Designing Hydrogen-Bonded Organic Frameworks (HOFs) with Permanent Porosity

Hisaki, Ichiro; Xin, Chen; Takahashi, Kiyonori et al.

Angewandte Chemie - International Edition, 2019, 58(33), 11160-11170

Number of Access:446（2025-09-20 04:38 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/92729

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Title
Designing Hydrogen-Bonded Organic Frameworks (HOFs) with Permanent Porosity
Creator
NRID
1000090419466 1000090419466
ORCID
0000-0002-8170-5605 0000-0002-8170-5605
researchmap permalink
Ichiro_Hisaki Ichiro_Hisaki
Scopus Author ID
12801798700 12801798700
CreatorName
Hisaki, Ichiro
CreatorName
Xin, Chen
NRID
1000090812595 1000090812595
CreatorName
Takahashi, Kiyonori
NRID
1000060270790 1000060270790
CreatorName
Nakamura, Takayoshi
Subject
gas sorption
hydrogen bonds
hydrogen-bonded organic frameworks (HOFs)
permanent porosity
porous materials
Description
This is the accepted version of the following article: Hisaki I., Xin C.,Takahashi K., et al. Designing Hydrogen-Bonded Organic Frameworks (HOFs) with Permanent Porosity. Angewandte Chemie - International Edition 58, 11160 (2019), which has been published in final form at https://doi.org/10.1002/anie.201902147. This article may be used for non-commercialpurposes in accordance with the Wiley Self-ArchivingPolicy [https://authorservices.wiley.com/author-resources/Journal-Authors/licensing/self-archiving.html]
Abstract
Designing organic components that can be used to construct porous materials enables the preparation of tailored functionalized materials. Research into porous materials has seen a resurgence in the past decade as a result of finding of self-standing porous molecular crystals (PMCs). Particularly, a number of crystalline systems with permanent porosity that are formed by self-assembly through hydrogen bonding (H-bonding) have been developed. Such systems are called hydrogen-bonded organic frameworks (HOFs). Herein we systematically describe H-bonding patterns (supramolecular synthons) and molecular structures (tectons) that have been used to achieve thermal and chemical durability, a large surface area, and functions, such as selective gas sorption and separation, which can provide design principles for constructing HOFs with permanent porosity.
Publisher
Wiley-VCH
Source Title
Angewandte Chemie - International Edition
Volume (Issue)
58(33)
Page
11160-11170
Date of Issued
2019-08-12
Language
English
Handle URL
https://hdl.handle.net/11094/92729
PISSN
14337851
eISSN
15213773
Relation.isVersionOf
DOI (Publisher Version)
https://doi.org/10.1002/anie.201902147
Access Rights
open access
CopyRight
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA.
oaire:version
Accepted Manuscript
Category
学術雑誌論文 Journal Article