journal_title	Journal of Materials Chemistry C
citation_volume	10
citation_issue	42
citation_firstpage	15816
citation_lastpage	15821
citation_doi	https://doi.org/10.1039/D2TC03765C
citation_public_url	https://hdl.handle.net/11094/91521

A nanosheet molding method to estimate the size of bilayers suspended in liquids

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