Rhodium-catalysed direct formylmethylation using vinylene carbonate and sequential dehydrogenative esterification

Kato, Moena; Ghosh, Koushik; Nishii, Yuji et al.

Chemical Communications, 2021, 67(57), 8280-8283

Number of Access:207（2025-08-14 15:05 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/92831

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Title
Rhodium-catalysed direct formylmethylation using vinylene carbonate and sequential dehydrogenative esterification
Creator
CreatorName
Kato, Moena
CreatorName
Ghosh, Koushik
NRID
1000070773787 1000070773787
ORCID
0000-0002-6824-0639 0000-0002-6824-0639
researchmap permalink
y_nishii y_nishii
Scopus Author ID
55233363700 55233363700
CreatorName
Nishii, Yuji
NRID
1000020183626 1000020183626
ORCID
0000-0001-8288-6439 0000-0001-8288-6439
researchmap permalink
read0013936 read0013936
Scopus Author ID
7402799909 7402799909
CreatorName
Miura, Masahiro
Description
Kato M., Ghosh K., Nishii Y., et al. Rhodium-catalysed direct formylmethylation using vinylene carbonate and sequential dehydrogenative esterification. Chemical Communications 57, 8280 (2021); https://doi.org/10.1039/D1CC03362J.
Abstract
A rhodium-catalysed direct formylmethylation adopting vinylene carbonate as an ethynol equivalent is reported. The developed catalytic system is further utilised for the oxidant-free production of esters with the liberation of hydrogen gas. Some control experiments are conducted to elucidate the reaction mechanism.
Publisher
Royal Society of Chemistry
Source Title
Chemical Communications
Volume (Issue)
67(57)
Page
8280-8283
Date of Issued
2021-07-22
Language
English
Handle URL
https://hdl.handle.net/11094/92831
PISSN
13597345
eISSN
1364548X
NCID
AA11071130
Relation.isVersionOf
DOI (Publisher Version)
https://doi.org/10.1039/D1CC03362J
Access Rights
open access
CopyRight
Reproduced from Kato M., Ghosh K., Nishii Y., et al. Rhodium-catalysed direct formylmethylation using vinylene carbonate and sequential dehydrogenative esterification. Chemical Communications 57, 8280 (2021); https://doi.org/10.1039/D1CC03362J with permission from the Royal Society of Chemistry.
oaire:version
Accepted Manuscript
Category
学術雑誌論文 Journal Article