Copper-mediated Trifluoromethylthiolation of Alkenyl Iodides with AgSCF₃

Kojima, Yuki; Hirano, Koji

Chemistry Letters, 2023, 52(10), 791-793

Number of Access:337（2025-07-17 20:35 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/92836

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Title
Copper-mediated Trifluoromethylthiolation of Alkenyl Iodides with AgSCF₃
Creator
CreatorName
Kojima, Yuki
NRID
1000070532696 1000070532696
ORCID
0000-0001-9752-1985 0000-0001-9752-1985
researchmap permalink
koj koj
Scopus Author ID
7402407063 7402407063
CreatorName
Hirano, Koji
Subject
Copper
Fluorine
Trifluoromethylthio group
Abstract
A copper-mediated trifluoromethylthiolation of alkenyl iodides with AgSCF₃ has been developed. CuSCF₃ species generated in-situ from a copper salt and AgSCF₃ can be coupled with alkenyl iodides to produce the corresponding trifluoromethylthioalkenes efficiently. The reaction conditions are compatible with various functional groups. Moreover, its scale-up synthesis is also possible to provide the desired trifluoromethylthiolated product even on a gram-scale.
Publisher
The Chemical Society of Japan
Source Title
Chemistry Letters
Volume (Issue)
52(10)
Page
791-793
Date of Issued
2023-10-05
Language
English
Handle URL
https://hdl.handle.net/11094/92836
PISSN
03667022
eISSN
13480715
Relation.isVersionOf
DOI (Publisher Version)
https://doi.org/10.1246/cl.230335
Access Rights
open access
CopyRight
© 2023 The Chemical Society of Japan
oaire:version
Accepted Manuscript
Category
学術雑誌論文 Journal Article