One-Step Synthesis of Benzophosphole Derivatives from Arylalkynes by Phosphenium-Dication-Mediated Sequential C-P/C-C Bond Forming Reaction

Nishimura, Kazutoshi; Xu, Shibo; Nishii, Yuji et al.

Organic Letters, 2023, 25(9), 1503-1508

Number of Access:420（2025-07-17 20:16 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/92684

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Title
One-Step Synthesis of Benzophosphole Derivatives from Arylalkynes by Phosphenium-Dication-Mediated Sequential C-P/C-C Bond Forming Reaction
Creator
CreatorName
Nishimura, Kazutoshi
CreatorName
Xu, Shibo
NRID
1000070773787 1000070773787
ORCID
0000-0002-6824-0639 0000-0002-6824-0639
researchmap permalink
y_nishii y_nishii
Scopus Author ID
55233363700 55233363700
CreatorName
Nishii, Yuji
NRID
1000070532696 1000070532696
ORCID
0000-0001-9752-1985 0000-0001-9752-1985
researchmap permalink
koj koj
Scopus Author ID
7402407063 7402407063
CreatorName
Hirano, Koji
Description
Nishimura K., Xu S., Nishii Y., et al. One-Step Synthesis of Benzophosphole Derivatives from Arylalkynes by Phosphenium-Dication-Mediated Sequential C-P/C-C Bond Forming Reaction. Organic Letters. 25(9), 1503-1508, 10 March 2023; © 2023 American Chemical Society. https://doi.org/10.1021/acs.orglett.3c00263.
Abstract
A metal-free, phosphenium-dication-mediated sequential C-P and C-C bond forming reaction has been developed. This protocol can provide concise access to the (di)benzophosphole derivatives in one synthetic operation from the readily available and simple arylalkynes and phosphinic acids. Application to the multiple cyclization reaction and the fully intermolecular three-component-coupling-type reaction are also described.
Publisher
American Chemical Society
Source Title
Organic Letters
Volume (Issue)
25(9)
Page
1503-1508
Date of Issued
2023-03-10
Language
English
Handle URL
https://hdl.handle.net/11094/92684
PISSN
15237060
eISSN
15237052
Relation.isVersionOf
DOI (Publisher Version)
https://doi.org/10.1021/acs.orglett.3c00263
Access Rights
open access
CopyRight
© 2023 American Chemical Society.
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.3c00263.
oaire:version
Accepted Manuscript
Category
学術雑誌論文 Journal Article