Sulfur-Directed C7-Selective Alkenylation of Indoles under Rhodium Catalysis

Kona, Chandrababu Naidu; Nishii, Yuji; Miura, Masahiro

Organic Letters, 2021, 23(16), 6252-6256

Number of Access:308（2025-11-05 05:50 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/92808

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Title
Sulfur-Directed C7-Selective Alkenylation of Indoles under Rhodium Catalysis
Creator
CreatorName
Kona, Chandrababu Naidu
NRID
1000070773787 1000070773787
ORCID
0000-0002-6824-0639 0000-0002-6824-0639
researchmap permalink
y_nishii y_nishii
Scopus Author ID
55233363700 55233363700
CreatorName
Nishii, Yuji
NRID
1000020183626 1000020183626
ORCID
0000-0001-8288-6439 0000-0001-8288-6439
researchmap permalink
read0013936 read0013936
Scopus Author ID
7402799909 7402799909
CreatorName
Miura, Masahiro
Description
Kona C.N., Nishii Y., Miura M.. Sulfur-Directed C7-Selective Alkenylation of Indoles under Rhodium Catalysis. Organic Letters. 23(16), 6252-6256, (2021), 20 August 2022; ©2021 American Chemical Society. https://doi.org/10.1021/acs.orglett.1c01990.
Abstract
Regioselective direct functionalization of an indole benzenoid fragment has been a significant challenge be-cause of its inherently lower reactivity. In this report, we introduce a Rh-catalyzed C7-selective alkenylation of indole de-rivatives utilizing a new sulfur directing group N-SCy. A notable feature of this system is that the directing group is readily installed to the indoles and easily removed after the catalysis under mild conditions.
Publisher
American Chemical Society
Source Title
Organic Letters
Volume (Issue)
23(16)
Page
6252-6256
Date of Issued
2021-08-20
Language
English
Handle URL
https://hdl.handle.net/11094/92808
PISSN
15237060
eISSN
15237052
NCID
AA11347843
Relation.isVersionOf
DOI (Publisher Version)
https://doi.org/10.1021/acs.orglett.1c01990
Access Rights
open access
CopyRight
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.1c01990.
oaire:version
Accepted Manuscript
Category
学術雑誌論文 Journal Article