A C₃-symmetric macrocycle-based, hydrogen-bonded, multiporous hexagonal network as a motif of porous molecular crystals　

Hisaki, Ichiro; Nakagawa, Shoichi; Tohnai, Norimitsu et al.

Angewandte Chemie - International Edition, 2015, 54(10), 3008-3012

Number of Access:475（2025-08-01 13:24 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/92738

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Title
A C₃-symmetric macrocycle-based, hydrogen-bonded, multiporous hexagonal network as a motif of porous molecular crystals　
Creator
NRID
1000090419466 1000090419466
ORCID
0000-0002-8170-5605 0000-0002-8170-5605
researchmap permalink
Ichiro_Hisaki Ichiro_Hisaki
Scopus Author ID
12801798700 12801798700
CreatorName
Hisaki, Ichiro
CreatorName
Nakagawa, Shoichi
NRID
1000030346184 1000030346184
researchmap permalink
read0089607 read0089607
Scopus Author ID
6701482198 6701482198
ORCID
0000-0001-7051-7599 0000-0001-7051-7599
CreatorName
Tohnai, Norimitsu
CreatorName
Miyata, Mikiji
Subject
Annulenes
Hydrogen bonds
Phenylene triangle
Porous materials
Supramolecular chemistry
Description
This is the accepted version of the following article: Hisaki I., Nakagawa S., Tohnai N., et al. A C₃-symmetric macrocycle-based, hydrogen-bonded, multiporous hexagonal network as a motif of porous molecular crystals. Angewandte Chemie - International Edition 54, 3008 (2015), which has been published in final form at https://doi.org/10.1002/anie.201411438.[Link to final article]. This article may be used for non-commercialpurposes in accordance with the Wiley Self-ArchivingPolicy [https://authorservices.wiley.com/author-resources/Journal-Authors/licensing/self-archiving.html]
Abstract
A C₃-symmetric π-conjugated macrocycle combined with an appropriate hydrogen bonding module (phenylene triangle) allowed the construction of crystalline supramolecular frameworks with a cavity volume of up to 58 %. The frameworks were obtained through non-interpenetrated stacking of a hexagonal sheet possessing three kinds of pores with different sizes and shapes. The activated porous material absorbed CO₂ up to 96 cm³ g-¹ at 195 K under 1 atm.
Publisher
Wiley-VCH
Source Title
Angewandte Chemie - International Edition
Volume (Issue)
54(10)
Page
3008-3012
Date of Issued
2015-03-02
Language
English
Handle URL
https://hdl.handle.net/11094/92738
PISSN
14337851
eISSN
15213773
Relation.isVersionOf
DOI (Publisher Version)
https://doi.org/10.1002/anie.201411438
Access Rights
open access
CopyRight
© 2015 Wiley-VCH Verlag GmbH & Co. KGaA.
oaire:version
Accepted Manuscript
Category
学術雑誌論文 Journal Article