Peri -Selective Direct Acylmethylation and Amidation of Naphthalene Derivatives Using Iridium and Rhodium Catalysts

Kona, Chandrababu Naidu; Oku, Rikuto; Nishii, Yuji; Miura, Masahiro

doi:https://doi.org/10.1055/a-1472-1059

Peri -Selective Direct Acylmethylation and Amidation of Naphthalene Derivatives Using Iridium and Rhodium Catalysts

Kona, Chandrababu Naidu; Oku, Rikuto; Nishii, Yuji et al.

Synthesis (Germany), 2021, 53(17), 3126-3136

Number of Access:246（2025-08-15 06:45 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/92780

Link to primary information

File	Format	Terms of use	Size	Views	Date.Available	Description	information
Synthesis_53_17_3126	pdf	None	669 KB	55	2023.10.20

Item Information

Output File Export EndNote Basic Export Mendeley

Title	Peri -Selective Direct Acylmethylation and Amidation of Naphthalene Derivatives Using Iridium and Rhodium Catalysts
Creator	CreatorName Kona, Chandrababu Naidu
	CreatorName Oku, Rikuto
	NRID 1000070773787 1000070773787 ORCID 0000-0002-6824-0639 0000-0002-6824-0639 researchmap permalink y_nishii y_nishii Scopus Author ID 55233363700 55233363700 CreatorName Nishii, Yuji
	NRID 1000020183626 1000020183626 ORCID 0000-0001-8288-6439 0000-0001-8288-6439 researchmap permalink read0013936 read0013936 Scopus Author ID 7402799909 7402799909 CreatorName Miura, Masahiro
Subject	alkylation
	amidation
	C-H Activation
	iridium
	rhodium
Description	This is an Accepted Manuscript of an article published by Thieme Publishing Group in Journal Title on Publication Date, available online at https://doi.org/10.1055/a-1472-1059.
Abstract	An iridium-catalyzed acylmethylation and a rhodium-catalyzed amidation of naphthalene derivatives are reported, adopting sulfoxonium ylides and dioxazolones as carbene and nitrene transfer agents, respectively. The use of SMe group as a directing group was key to ensure the peri -selective functionalization, and it can be easily removed or diversely transformed to other synthetically useful functionalities after the catalysis.
Publisher	Georg Thieme Verlag
Source Title	Synthesis (Germany)
Volume (Issue)	53(17)
Page	3126-3136
Date of Issued	2021-04-22
Language	English
Handle URL	https://hdl.handle.net/11094/92780
PISSN	00397881
eISSN	1437210X
NCID	AA00855740
Relation.isVersionOf	DOI (Publisher Version) https://doi.org/10.1055/a-1472-1059
Access Rights	open access
CopyRight	© 2021 Georg Thieme Verlag. All rights reserved.
oaire:version	Accepted Manuscript
Category	学術雑誌論文 Journal Article

Resource Type	journal article
Local Type	Journal Article
DCMI Type	Text
DCTERMS.bibliographicCitation	Synthesis (Germany). 2021, 53(17), p. 3126-3136
DC.title	Peri -Selective Direct Acylmethylation and Amidation of Naphthalene Derivatives Using Iridium and Rhodium Catalysts
DC.creator	Kona, Chandrababu Naidu
	Oku, Rikuto
	Nishii, Yuji
	Miura, Masahiro
DC.publisher	Georg Thieme Verlag
DC.language' scheme='DCTERMS.RFC1766	English
DC.type' scheme='DCTERMS.DCMIType	Text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2021-04-22
DC.identifier	https://doi.org/10.1055/a-1472-1059
DC.subject	alkylation
	amidation
	C-H Activation
	iridium
	rhodium
DC.description	This is an Accepted Manuscript of an article published by Thieme Publishing Group in Journal Title on Publication Date, available online at https://doi.org/10.1055/a-1472-1059.
DCTERMS.abstract	An iridium-catalyzed acylmethylation and a rhodium-catalyzed amidation of naphthalene derivatives are reported, adopting sulfoxonium ylides and dioxazolones as carbene and nitrene transfer agents, respectively. The use of SMe group as a directing group was key to ensure the peri -selective functionalization, and it can be easily removed or diversely transformed to other synthetically useful functionalities after the catalysis.
DC.rights	© 2021 Georg Thieme Verlag. All rights reserved.
DC.format	92780
citation_title	Peri -Selective Direct Acylmethylation and Amidation of Naphthalene Derivatives Using Iridium and Rhodium Catalysts
citation_author	Kona, Chandrababu Naidu
	Oku, Rikuto
	Nishii, Yuji
	Miura, Masahiro
citation_publisher	Georg Thieme Verlag
citation_language	English
citation_date	2021-04-22
citation_journal_title	Synthesis (Germany)
citation_volume	53
citation_issue	17
citation_firstpage	3126
citation_lastpage	3136
citation_doi	https://doi.org/10.1055/a-1472-1059
citation_public_url	https://hdl.handle.net/11094/92780

Peri -Selective Direct Acylmethylation and Amidation of Naphthalene Derivatives Using Iridium and Rhodium Catalysts

Link to primary information

Item Information

Show details