CH3Cl Dissociation, CH3 abstraction, and Cl adsorption from the dissociative scattering of supersonic CH3Cl on Cu(111) and Cu(410)

Makino, Takamasa; Tsuda, Yasutaka; Yoshigoe, Akitaka; Diño, Wilson Agerico; Okada, Michio

doi:https://doi.org/10.1016/j.apsusc.2023.158568

CH3Cl Dissociation, CH3 abstraction, and Cl adsorption from the dissociative scattering of supersonic CH3Cl on Cu(111) and Cu(410)

Makino, Takamasa; Tsuda, Yasutaka; Yoshigoe, Akitaka et al.

Applied Surface Science, 2024, 642, 158568

Number of Access:617（2025-08-28 21:38 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/93902

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Title	CH3Cl Dissociation, CH3 abstraction, and Cl adsorption from the dissociative scattering of supersonic CH3Cl on Cu(111) and Cu(410)
Creator	CreatorName Makino, Takamasa
	NRID 1000050869394 1000050869394 CreatorName Tsuda, Yasutaka
	NRID 1000000283490 1000000283490 CreatorName Yoshigoe, Akitaka
	NRID 1000060379146 1000060379146 ORCID 0000-0001-6154-7681 0000-0001-6154-7681 researchmap permalink read0089939 read0089939 Scopus Author ID 35600189900 35600189900 CreatorName Diño, Wilson Agerico
	NRID 1000030281116 1000030281116 researchmap permalink read0046583 read0046583 Scopus Author ID 55696587000 55696587000 CreatorName Okada, Michio
Description	Makino T., Tsuda Y., Yoshigoe A., et al. CH3Cl Dissociation, CH3 abstraction, and Cl adsorption from the dissociative scattering of supersonic CH3Cl on Cu(111) and Cu(410). Applied Surface Science 642, 158568 (2024); https://doi.org/10.1016/j.apsusc.2023.158568.
Abstract	To study the elementary steps in the Rochow-Müller process, we bombarded Cu(1 1 1) and Cu(4 1 0) with 0.7–1.9 eV supersonic molecular beams (SSMB) of CH3Cl. We then identified the corresponding adsorbed species using X-ray photoemission spectroscopy (XPS) in conjunction with synchrotron radiation (SR). We found Cl as the dominant adsorbed species (much higher than that of adsorbed carbonaceous species) coming from the dissociative scattering of CH3Cl. We also found that the threshold kinetic energy of the reaction depends on the crystal surface orientation.
Publisher	Elsevier B.V.
Source Title	Applied Surface Science
Volume (Issue)	642
Page	158568
Date of Issued	2024-01-01
Language	English
Handle URL	https://hdl.handle.net/11094/93902
PISSN	01694332
Relation.isVersionOf	DOI (Publisher Version) https://doi.org/10.1016/j.apsusc.2023.158568
Access Rights	embargoed access
CopyRight	© 2023. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/
CopyRight	The full-text file will be made open to the public on 1 January 2026 in accordance with the publisher's policy.
oaire:version	Accepted Manuscript
Category	学術雑誌論文 Journal Article

Resource Type	journal article
Local Type	Journal Article
DCMI Type	Text
DCTERMS.bibliographicCitation	Applied Surface Science. 2024, 642, p. 158568
DC.title	CH3Cl Dissociation, CH3 abstraction, and Cl adsorption from the dissociative scattering of supersonic CH3Cl on Cu(111) and Cu(410)
DC.creator	Makino, Takamasa
	Tsuda, Yasutaka
	Yoshigoe, Akitaka
	Diño, Wilson Agerico
	Okada, Michio
DC.publisher	Elsevier B.V.
DC.language' scheme='DCTERMS.RFC1766	English
DC.type' scheme='DCTERMS.DCMIType	Text
DCTERMS.issued' scheme='DCTERMS.W3CDTF	2024-01-01
DC.identifier	https://doi.org/10.1016/j.apsusc.2023.158568
DC.description	Makino T., Tsuda Y., Yoshigoe A., et al. CH3Cl Dissociation, CH3 abstraction, and Cl adsorption from the dissociative scattering of supersonic CH3Cl on Cu(111) and Cu(410). Applied Surface Science 642, 158568 (2024); https://doi.org/10.1016/j.apsusc.2023.158568.
DCTERMS.abstract	To study the elementary steps in the Rochow-Müller process, we bombarded Cu(1 1 1) and Cu(4 1 0) with 0.7–1.9 eV supersonic molecular beams (SSMB) of CH3Cl. We then identified the corresponding adsorbed species using X-ray photoemission spectroscopy (XPS) in conjunction with synchrotron radiation (SR). We found Cl as the dominant adsorbed species (much higher than that of adsorbed carbonaceous species) coming from the dissociative scattering of CH3Cl. We also found that the threshold kinetic energy of the reaction depends on the crystal surface orientation.
DC.rights	© 2023. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/
DC.rights	The full-text file will be made open to the public on 1 January 2026 in accordance with the publisher's policy.
DC.format	93902
citation_title	CH3Cl Dissociation, CH3 abstraction, and Cl adsorption from the dissociative scattering of supersonic CH3Cl on Cu(111) and Cu(410)
citation_author	Makino, Takamasa
	Tsuda, Yasutaka
	Yoshigoe, Akitaka
	Diño, Wilson Agerico
	Okada, Michio
citation_publisher	Elsevier B.V.
citation_language	English
citation_date	2024-01-01
citation_journal_title	Applied Surface Science
citation_volume	642
citation_firstpage	158568
citation_doi	https://doi.org/10.1016/j.apsusc.2023.158568
citation_public_url	https://hdl.handle.net/11094/93902

CH3Cl Dissociation, CH3 abstraction, and Cl adsorption from the dissociative scattering of supersonic CH3Cl on Cu(111) and Cu(410)

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