Single‐Crystal‐to‐Single‐Crystal Installation of Ln₄(OH)₄ Cubanes in an Anionic Metallosupramolecular Framework

Yoshinari, Nobuto; Meundaeng, Natthaya; Tabe, Hiroyasu et al.

Angewandte Chemie, 2020, 132(41), 18204-18209

Number of Access:724（2025-08-20 22:57 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/92447

Link to primary information 

File Format Terms of use Size Views Date.Available Description information
AngewChem_132_41_18204 pdf None 448 KB 69 2023.08.23  

Item Information

Output File Export EndNote Basic Export Mendeley

Title
Single‐Crystal‐to‐Single‐Crystal Installation of Ln₄(OH)₄ Cubanes in an Anionic Metallosupramolecular Framework
Creator
NRID
1000010583338 1000010583338
ORCID
0000-0003-2457-0967 0000-0003-2457-0967
researchmap permalink
read0151149 read0151149
Scopus Author ID
14009212400 14009212400
CreatorName
Yoshinari, Nobuto
CreatorName
Meundaeng, Natthaya
NRID
1000050803764 1000050803764
CreatorName
Tabe, Hiroyasu
NRID
1000030358270 1000030358270
CreatorName
Yamada, Yusuke
NRID
1000040587466 1000040587466
researchmap permalink
sayamash sayamash
Scopus Author ID
55210349200 55210349200
CreatorName
Yamashita, Satoshi
NRID
1000060222163 1000060222163
researchmap permalink
thermo102 thermo102
Scopus Author ID
55556980600 55556980600
CreatorName
Nakazawa, Yasuhiro
Scopus Author ID
7202325347 7202325347
NRID
1000050201497 1000050201497
researchmap permalink
takumikonno takumikonno
CreatorName
Konno, Takumi
Subject
Cluster compounds
Crystal engineering
Lanthanides
Postsynthetic modification
Description
This is the accepted version of the following article: Yoshinari Nobuto, Meundaeng Natthaya, Tabe Hiroyasu, et al. Single‐Crystal‐to‐Single‐Crystal Installation of Ln₄(OH)₄ Cubanes in an Anionic Metallosupramolecular Framework. Angewandte Chemie 132, 18204 (2020), which has been published in final form at https://doi.org/10.1002/ange.202008296. This article may be used for non-commercialpurposes in accordance with the Wiley Self-ArchivingPolicy [https://authorservices.wiley.com/author-resources/Journal-Authors/licensing/self-archiving.html]
Abstract
Postsynthetic installation of lanthanide cubanes into a metallosupramolecular framework via a single-crystal-to-single-crystal (SCSC) transformation is presented. Soaking single crystals of K6[Rh4Zn4O(l-cys)12] (K6[1]; l-H2cys=l-cysteine) in a water/ethanol solution containing Ln(OAc)3 (Ln3+=lanthanide ion) results in the exchange of K+ by Ln3+ with retention of the single crystallinity, producing Ln2[1] (2Ln) and Ln0.33[Ln4(OH)4(OAc)3(H2O)7][1] (3Ln) for early and late lanthanides, respectively. While the Ln3+ ions in 2Ln exist as disordered aqua species, those in 3Ln form ordered hydroxide-bridged cubane clusters that connect [1]6− anions in a 3D metal-organic framework through coordination bonds with carboxylate groups. This study shows the utility of an anionic metallosupramolecular framework with carboxylate groups for the creation of a series of metal cubanes that have great potential for various applications, such as magnetic materials and heterogeneous catalysts.
Publisher
Wiley
Source Title
Angewandte Chemie
Volume (Issue)
132(41)
Page
18204-18209
Date of Issued
2020-08-13
Language
English
Handle URL
https://hdl.handle.net/11094/92447
PISSN
00448249
eISSN
15213757
NCID
AA11614145
Relation.isVersionOf
DOI (Publisher Version)
https://doi.org/10.1002/ange.202008296
Access Rights
open access
CopyRight
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA.
oaire:version
Accepted Manuscript
Category
学術雑誌論文 Journal Article