Cp*M-Catalyzed Direct Annulation with Terminal Alkynes and Their Surrogates for the Construction of Multi-Ring Systems

Nishii, Yuji; Miura, Masahiro

ACS Catalysis, 2020, 10(17), 9747-9757

Number of Access:104（2025-06-08 12:48 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/92813

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Title
Cp*M-Catalyzed Direct Annulation with Terminal Alkynes and Their Surrogates for the Construction of Multi-Ring Systems
Creator
NRID
1000070773787 1000070773787
ORCID
0000-0002-6824-0639 0000-0002-6824-0639
researchmap permalink
y_nishii y_nishii
Scopus Author ID
55233363700 55233363700
CreatorName
Nishii, Yuji
NRID
1000020183626 1000020183626
ORCID
0000-0001-8288-6439 0000-0001-8288-6439
researchmap permalink
read0013936 read0013936
Scopus Author ID
7402799909 7402799909
CreatorName
Miura, Masahiro
Subject
alkynes
C-H functionalization
cobalt
cyclization
iridium
rhodium
Description
Nishii Y., Miura M.. Cp*M-Catalyzed Direct Annulation with Terminal Alkynes and Their Surrogates for the Construction of Multi-Ring Systems. ACS Catalysis. 10(17), 9747-9757, (2020), 4 September 2020; ©2020 American Chemical Society. https://doi.org/10.1021/acscatal.0c02972.
Abstract
Transition-metal-catalyzed C–H activation followed by oxidative cyclization with unsaturated coupling partners has been a valuable synthetic tool for the multi-ring molecular scaffolds. This Perspective introduces the recent progress on the Cp*M-catalyzed (M = Co, Rh, and Ir) oxidative direct annulation of functionalized arenes with terminal alkynes and their equivalents through C–H bond cleavage. The highlighted examples are categorized according to the ten different types of reagents used in the transfor-mations. The representative conditions, selected examples of the reaction scope, and key mechanistic aspects are briefly summarized.
Publisher
American Chemical Society
Source Title
ACS Catalysis
Volume (Issue)
10(17)
Page
9747-9757
Date of Issued
2020-09-04
Language
English
Handle URL
https://hdl.handle.net/11094/92813
eISSN
21555435
NCID
AA12599706
Relation.isVersionOf
DOI (Publisher Version)
https://doi.org/10.1021/acscatal.0c02972
Access Rights
open access
CopyRight
This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acscatal.0c02972.
oaire:version
Accepted Manuscript
Category
学術雑誌論文 Journal Article