One-Step Synthesis of Benzophosphole Derivatives from Arylalkynes by Phosphenium-Dication-Mediated Sequential C-P/C-C Bond Forming Reaction

Nishimura, Kazutoshi; Xu, Shibo; Nishii, Yuji; Hirano, Koji

doi:https://doi.org/10.1021/acs.orglett.3c00263

One-Step Synthesis of Benzophosphole Derivatives from Arylalkynes by Phosphenium-Dication-Mediated Sequential C-P/C-C Bond Forming Reaction

Nishimura, Kazutoshi; Xu, Shibo; Nishii, Yuji et al.

Organic Letters, 2023, 25(9), 1503-1508

Number of Access:547（2025-12-22 01:33 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/92684

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Title	One-Step Synthesis of Benzophosphole Derivatives from Arylalkynes by Phosphenium-Dication-Mediated Sequential C-P/C-C Bond Forming Reaction
Creator	CreatorName Nishimura, Kazutoshi
	CreatorName Xu, Shibo
	NRID 1000070773787 1000070773787 ORCID 0000-0002-6824-0639 0000-0002-6824-0639 researchmap permalink y_nishii y_nishii Scopus Author ID 55233363700 55233363700 CreatorName Nishii, Yuji
	NRID 1000070532696 1000070532696 ORCID 0000-0001-9752-1985 0000-0001-9752-1985 researchmap permalink koj koj Scopus Author ID 7402407063 7402407063 CreatorName Hirano, Koji
Description	Nishimura K., Xu S., Nishii Y., et al. One-Step Synthesis of Benzophosphole Derivatives from Arylalkynes by Phosphenium-Dication-Mediated Sequential C-P/C-C Bond Forming Reaction. Organic Letters. 25(9), 1503-1508, 10 March 2023; © 2023 American Chemical Society. https://doi.org/10.1021/acs.orglett.3c00263.
Abstract	A metal-free, phosphenium-dication-mediated sequential C-P and C-C bond forming reaction has been developed. This protocol can provide concise access to the (di)benzophosphole derivatives in one synthetic operation from the readily available and simple arylalkynes and phosphinic acids. Application to the multiple cyclization reaction and the fully intermolecular three-component-coupling-type reaction are also described.
Publisher	American Chemical Society
Source Title	Organic Letters
Volume (Issue)	25(9)
Page	1503-1508
Date of Issued	2023-03-10
Language	English
Handle URL	https://hdl.handle.net/11094/92684
PISSN	15237060
eISSN	15237052
Relation.isVersionOf	DOI (Publisher Version) https://doi.org/10.1021/acs.orglett.3c00263
Access Rights	open access
CopyRight	© 2023 American Chemical Society.
CopyRight	This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.3c00263.
oaire:version	Accepted Manuscript
Category	学術雑誌論文 Journal Article

Resource Type	journal article
Local Type	Journal Article
DCMI Type	Text
DCTERMS.bibliographicCitation	Organic Letters. 2023, 25(9), p. 1503-1508
DC.title	One-Step Synthesis of Benzophosphole Derivatives from Arylalkynes by Phosphenium-Dication-Mediated Sequential C-P/C-C Bond Forming Reaction
DC.creator	Nishimura, Kazutoshi
	Xu, Shibo
	Nishii, Yuji
	Hirano, Koji
DC.publisher	American Chemical Society
DC.language' scheme='DCTERMS.RFC1766	English
DC.type' scheme='DCTERMS.DCMIType	Text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2023-03-10
DC.identifier	https://doi.org/10.1021/acs.orglett.3c00263
DC.description	Nishimura K., Xu S., Nishii Y., et al. One-Step Synthesis of Benzophosphole Derivatives from Arylalkynes by Phosphenium-Dication-Mediated Sequential C-P/C-C Bond Forming Reaction. Organic Letters. 25(9), 1503-1508, 10 March 2023; © 2023 American Chemical Society. https://doi.org/10.1021/acs.orglett.3c00263.
DCTERMS.abstract	A metal-free, phosphenium-dication-mediated sequential C-P and C-C bond forming reaction has been developed. This protocol can provide concise access to the (di)benzophosphole derivatives in one synthetic operation from the readily available and simple arylalkynes and phosphinic acids. Application to the multiple cyclization reaction and the fully intermolecular three-component-coupling-type reaction are also described.
DC.rights	© 2023 American Chemical Society.
DC.rights	This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.3c00263.
DC.format	92684
citation_title	One-Step Synthesis of Benzophosphole Derivatives from Arylalkynes by Phosphenium-Dication-Mediated Sequential C-P/C-C Bond Forming Reaction
citation_author	Nishimura, Kazutoshi
	Xu, Shibo
	Nishii, Yuji
	Hirano, Koji
citation_publisher	American Chemical Society
citation_language	English
citation_date	2023-03-10
citation_journal_title	Organic Letters
citation_volume	25
citation_issue	9
citation_firstpage	1503
citation_lastpage	1508
citation_doi	https://doi.org/10.1021/acs.orglett.3c00263
citation_public_url	https://hdl.handle.net/11094/92684

One-Step Synthesis of Benzophosphole Derivatives from Arylalkynes by Phosphenium-Dication-Mediated Sequential C-P/C-C Bond Forming Reaction

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