Postsynthetic Installation of Lanthanide Cubane Clusters in a 3D Hydrogen-Bonded Framework of Irᴵᴵᴵ₄Znᴵᴵ₄ Multicarboxylates

Thammakan, Supaphorn; Yoshinari, Nobuto; Tsuchikawa, Marie et al.

Inorganic Chemistry, 2024, 63(14), 6239-6247

Number of Access:204（2025-08-20 22:57 Counts）

Identifier to cite or link to this item: https://hdl.handle.net/11094/95451

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Title
Postsynthetic Installation of Lanthanide Cubane Clusters in a 3D Hydrogen-Bonded Framework of Irᴵᴵᴵ₄Znᴵᴵ₄ Multicarboxylates
Creator
CreatorName
Thammakan, Supaphorn
NRID
1000010583338 1000010583338
ORCID
0000-0003-2457-0967 0000-0003-2457-0967
researchmap permalink
read0151149 read0151149
Scopus Author ID
14009212400 14009212400
CreatorName
Yoshinari, Nobuto
CreatorName
Tsuchikawa, Marie
CreatorName
Rujiwatra, Apinpus
NRID
1000050201497 1000050201497
researchmap permalink
takumikonno takumikonno
Scopus Author ID
7202325347 7202325347
CreatorName
Konno, Takumi
Description
Thammakan S., Yoshinari N., Tsuchikawa M., et al. Postsynthetic Installation of Lanthanide Cubane Clusters in a 3D Hydrogen-Bonded Framework of Irᴵᴵᴵ₄Znᴵᴵ₄ Multicarboxylates. Inorganic Chemistry 63, 6239 (2024); https://doi.org/10.1021/acs.inorgchem.3c04513.
Abstract
Immersing single crystals of (Δ)4-K6[Ir4Zn4O(l-cysteinate)12]·nH2O (K6[1Ir]·nH2O) bearing 12 free carboxylate groups, which was newly prepared from Δ-H3[Ir(l-cysteinate)3], ZnBr2, ZnO, and KOH, in an aqueous solution of lanthanide(III) acetate produced Ln2[1Ir]·nH2O (2Ln; Ln = LaIII, CeIII, PrIII, and NdIII) and Ln0.33[Ln4(OH)4(OAc)3(H2O)7][1Ir]·nH2O (3Ln; Ln = SmIII, EuIII, GdIII, TbIII, DyIII, ErIII, HoIII, TmIII, YbIII, and LuIII) in a single-crystal-to-single-crystal transformation manner. X-ray crystallography showed that the KI ions in K6[1Ir]·nH2O are completely exchanged by the LnIII ions in 2Ln and 3Ln, retaining the 3D hydrogen-bonded framework that consists of the IrIII4ZnII4 complex anions of [1Ir]6-. While 2Ln contained the LnIII ions as isolated aqua species, the LnIII ions in 3Ln existed as cationic cubane clusters of [Ln4(OH)4(OAc)3(H2O)7]5+; these were linked by [1Ir]6- anions through carboxylate groups in a 3D polymeric structure. 3Ln showed magnetic and photoluminescence properties that are characteristically observed for discrete LnIII species in the solid state.
Publisher
American Chemical Society
Source Title
Inorganic Chemistry
Volume (Issue)
63(14)
Page
6239-6247
Date of Issued
2024-04-08
Language
English
Handle URL
https://hdl.handle.net/11094/95451
PISSN
00201669
eISSN
1520510X
Relation.isVersionOf
DOI (Publisher Version)
https://doi.org/10.1021/acs.inorgchem.3c04513
Access Rights
open access
CopyRight
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.3c04513.
oaire:version
Accepted Manuscript
Category
学術雑誌論文 Journal Article