Pd-catalysed, Ag-assisted C2-H alkenylation of benzophospholes

Tokura, Yu; Xu, Shibo; Kojima, Yuki et al.

Chemical Communications, 2022, 58(87), 12208-12211

Number of Access:70（2025-06-07 18:07 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/92739

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Title
Pd-catalysed, Ag-assisted C2-H alkenylation of benzophospholes
Creator
CreatorName
Tokura, Yu
CreatorName
Xu, Shibo
CreatorName
Kojima, Yuki
NRID
1000020183626 1000020183626
ORCID
0000-0001-8288-6439 0000-0001-8288-6439
researchmap permalink
read0013936 read0013936
Scopus Author ID
7402799909 7402799909
CreatorName
Miura, Masahiro
NRID
1000070532696 1000070532696
ORCID
0000-0001-9752-1985 0000-0001-9752-1985
researchmap permalink
koj koj
Scopus Author ID
7402407063 7402407063
CreatorName
Hirano, Koji
Description
Tokura Y., Xu S., Kojima Y., et al. Pd-catalysed, Ag-assisted C2-H alkenylation of benzophospholes. Chemical Communications 58, 12208 (2022); https://doi.org/10.1039/D2CC04942B .
Abstract
A palladium-catalysed, silver-assisted regioselective C2-H alkenylation of benzophospholes with terminal alkenes has been developed. The palladium catalysis accommodates styrenes and electron-deficient alkenes including ester, ketone, nitrile, and phosphonate. Thus, this protocol enables the rapid construction of various benzophosphole-vinylene conjugations from the two simple C-H starting substrates. Optical properties of newly synthesized C2-alkenylated benzophospholes are also investigated.
Publisher
Royal Society of Chemistry
Source Title
Chemical Communications
Volume (Issue)
58(87)
Page
12208-12211
Date of Issued
2022-10-12
Language
English
Handle URL
https://hdl.handle.net/11094/92739
PISSN
13597345
eISSN
1364548X
Relation.isVersionOf
DOI (Publisher Version)
https://doi.org/10.1039/D2CC04942B
Access Rights
open access
CopyRight
Reproduced from Tokura Y., Xu S., Kojima Y., et al. Pd-catalysed, Ag-assisted C2-H alkenylation of benzophospholes. Chemical Communications 58, 12208 (2022); https://doi.org/10.1039/D2CC04942B with permission from the Royal Society of Chemistry.
oaire:version
Accepted Manuscript
Category
学術雑誌論文 Journal Article